DE2306879A1 - Elektrochemische vorrichtung zur bestimmung des sauerstoffgehaltes eines fludes - Google Patents
Elektrochemische vorrichtung zur bestimmung des sauerstoffgehaltes eines fludesInfo
- Publication number
- DE2306879A1 DE2306879A1 DE2306879A DE2306879A DE2306879A1 DE 2306879 A1 DE2306879 A1 DE 2306879A1 DE 2306879 A DE2306879 A DE 2306879A DE 2306879 A DE2306879 A DE 2306879A DE 2306879 A1 DE2306879 A1 DE 2306879A1
- Authority
- DE
- Germany
- Prior art keywords
- cathode
- anode
- fluid
- sulfide
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052760 oxygen Inorganic materials 0.000 title claims description 26
- 239000001301 oxygen Substances 0.000 title claims description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 25
- 239000012530 fluid Substances 0.000 title claims description 13
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 239000008151 electrolyte solution Substances 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 230000035945 sensitivity Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 229910052946 acanthite Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 claims 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 claims 1
- 229940056910 silver sulfide Drugs 0.000 claims 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims 1
- 150000004763 sulfides Chemical class 0.000 claims 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 239000003792 electrolyte Substances 0.000 description 15
- 239000012528 membrane Substances 0.000 description 12
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 239000000872 buffer Substances 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 150000003464 sulfur compounds Chemical class 0.000 description 4
- 235000013601 eggs Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000010405 anode material Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 2
- 101150018711 AASS gene Proteins 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010012335 Dependence Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- -1 Poly (tetrafluoroethylene) Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 208000026753 anterior segment dysgenesis Diseases 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- KDQPSPMLNJTZAL-UHFFFAOYSA-L disodium hydrogenphosphate dihydrate Chemical compound O.O.[Na+].[Na+].OP([O-])([O-])=O KDQPSPMLNJTZAL-UHFFFAOYSA-L 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- WABYCCJHARSRBH-UHFFFAOYSA-N metaclazepam Chemical compound C12=CC(Br)=CC=C2N(C)C(COC)CN=C1C1=CC=CC=C1Cl WABYCCJHARSRBH-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- BEEDODBODQVSIM-UHFFFAOYSA-N oxymetazoline hydrochloride Chemical compound Cl.CC1=CC(C(C)(C)C)=C(O)C(C)=C1CC1=NCCN1 BEEDODBODQVSIM-UHFFFAOYSA-N 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229940119096 sinex Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910021655 trace metal ion Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22603772A | 1972-02-14 | 1972-02-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2306879A1 true DE2306879A1 (de) | 1973-08-16 |
Family
ID=22847306
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2306879A Pending DE2306879A1 (de) | 1972-02-14 | 1973-02-13 | Elektrochemische vorrichtung zur bestimmung des sauerstoffgehaltes eines fludes |
| DE2365477*A Pending DE2365477A1 (de) | 1972-02-14 | 1973-02-13 | Elektrochemische vorrichtung zur bestimmung des sauerstoffgehaltes eines fludes |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2365477*A Pending DE2365477A1 (de) | 1972-02-14 | 1973-02-13 | Elektrochemische vorrichtung zur bestimmung des sauerstoffgehaltes eines fludes |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3785948A (enExample) |
| JP (1) | JPS4890589A (enExample) |
| AU (1) | AU5200973A (enExample) |
| CH (1) | CH552213A (enExample) |
| DE (2) | DE2306879A1 (enExample) |
| FR (1) | FR2172685A5 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2657351A1 (de) * | 1975-12-18 | 1977-07-07 | Miles Lab | Vorrichtung mit membran, insbesondere zum durchfuehren eines polarographischen verfahrens |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3839178A (en) * | 1972-10-05 | 1974-10-01 | Gen Electric | Potentiometric oxygen sensor |
| US3859191A (en) * | 1973-04-09 | 1975-01-07 | Orion Research | Hydrogen cyanide sensing cell |
| DE2436261B2 (de) * | 1974-07-27 | 1976-11-25 | Bayer Ag, 5090 Leverkusen | Elektrochemische gasdetektoren |
| GB1550149A (en) * | 1975-10-28 | 1979-08-08 | Dictaphone Corp | Direct gas sensors |
| JPS52127392A (en) * | 1976-04-19 | 1977-10-25 | Hokushin Electric Works | Membrane type gas densitometer |
| GB1587880A (en) * | 1976-12-29 | 1981-04-08 | Hagihara B | Oxygen measuring electrode assembly |
| JPS596432Y2 (ja) * | 1977-05-31 | 1984-02-28 | 株式会社島津製作所 | イオン選択性電極 |
| DE2836868B2 (de) * | 1978-08-23 | 1980-06-19 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Meßwertaufnehmer, insbesondere zur Bestimmung des Partialdruckes von gelösten Gasen |
| US4273638A (en) * | 1978-12-19 | 1981-06-16 | American Hospital Supply Corporation | Electrochemical sensing probe |
| JPS566151A (en) * | 1979-06-27 | 1981-01-22 | Toyota Motor Corp | Solid pole oxygen sensor |
| WO1987002461A1 (en) * | 1985-10-11 | 1987-04-23 | Beckman Industrial Corporation Process Instruments | A method of fabricating rhodium foil-glass electrodes |
| DE3780879D1 (de) * | 1986-06-06 | 1992-09-10 | Kontron Instr Holding | Elektrodenanordnung. |
| JPH06105236B2 (ja) * | 1988-10-17 | 1994-12-21 | 株式会社堀場製作所 | 比較電極 |
| JPH03183943A (ja) * | 1989-12-14 | 1991-08-09 | Hitachi Ltd | 酸素センサ |
| DE19515392C2 (de) * | 1995-04-26 | 1997-07-17 | Prominent Dosiertechnik Gmbh | Elektrochemische Meßzelle |
| CN101027549B (zh) * | 2002-06-28 | 2012-02-29 | 罗斯蒙德分析公司 | 抗硫传感器 |
| US20120193229A1 (en) * | 2011-01-27 | 2012-08-02 | Life Safety Distribution Ag | Electrochemical Oxygen Sensor with Internal Barrier to Oxygen Diffusion |
| CN108027339A (zh) * | 2015-07-22 | 2018-05-11 | 霍尼韦尔国际公司 | 经单件成形的平面间隔器 |
| CN108139352B (zh) | 2015-08-24 | 2020-07-24 | 霍尼韦尔国际公司 | 氧传感器和检测氧的方法 |
| JP6955950B2 (ja) * | 2017-09-29 | 2021-10-27 | マクセル株式会社 | 電気化学式酸素センサ |
-
1972
- 1972-02-14 US US00226037A patent/US3785948A/en not_active Expired - Lifetime
-
1973
- 1973-02-08 AU AU52009/73A patent/AU5200973A/en not_active Expired
- 1973-02-13 DE DE2306879A patent/DE2306879A1/de active Pending
- 1973-02-13 CH CH205673A patent/CH552213A/xx not_active IP Right Cessation
- 1973-02-13 DE DE2365477*A patent/DE2365477A1/de active Pending
- 1973-02-13 FR FR7305067A patent/FR2172685A5/fr not_active Expired
- 1973-02-14 JP JP48017587A patent/JPS4890589A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2657351A1 (de) * | 1975-12-18 | 1977-07-07 | Miles Lab | Vorrichtung mit membran, insbesondere zum durchfuehren eines polarographischen verfahrens |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4890589A (enExample) | 1973-11-26 |
| FR2172685A5 (enExample) | 1973-09-28 |
| DE2365477A1 (de) | 1975-04-30 |
| US3785948A (en) | 1974-01-15 |
| CH552213A (de) | 1974-07-31 |
| AU5200973A (en) | 1974-08-08 |
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