DE2244181C2 - Chromatographische Elemente zur Dünnschichtchromatographie und Verfahren zu ihrer Herstellung - Google Patents
Chromatographische Elemente zur Dünnschichtchromatographie und Verfahren zu ihrer HerstellungInfo
- Publication number
- DE2244181C2 DE2244181C2 DE2244181A DE2244181A DE2244181C2 DE 2244181 C2 DE2244181 C2 DE 2244181C2 DE 2244181 A DE2244181 A DE 2244181A DE 2244181 A DE2244181 A DE 2244181A DE 2244181 C2 DE2244181 C2 DE 2244181C2
- Authority
- DE
- Germany
- Prior art keywords
- adsorbent
- glass
- thin
- glass powder
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004809 thin layer chromatography Methods 0.000 title claims description 10
- 238000000034 method Methods 0.000 title description 26
- 239000011521 glass Substances 0.000 claims description 36
- 239000003463 adsorbent Substances 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000010453 quartz Substances 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 238000004458 analytical method Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 239000002904 solvent Substances 0.000 description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 238000010304 firing Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920002401 polyacrylamide Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000007173 Abies balsamea Nutrition 0.000 description 2
- 244000283070 Abies balsamea Species 0.000 description 2
- 239000004858 Canada balsam Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 2
- 229940081735 acetylcellulose Drugs 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000001030 gas--liquid chromatography Methods 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229940079938 nitrocellulose Drugs 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000012800 visualization Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002196 Pyroceram Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005264 electron capture Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011507 gypsum plaster Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229940126601 medicinal product Drugs 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000005373 porous glass Substances 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000001612 separation test Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/90—Plate chromatography, e.g. thin layer or paper chromatography
- G01N30/92—Construction of the plate
- G01N30/93—Application of the sorbent layer
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/50—Conditioning of the sorbent material or stationary liquid
- G01N30/52—Physical parameters
- G01N2030/524—Physical parameters structural properties
- G01N2030/528—Monolithic sorbent material
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP46069416A JPS5235320B2 (OSRAM) | 1971-09-08 | 1971-09-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2244181A1 DE2244181A1 (de) | 1973-03-15 |
| DE2244181C2 true DE2244181C2 (de) | 1986-07-24 |
Family
ID=13401968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2244181A Expired DE2244181C2 (de) | 1971-09-08 | 1972-09-08 | Chromatographische Elemente zur Dünnschichtchromatographie und Verfahren zu ihrer Herstellung |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3839205A (OSRAM) |
| JP (1) | JPS5235320B2 (OSRAM) |
| AU (1) | AU473915B2 (OSRAM) |
| CA (1) | CA971484A (OSRAM) |
| CH (1) | CH549215A (OSRAM) |
| DE (1) | DE2244181C2 (OSRAM) |
| FR (1) | FR2152142A5 (OSRAM) |
| GB (1) | GB1390258A (OSRAM) |
| IT (1) | IT964973B (OSRAM) |
| NL (1) | NL7212222A (OSRAM) |
| SE (1) | SE406810B (OSRAM) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5410420Y2 (OSRAM) * | 1973-11-28 | 1979-05-15 | ||
| JPS5296119U (OSRAM) * | 1976-01-14 | 1977-07-19 | ||
| JPS551532A (en) * | 1978-06-21 | 1980-01-08 | Hitachi Ltd | Fuel storage rack |
| US4261835A (en) * | 1979-04-27 | 1981-04-14 | Creeger Samuel M | Thin layer and paper chromatography cones |
| US4508624A (en) * | 1980-09-29 | 1985-04-02 | Kyoto Ceramic Co., Ltd. | Ceramic body for chromatography and process for preparation thereof |
| USH896H (en) | 1983-05-31 | 1991-03-05 | Shell Oil Company | Separating column for gas chromatography |
| JPS6042653A (ja) * | 1983-08-17 | 1985-03-06 | Shionogi & Co Ltd | クロマトグラフィ−・プレ−ト |
| JPS61210956A (ja) * | 1985-03-15 | 1986-09-19 | Cosmo Co Ltd | クロマトグラフイ−用薄層棒 |
| DE19627924C2 (de) * | 1996-06-21 | 2003-02-20 | Michael Kuehn | Verfahren und Mischung zur Herstellung eines selbsttragenden Werkstoffs sowie Werkstoff |
| US5811665A (en) * | 1996-09-11 | 1998-09-22 | Alanex Corporation | Large scale sorption-driven solid state chromatography |
| US20070235389A1 (en) * | 2006-04-10 | 2007-10-11 | Boyes Barry E | Metal-coated superficially porous supports as a medium for HPLC of phosphorus-containing materials |
| CN112748212B (zh) * | 2019-10-31 | 2024-06-07 | 中国石油化工股份有限公司 | 一种色谱棒制备容器及色谱棒制备方法 |
| CN111380994B (zh) * | 2020-05-15 | 2023-02-28 | 淄博山分分析仪器有限公司 | 一种棒状薄层色谱用色谱棒的制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3005514A (en) * | 1959-04-20 | 1961-10-24 | Cons Electrodynamics Corp | Fluid treating columns |
| DE1926465U (de) * | 1965-02-27 | 1965-11-04 | Peter Dr Pogacar | Geraet zur chromatographischen und elektrophoretischen trennung geloester stoffgemische zu analytischen, praeparativen oder diagnostischen zwecken. |
| US3418152A (en) * | 1966-08-01 | 1968-12-24 | Eastman Kodak Co | Method of making a chromatographic element containing a resinous binder and product produced thereby |
| CA941314A (en) * | 1970-02-13 | 1974-02-05 | Shionogi And Co. Ltd. | Sintered chromatographic plate and method for producing same |
-
1971
- 1971-09-08 JP JP46069416A patent/JPS5235320B2/ja not_active Expired
-
1972
- 1972-08-21 GB GB3895772A patent/GB1390258A/en not_active Expired
- 1972-08-22 IT IT69693/72A patent/IT964973B/it active
- 1972-09-06 FR FR7231563A patent/FR2152142A5/fr not_active Expired
- 1972-09-06 SE SE7211481A patent/SE406810B/sv unknown
- 1972-09-07 CA CA151,118A patent/CA971484A/en not_active Expired
- 1972-09-07 CH CH1315072A patent/CH549215A/xx not_active IP Right Cessation
- 1972-09-07 US US00287036A patent/US3839205A/en not_active Expired - Lifetime
- 1972-09-08 DE DE2244181A patent/DE2244181C2/de not_active Expired
- 1972-09-08 NL NL7212222A patent/NL7212222A/xx unknown
- 1972-09-08 AU AU46491/72A patent/AU473915B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH549215A (de) | 1974-05-15 |
| GB1390258A (en) | 1975-04-09 |
| AU473915B2 (en) | 1976-07-08 |
| FR2152142A5 (OSRAM) | 1973-04-20 |
| JPS5235320B2 (OSRAM) | 1977-09-08 |
| CA971484A (en) | 1975-07-22 |
| US3839205A (en) | 1974-10-01 |
| DE2244181A1 (de) | 1973-03-15 |
| NL7212222A (OSRAM) | 1973-03-12 |
| JPS4835891A (OSRAM) | 1973-05-26 |
| SE406810B (sv) | 1979-02-26 |
| IT964973B (it) | 1974-01-31 |
| AU4649172A (en) | 1974-03-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |