DE2312514A1 - Verfahren zur durchfuehrung von reformierreaktionen - Google Patents
Verfahren zur durchfuehrung von reformierreaktionenInfo
- Publication number
- DE2312514A1 DE2312514A1 DE2312514A DE2312514A DE2312514A1 DE 2312514 A1 DE2312514 A1 DE 2312514A1 DE 2312514 A DE2312514 A DE 2312514A DE 2312514 A DE2312514 A DE 2312514A DE 2312514 A1 DE2312514 A1 DE 2312514A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- bed
- reforming reaction
- hydrogen
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 35
- 238000006243 chemical reaction Methods 0.000 title description 3
- 239000003054 catalyst Substances 0.000 claims description 88
- 239000007789 gas Substances 0.000 claims description 71
- 238000002309 gasification Methods 0.000 claims description 42
- 229910052739 hydrogen Inorganic materials 0.000 claims description 38
- 239000001257 hydrogen Substances 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 230000008929 regeneration Effects 0.000 claims description 28
- 238000011069 regeneration method Methods 0.000 claims description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- 230000003197 catalytic effect Effects 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- 238000000629 steam reforming Methods 0.000 claims description 19
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims description 16
- 238000005984 hydrogenation reaction Methods 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 239000000376 reactant Substances 0.000 claims description 13
- 238000006057 reforming reaction Methods 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 6
- 238000002407 reforming Methods 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 239000011874 heated mixture Substances 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1348972A GB1421767A (en) | 1972-03-22 | 1972-03-22 | Methods of gasifying hydrocabons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2312514A1 true DE2312514A1 (de) | 1973-09-27 |
Family
ID=10023897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2312514A Pending DE2312514A1 (de) | 1972-03-22 | 1973-03-13 | Verfahren zur durchfuehrung von reformierreaktionen |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS4914501A (enExample) |
| BE (1) | BE797092A (enExample) |
| BR (1) | BR7301988D0 (enExample) |
| DE (1) | DE2312514A1 (enExample) |
| FR (1) | FR2176989B1 (enExample) |
| GB (1) | GB1421767A (enExample) |
| IE (1) | IE37327B1 (enExample) |
| IT (1) | IT981498B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2042040B (en) | 1978-05-30 | 1982-07-14 | Inventec Patents Ltd | Foldable step-stool |
| US7491250B2 (en) | 2002-06-25 | 2009-02-17 | Exxonmobil Research And Engineering Company | Pressure swing reforming |
| US7217303B2 (en) | 2003-02-28 | 2007-05-15 | Exxonmobil Research And Engineering Company | Pressure swing reforming for fuel cell systems |
| US7914764B2 (en) | 2003-02-28 | 2011-03-29 | Exxonmobil Research And Engineering Company | Hydrogen manufacture using pressure swing reforming |
| CN103265394B (zh) * | 2013-05-27 | 2015-06-03 | 神华集团有限责任公司 | 一种甲烷化反应系统及甲烷化催化剂的再生工艺 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2472844A (en) * | 1942-06-25 | 1949-06-14 | Standard Oil Dev Co | Maintenance of catalyst activity in hydrocarbon conversion processes |
-
1972
- 1972-03-22 GB GB1348972A patent/GB1421767A/en not_active Expired
-
1973
- 1973-02-27 IE IE304/73A patent/IE37327B1/xx unknown
- 1973-03-13 DE DE2312514A patent/DE2312514A1/de active Pending
- 1973-03-16 JP JP48030811A patent/JPS4914501A/ja active Pending
- 1973-03-20 BR BR731988A patent/BR7301988D0/pt unknown
- 1973-03-20 IT IT21867/73A patent/IT981498B/it active
- 1973-03-21 FR FR7310091A patent/FR2176989B1/fr not_active Expired
- 1973-03-21 BE BE129052A patent/BE797092A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2176989B1 (enExample) | 1976-09-10 |
| IE37327B1 (en) | 1977-06-22 |
| GB1421767A (en) | 1976-01-21 |
| FR2176989A1 (enExample) | 1973-11-02 |
| IT981498B (it) | 1974-10-10 |
| BE797092A (fr) | 1973-07-16 |
| JPS4914501A (enExample) | 1974-02-08 |
| BR7301988D0 (pt) | 1974-07-18 |
| IE37327L (en) | 1973-09-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |