DE2239356A1 - Styrolpolymerisate mit verbesserter fliessfaehigkeit - Google Patents
Styrolpolymerisate mit verbesserter fliessfaehigkeitInfo
- Publication number
- DE2239356A1 DE2239356A1 DE19722239356 DE2239356A DE2239356A1 DE 2239356 A1 DE2239356 A1 DE 2239356A1 DE 19722239356 DE19722239356 DE 19722239356 DE 2239356 A DE2239356 A DE 2239356A DE 2239356 A1 DE2239356 A1 DE 2239356A1
- Authority
- DE
- Germany
- Prior art keywords
- styrene
- molecular weight
- polymerization
- lubricant
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 60
- 229920000642 polymer Polymers 0.000 claims description 15
- 238000005984 hydrogenation reaction Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 238000009757 thermoplastic moulding Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000314 lubricant Substances 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 13
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000000178 monomer Substances 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 150000003440 styrenes Chemical class 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000007868 Raney catalyst Substances 0.000 description 2
- 229910000564 Raney nickel Inorganic materials 0.000 description 2
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229920006222 acrylic ester polymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229940067592 ethyl palmitate Drugs 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 230000008542 thermal sensitivity Effects 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722239356 DE2239356A1 (de) | 1972-08-10 | 1972-08-10 | Styrolpolymerisate mit verbesserter fliessfaehigkeit |
| NL7310843A NL7310843A (enExample) | 1972-08-10 | 1973-08-06 | |
| FR7329018A FR2195642A1 (en) | 1972-08-10 | 1973-08-08 | Lubricated thermoplastic styrene polymer - contg hydrogenated styrene oligomer |
| BE134358A BE803358A (fr) | 1972-08-10 | 1973-08-08 | Polymere du styrene a fluidite amelioree |
| JP8936173A JPS4975660A (enExample) | 1972-08-10 | 1973-08-10 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722239356 DE2239356A1 (de) | 1972-08-10 | 1972-08-10 | Styrolpolymerisate mit verbesserter fliessfaehigkeit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2239356A1 true DE2239356A1 (de) | 1974-02-21 |
Family
ID=5853222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722239356 Pending DE2239356A1 (de) | 1972-08-10 | 1972-08-10 | Styrolpolymerisate mit verbesserter fliessfaehigkeit |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS4975660A (enExample) |
| BE (1) | BE803358A (enExample) |
| DE (1) | DE2239356A1 (enExample) |
| FR (1) | FR2195642A1 (enExample) |
| NL (1) | NL7310843A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999050347A1 (en) * | 1998-03-28 | 1999-10-07 | Safeglass (Europe) Limited | Safety glass |
| WO2000014157A1 (en) * | 1998-09-09 | 2000-03-16 | The Dow Chemical Company | Monovinylidene aromatic resins |
| WO2001072895A1 (de) * | 2000-03-24 | 2001-10-04 | Bayer Aktiengesellschaft | Thermoplastische polyvinylcyclohexan-formmassen mit verbesserten eigenschaften |
| WO2005026256A1 (en) * | 2003-09-11 | 2005-03-24 | Safeglass (Europe) Limited | Glass like material with improved safety characteristics |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2013003571A (es) * | 2010-10-01 | 2013-08-29 | Basf Se | Oligomeros (met)acrilicos estirenicos. |
| JP7122957B2 (ja) * | 2018-12-21 | 2022-08-22 | ヤスハラケミカル株式会社 | 繊維強化熱可塑性樹脂組成物、およびそれから得られる成形体 |
-
1972
- 1972-08-10 DE DE19722239356 patent/DE2239356A1/de active Pending
-
1973
- 1973-08-06 NL NL7310843A patent/NL7310843A/xx unknown
- 1973-08-08 FR FR7329018A patent/FR2195642A1/fr not_active Withdrawn
- 1973-08-08 BE BE134358A patent/BE803358A/xx unknown
- 1973-08-10 JP JP8936173A patent/JPS4975660A/ja active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999050347A1 (en) * | 1998-03-28 | 1999-10-07 | Safeglass (Europe) Limited | Safety glass |
| WO2000014157A1 (en) * | 1998-09-09 | 2000-03-16 | The Dow Chemical Company | Monovinylidene aromatic resins |
| WO2001072895A1 (de) * | 2000-03-24 | 2001-10-04 | Bayer Aktiengesellschaft | Thermoplastische polyvinylcyclohexan-formmassen mit verbesserten eigenschaften |
| WO2005026256A1 (en) * | 2003-09-11 | 2005-03-24 | Safeglass (Europe) Limited | Glass like material with improved safety characteristics |
| GB2411898A (en) * | 2003-09-11 | 2005-09-14 | Safeglass | Glass like material with improved safety characteristics |
| GB2411898B (en) * | 2003-09-11 | 2008-03-26 | Safeglass | Glass like material with improved safety characteristics |
Also Published As
| Publication number | Publication date |
|---|---|
| BE803358A (fr) | 1974-02-08 |
| NL7310843A (enExample) | 1974-02-12 |
| JPS4975660A (enExample) | 1974-07-22 |
| FR2195642A1 (en) | 1974-03-08 |
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