DE2244462C3 - In Wasser stabile Titanchelate - Google Patents
In Wasser stabile TitanchelateInfo
- Publication number
- DE2244462C3 DE2244462C3 DE2244462A DE2244462A DE2244462C3 DE 2244462 C3 DE2244462 C3 DE 2244462C3 DE 2244462 A DE2244462 A DE 2244462A DE 2244462 A DE2244462 A DE 2244462A DE 2244462 C3 DE2244462 C3 DE 2244462C3
- Authority
- DE
- Germany
- Prior art keywords
- titanium
- parts
- chelate
- color
- glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010936 titanium Substances 0.000 title claims description 34
- 229910052719 titanium Inorganic materials 0.000 title claims description 32
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 38
- 239000013522 chelant Substances 0.000 claims description 28
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 13
- -1 titanium orthoesters Chemical class 0.000 claims description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 8
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 6
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 4
- 229940043276 diisopropanolamine Drugs 0.000 claims description 4
- 229940051250 hexylene glycol Drugs 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- HQPMKSGTIOYHJT-UHFFFAOYSA-N ethane-1,2-diol;propane-1,2-diol Chemical compound OCCO.CC(O)CO HQPMKSGTIOYHJT-UHFFFAOYSA-N 0.000 claims 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 28
- 239000000499 gel Substances 0.000 description 23
- 239000000839 emulsion Substances 0.000 description 16
- 239000003973 paint Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 10
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000003349 gelling agent Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 230000009974 thixotropic effect Effects 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 240000002129 Malva sylvestris Species 0.000 description 4
- 235000006770 Malva sylvestris Nutrition 0.000 description 4
- 235000013351 cheese Nutrition 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- IHEDBVUTTQXGSJ-UHFFFAOYSA-M 2-[bis(2-oxidoethyl)amino]ethanolate;titanium(4+);hydroxide Chemical compound [OH-].[Ti+4].[O-]CCN(CC[O-])CC[O-] IHEDBVUTTQXGSJ-UHFFFAOYSA-M 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 229960004063 propylene glycol Drugs 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004146 Propane-1,2-diol Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229940093476 ethylene glycol Drugs 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/04—Thixotropic paints
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5003871A GB1362054A (en) | 1971-10-28 | 1971-10-28 | Aqueous emulsion paints |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2244462A1 DE2244462A1 (de) | 1973-05-03 |
| DE2244462B2 DE2244462B2 (de) | 1980-09-11 |
| DE2244462C3 true DE2244462C3 (de) | 1983-05-19 |
Family
ID=10454418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2244462A Expired DE2244462C3 (de) | 1971-10-28 | 1972-09-11 | In Wasser stabile Titanchelate |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3892791A (enExample) |
| CA (1) | CA971181A (enExample) |
| DE (1) | DE2244462C3 (enExample) |
| FR (1) | FR2157814B1 (enExample) |
| GB (1) | GB1362054A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3737047A1 (de) * | 1987-10-31 | 1989-05-11 | Huels Troisdorf | Zubereitung auf basis von titan-chelaten von diolen und von titanacylaten |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2620189C3 (de) | 1976-05-07 | 1980-06-12 | Hoechst Ag, 6000 Frankfurt | Thixotrope Mischung |
| GB1588521A (en) * | 1977-02-08 | 1981-04-23 | Manchem Ltd | Metal complexes |
| US4159209A (en) * | 1978-02-09 | 1979-06-26 | Manchem Limited | Metal complexes |
| US4438039A (en) | 1980-07-02 | 1984-03-20 | General Electric Company | Titanium chelate catalyst for silicone compositions |
| DE3337098A1 (de) * | 1983-10-12 | 1985-05-02 | Dynamit Nobel Ag, 5210 Troisdorf | Neue titanchelate und zubereitungen, die diese chelate enthalten |
| DE3337099A1 (de) * | 1983-10-12 | 1985-05-02 | Dynamit Nobel Ag, 5210 Troisdorf | Wasserloesliche triethanolamintitanate |
| EP0144135B1 (en) * | 1983-11-02 | 1992-03-18 | Imperial Chemical Industries Plc | Lidded paint container containing aqueous solid paint |
| JPH01501068A (ja) * | 1986-10-03 | 1989-04-13 | ヒユツテネス―アルベルトス ヘーミツシエ ヴエルケ ゲーエムベーハー | チキソトロープコーチング剤用増粘剤 |
| GB8717667D0 (en) * | 1987-07-25 | 1987-09-03 | Tioxide Group Plc | Titanium compounds |
| US4788172A (en) * | 1987-07-27 | 1988-11-29 | Deardorff Donald L | Titanium compounds |
| GB9116267D0 (en) * | 1991-07-27 | 1991-09-11 | Tioxide Chemicals Limited | Aqueous compositions |
| AT400438B (de) * | 1993-08-27 | 1995-12-27 | Vianova Kunstharz Ag | Verfahren zur herstellung von organischen titanverbindungen und deren verwendung in kathodisch abscheidbaren elektrotauchlacken |
| US5474964A (en) * | 1994-09-16 | 1995-12-12 | Phillips Petroleum Company | Hydrocarbon isomerization catalyst and use thereof |
| US5710086A (en) * | 1996-03-20 | 1998-01-20 | General Electric Company | Titanate catalysts |
| JP4550368B2 (ja) * | 2003-02-25 | 2010-09-22 | マツモトファインケミカル株式会社 | 水性チタン組成物 |
| DE102018004944A1 (de) | 2018-06-22 | 2019-12-24 | Brillux Gmbh & Co. Kg | Dispersionsfarbe |
| GB202402835D0 (en) * | 2024-02-28 | 2024-04-10 | Catalytic Tech Ltd | Titanium complexes, methods of preparation and uses thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2643262A (en) * | 1950-04-28 | 1953-06-23 | Du Pont | Organic compounds of titanium |
| GB755728A (en) * | 1952-06-05 | 1956-08-29 | Nat Lead Co | Improvements in or relating to organic titanium and zirconium compounds |
| US2824114A (en) * | 1952-09-09 | 1958-02-18 | Du Pont | Water soluble group iv-a metal esters of amino alcohols and their preparation |
| US2920089A (en) * | 1955-07-14 | 1960-01-05 | Kendall & Co | Organo-metallic titanium compounds and method of making the same |
| US2950174A (en) * | 1956-04-05 | 1960-08-23 | Lagally Paul | Preparation and stabilization of water soluble reactive titanium derivatives |
| US2894966A (en) * | 1956-07-10 | 1959-07-14 | Nat Lead Co | Process for the preparation of stabilized organotitanium compounds |
| GB1244232A (en) * | 1969-03-18 | 1971-08-25 | British Titan Ltd | Improvements in and relating to titanium chelates |
| GB1244233A (en) * | 1969-03-18 | 1971-08-25 | British Titan Ltd | Improvements in and relating to titanium chelates |
-
1971
- 1971-10-28 GB GB5003871A patent/GB1362054A/en not_active Expired
-
1972
- 1972-09-11 DE DE2244462A patent/DE2244462C3/de not_active Expired
- 1972-09-13 CA CA151,562A patent/CA971181A/en not_active Expired
- 1972-09-25 US US291668A patent/US3892791A/en not_active Expired - Lifetime
- 1972-09-28 FR FR7234414A patent/FR2157814B1/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3737047A1 (de) * | 1987-10-31 | 1989-05-11 | Huels Troisdorf | Zubereitung auf basis von titan-chelaten von diolen und von titanacylaten |
Also Published As
| Publication number | Publication date |
|---|---|
| US3892791A (en) | 1975-07-01 |
| CA971181A (en) | 1975-07-15 |
| DE2244462A1 (de) | 1973-05-03 |
| DE2244462B2 (de) | 1980-09-11 |
| FR2157814B1 (enExample) | 1978-03-10 |
| GB1362054A (en) | 1974-07-30 |
| FR2157814A1 (enExample) | 1973-06-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8263 | Opposition against grant of a patent | ||
| 8381 | Inventor (new situation) |
Free format text: BROOK, DAVID WHITELEY, MIDDLESBROUGH, TESSIDE, GB KAY, PETER DUNLOP, HARTLEPOOL, DURHAM, GB |
|
| C3 | Grant after two publication steps (3rd publication) |