DE2246753B2 - Galvanisches Element mit sich verbrauchender Zinkelektrode - Google Patents
Galvanisches Element mit sich verbrauchender ZinkelektrodeInfo
- Publication number
- DE2246753B2 DE2246753B2 DE2246753A DE2246753A DE2246753B2 DE 2246753 B2 DE2246753 B2 DE 2246753B2 DE 2246753 A DE2246753 A DE 2246753A DE 2246753 A DE2246753 A DE 2246753A DE 2246753 B2 DE2246753 B2 DE 2246753B2
- Authority
- DE
- Germany
- Prior art keywords
- mercury
- zinc
- ethylene oxide
- elements
- polyethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 26
- 229910052725 zinc Inorganic materials 0.000 title claims description 23
- 239000011701 zinc Substances 0.000 title claims description 23
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 29
- 229910052753 mercury Inorganic materials 0.000 claims description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 22
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 17
- 239000003792 electrolyte Substances 0.000 claims description 13
- 229920001223 polyethylene glycol Polymers 0.000 claims description 13
- 239000002202 Polyethylene glycol Substances 0.000 claims description 11
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 8
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- SZKTYYIADWRVSA-UHFFFAOYSA-N zinc manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[Mn++].[Zn++] SZKTYYIADWRVSA-UHFFFAOYSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229940008718 metallic mercury Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18586471A | 1971-10-01 | 1971-10-01 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2246753A1 DE2246753A1 (de) | 1973-04-19 |
| DE2246753B2 true DE2246753B2 (de) | 1979-10-11 |
| DE2246753C3 DE2246753C3 (enrdf_load_stackoverflow) | 1980-06-26 |
Family
ID=22682740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2246753A Granted DE2246753B2 (de) | 1971-10-01 | 1972-09-23 | Galvanisches Element mit sich verbrauchender Zinkelektrode |
Country Status (15)
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT966734B (it) * | 1972-07-24 | 1974-02-20 | Minnesota Mining & Mfg | Metodo per ridurre la caricabilita statica di strati fotografici e di elementi fotografici strati fotografici ed elementi fotografici ottenuti con tale metodo |
| JPS5623141B2 (enrdf_load_stackoverflow) * | 1974-06-17 | 1981-05-29 | ||
| JPS5810738B2 (ja) * | 1975-05-02 | 1983-02-26 | 富士写真フイルム株式会社 | 油溶性写真用添加剤をゼラチン水溶液中に分散する方法 |
| US4195120A (en) * | 1978-11-03 | 1980-03-25 | P. R. Mallory & Co. Inc. | Hydrogen evolution inhibitors for cells having zinc anodes |
| US4455358A (en) * | 1979-12-26 | 1984-06-19 | Duracell Inc. | Electrochemical cells having a gelled anode-electrolyte mixture |
| US4288913A (en) * | 1979-12-26 | 1981-09-15 | Duracell International Inc. | Method of forming in situ gelled anode |
| US4508764A (en) * | 1982-12-14 | 1985-04-02 | E. I. Du Pont De Nemours And Company | Coating process employs surfactants |
| FR2567328B1 (fr) * | 1984-07-04 | 1986-07-11 | Wonder | Procede de stabilisation des generateurs electrochimiques primaires a anodes reactives en zinc, aluminium ou magnesium et anode pour un tel generateur stabilisee par ce procede |
| US4582781A (en) * | 1984-08-01 | 1986-04-15 | Eastman Kodak Company | Antistatic compositions comprising polymerized oxyalkylene monomers and an inorganic tetrafluoroborate, perfluoroalkyl carboxylate, hexafluorophosphate or perfluoroalkylsulfonate salt |
| IE57432B1 (en) * | 1985-02-12 | 1992-09-09 | Duracell Int | Cell corrosion reduction |
| DE3782351T2 (de) | 1986-03-25 | 1993-05-27 | Konishiroku Photo Ind | Lichtempfindliches photographisches silberhalogenidmaterial, das fuer schnelle entwicklung verwendbar ist. |
| JPH0777131B2 (ja) * | 1987-04-02 | 1995-08-16 | 松下電器産業株式会社 | 亜鉛アルカリ電池 |
| US5626988A (en) * | 1994-05-06 | 1997-05-06 | Battery Technologies Inc. | Sealed rechargeable cells containing mercury-free zinc anodes, and a method of manufacture |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2900434A (en) * | 1956-01-03 | 1959-08-18 | Union Carbide Corp | Corrosion inhibitors |
-
0
- BE BE789556D patent/BE789556A/xx not_active IP Right Cessation
-
1972
- 1972-08-17 CA CA149,600A patent/CA983102A/en not_active Expired
- 1972-09-23 DE DE2246753A patent/DE2246753B2/de active Granted
- 1972-09-28 AU AU47183/72A patent/AU459895B2/en not_active Expired
- 1972-09-28 DK DK480472AA patent/DK140537B/da not_active IP Right Cessation
- 1972-09-29 SE SE7212636A patent/SE404463B/xx unknown
- 1972-09-29 JP JP47097250A patent/JPS527810B2/ja not_active Expired
- 1972-09-29 BR BR006767/72A patent/BR7206767D0/pt unknown
- 1972-09-29 FR FR7234577A patent/FR2156662B1/fr not_active Expired
- 1972-09-29 NL NL7213234A patent/NL7213234A/xx unknown
- 1972-09-29 ZA ZA726663A patent/ZA726663B/xx unknown
- 1972-09-29 GB GB4495572A patent/GB1378584A/en not_active Expired
- 1972-09-30 OA OA54708A patent/OA04189A/xx unknown
-
1975
- 1975-11-25 KE KE2583*UA patent/KE2583A/xx unknown
- 1975-12-30 MY MY283/75A patent/MY7500283A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR7206767D0 (pt) | 1973-08-30 |
| JPS527810B2 (enrdf_load_stackoverflow) | 1977-03-04 |
| FR2156662B1 (enrdf_load_stackoverflow) | 1976-08-13 |
| KE2583A (en) | 1975-12-11 |
| BE789556A (fr) | 1973-03-29 |
| OA04189A (fr) | 1979-12-31 |
| CA983102A (en) | 1976-02-03 |
| DE2246753C3 (enrdf_load_stackoverflow) | 1980-06-26 |
| ZA726663B (en) | 1973-06-27 |
| GB1378584A (en) | 1974-12-27 |
| JPS4843130A (enrdf_load_stackoverflow) | 1973-06-22 |
| FR2156662A1 (enrdf_load_stackoverflow) | 1973-06-01 |
| MY7500283A (en) | 1975-12-31 |
| AU459895B2 (en) | 1975-04-10 |
| SE404463B (sv) | 1978-10-02 |
| DE2246753A1 (de) | 1973-04-19 |
| NL7213234A (enrdf_load_stackoverflow) | 1973-04-03 |
| DK140537B (da) | 1979-09-24 |
| AU4718372A (en) | 1974-04-04 |
| DK140537C (enrdf_load_stackoverflow) | 1980-02-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: EVEREADY BATTERY CO. INC., ST. LOUIS, MO., US |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: FUCHS, J., DR.-ING. DIPL.-ING. B.COM. LUDERSCHMIDT, W., DIPL.-CHEM. DR.PHIL.NAT., PAT.-ANWAELTE, 6200 WIESBADEN |