DE2300172A1 - Verfahren zur extraktion von nickel und kobalt aus oxydischen nickel- und kobalthaltigen laterit- und garnieriterzen - Google Patents
Verfahren zur extraktion von nickel und kobalt aus oxydischen nickel- und kobalthaltigen laterit- und garnieriterzenInfo
- Publication number
- DE2300172A1 DE2300172A1 DE2300172A DE2300172A DE2300172A1 DE 2300172 A1 DE2300172 A1 DE 2300172A1 DE 2300172 A DE2300172 A DE 2300172A DE 2300172 A DE2300172 A DE 2300172A DE 2300172 A1 DE2300172 A1 DE 2300172A1
- Authority
- DE
- Germany
- Prior art keywords
- nickel
- solution
- cobalt
- ammonium
- leaching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910017052 cobalt Inorganic materials 0.000 title claims description 86
- 239000010941 cobalt Substances 0.000 title claims description 86
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 85
- 238000000034 method Methods 0.000 title claims description 77
- 230000008569 process Effects 0.000 title claims description 52
- 238000000605 extraction Methods 0.000 title claims description 19
- 229910001710 laterite Inorganic materials 0.000 title claims description 9
- 239000011504 laterite Substances 0.000 title claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 199
- 229910052759 nickel Inorganic materials 0.000 claims description 97
- 238000002386 leaching Methods 0.000 claims description 45
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 43
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 31
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 31
- 239000001099 ammonium carbonate Substances 0.000 claims description 31
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 28
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 28
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 24
- 239000002244 precipitate Substances 0.000 claims description 23
- 229910021529 ammonia Inorganic materials 0.000 claims description 21
- 238000009835 boiling Methods 0.000 claims description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 13
- 239000001569 carbon dioxide Substances 0.000 claims description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- QBDILLPJCWWCEZ-UHFFFAOYSA-K S(=O)(=O)([O-])[O-].[NH4+].S(=O)(=O)([O-])[O-].[Ni+3] Chemical compound S(=O)(=O)([O-])[O-].[NH4+].S(=O)(=O)([O-])[O-].[Ni+3] QBDILLPJCWWCEZ-UHFFFAOYSA-K 0.000 claims description 5
- 150000003463 sulfur Chemical class 0.000 claims description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
- 239000001166 ammonium sulphate Substances 0.000 claims description 4
- 230000029087 digestion Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 3
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 description 102
- 239000000047 product Substances 0.000 description 10
- 230000009467 reduction Effects 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 5
- 238000005137 deposition process Methods 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- NVIVJPRCKQTWLY-UHFFFAOYSA-N cobalt nickel Chemical compound [Co][Ni][Co] NVIVJPRCKQTWLY-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- DKWADZDKFNWNNT-UHFFFAOYSA-N diazanium hydrogen carbonate hydrogen sulfate Chemical compound [NH4+].[NH4+].[O-]C([O-])=O.OS(O)(=O)=O DKWADZDKFNWNNT-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000080590 Niso Species 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- FWXMDRDFMGXWOB-UHFFFAOYSA-M C([O-])([O-])=O.[NH4+].[Co+] Chemical group C([O-])([O-])=O.[NH4+].[Co+] FWXMDRDFMGXWOB-UHFFFAOYSA-M 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910020598 Co Fe Inorganic materials 0.000 description 1
- -1 Cobalt amine sulfates Chemical class 0.000 description 1
- 229910017709 Ni Co Inorganic materials 0.000 description 1
- 206010035148 Plague Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- MCNTVOFOCCAUQI-UHFFFAOYSA-M [NH4+].C([O-])([O-])=O.[Ni+] Chemical compound [NH4+].C([O-])([O-])=O.[Ni+] MCNTVOFOCCAUQI-UHFFFAOYSA-M 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- ZRUWFKRETRELPY-UHFFFAOYSA-N azane;nickel(2+) Chemical compound N.[Ni+2] ZRUWFKRETRELPY-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0446—Leaching processes with an ammoniacal liquor or with a hydroxide of an alkali or alkaline-earth metal
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0476—Separation of nickel from cobalt
- C22B23/0492—Separation of nickel from cobalt in ammoniacal type solutions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21538772A | 1972-01-04 | 1972-01-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2300172A1 true DE2300172A1 (de) | 1973-07-26 |
Family
ID=22802791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2300172A Pending DE2300172A1 (de) | 1972-01-04 | 1973-01-03 | Verfahren zur extraktion von nickel und kobalt aus oxydischen nickel- und kobalthaltigen laterit- und garnieriterzen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3767762A (OSRAM) |
| JP (1) | JPS5617418B2 (OSRAM) |
| AU (1) | AU458059B2 (OSRAM) |
| BR (1) | BR7300047D0 (OSRAM) |
| CA (1) | CA980129A (OSRAM) |
| DE (1) | DE2300172A1 (OSRAM) |
| FR (1) | FR2167653B1 (OSRAM) |
| GB (1) | GB1386921A (OSRAM) |
| OA (1) | OA04311A (OSRAM) |
| ZA (1) | ZA7317B (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114604910A (zh) * | 2022-03-15 | 2022-06-10 | 重庆大学 | 一种镁、镍溶液矿化co2同时得到碳酸镍的方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3929468A (en) * | 1975-01-02 | 1975-12-30 | Us Interior | Process for recovery of non-ferrous metals from oxide ores and concentrates |
| AU562406B2 (en) * | 1982-09-24 | 1987-06-11 | Chevron Research Company | Recovering metal values from spent catalysts |
| US4432953A (en) * | 1982-09-24 | 1984-02-21 | Chevron Research Company | Leaching cobalt from spent hydroprocessing catalysts with sulfur dioxide |
| FR2536088B1 (fr) * | 1982-09-24 | 1987-11-20 | Chevron Res | Procede pour recuperer des metaux de catalyseurs uses d'hydrotraitement |
| US5650057A (en) * | 1993-07-29 | 1997-07-22 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US6048506A (en) * | 1993-10-29 | 2000-04-11 | Queensland Nickel Pty. Ltd. | Process for the removal of cationic impurities from a cobalt sulphate solution |
| CA2134490C (en) * | 1993-10-29 | 2000-05-23 | John E. Fittock | Process for the preparation of a high purity cobalt intermediate |
| US6231823B1 (en) | 2000-03-27 | 2001-05-15 | Dynatec Corporation | Solvent extraction process for the separation of cobalt from nickel in aqueous sulphate-containing solutions |
| AUPR917701A0 (en) * | 2001-11-29 | 2001-12-20 | QNI Technology Limited | Integrated ammoniacal solvent extraction and hydrogen reduction of nickel |
| JP6099601B2 (ja) | 2014-02-17 | 2017-03-22 | 国立大学法人高知大学 | ニッケル粉の製造方法 |
| CN113666437B (zh) * | 2021-07-15 | 2022-11-15 | 广东邦普循环科技有限公司 | 由镍铁铜合金制备硫酸镍的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2767055A (en) * | 1953-12-23 | 1956-10-16 | Chemical Construction Corp | Cobaltic pentammine sulfate separation |
| US2777753A (en) * | 1956-06-15 | 1957-01-15 | American Cyanamid Co | Separation of cobalt from nickel |
-
1972
- 1972-01-04 US US3767762D patent/US3767762A/en not_active Expired - Lifetime
- 1972-04-07 CA CA139,119A patent/CA980129A/en not_active Expired
- 1972-12-29 JP JP418973A patent/JPS5617418B2/ja not_active Expired
-
1973
- 1973-01-01 GB GB8173A patent/GB1386921A/en not_active Expired
- 1973-01-02 ZA ZA730017A patent/ZA7317B/xx unknown
- 1973-01-03 BR BR4773A patent/BR7300047D0/pt unknown
- 1973-01-03 FR FR7300174A patent/FR2167653B1/fr not_active Expired
- 1973-01-03 DE DE2300172A patent/DE2300172A1/de active Pending
- 1973-01-04 AU AU50750/73A patent/AU458059B2/en not_active Expired
- 1973-01-04 OA OA54802A patent/OA04311A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114604910A (zh) * | 2022-03-15 | 2022-06-10 | 重庆大学 | 一种镁、镍溶液矿化co2同时得到碳酸镍的方法 |
| CN114604910B (zh) * | 2022-03-15 | 2023-10-13 | 重庆大学 | 一种镁、镍溶液矿化co2同时得到碳酸镍的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU5075073A (en) | 1974-08-15 |
| JPS4885416A (OSRAM) | 1973-11-13 |
| BR7300047D0 (pt) | 1973-09-18 |
| ZA7317B (en) | 1973-09-26 |
| CA980129A (en) | 1975-12-23 |
| US3767762A (en) | 1973-10-23 |
| AU458059B2 (en) | 1975-02-20 |
| GB1386921A (en) | 1975-03-12 |
| FR2167653A1 (OSRAM) | 1973-08-24 |
| JPS5617418B2 (OSRAM) | 1981-04-22 |
| FR2167653B1 (OSRAM) | 1978-05-26 |
| OA04311A (fr) | 1980-01-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHJ | Non-payment of the annual fee |