DE2233143C3 - Thermoplastische Formmassen auf Poly(oxymethylen)-Basis - Google Patents
Thermoplastische Formmassen auf Poly(oxymethylen)-BasisInfo
- Publication number
- DE2233143C3 DE2233143C3 DE2233143A DE2233143A DE2233143C3 DE 2233143 C3 DE2233143 C3 DE 2233143C3 DE 2233143 A DE2233143 A DE 2233143A DE 2233143 A DE2233143 A DE 2233143A DE 2233143 C3 DE2233143 C3 DE 2233143C3
- Authority
- DE
- Germany
- Prior art keywords
- trioxane
- weight
- copolymer
- poly
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920006324 polyoxymethylene Polymers 0.000 title claims description 36
- 150000001875 compounds Chemical class 0.000 title claims description 15
- 238000009757 thermoplastic moulding Methods 0.000 title claims description 5
- -1 trioxane Compound Chemical class 0.000 claims description 29
- 229920001577 copolymer Polymers 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 28
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 claims description 20
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 20
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 15
- 238000000465 moulding Methods 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 229920000728 polyester Polymers 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000002667 nucleating agent Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920001567 vinyl ester resin Polymers 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 229920005684 linear copolymer Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 description 28
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- 239000000155 melt Substances 0.000 description 7
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 210000003298 dental enamel Anatomy 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000007373 indentation Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 229930188620 butyrolactone Natural products 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- FPIGOBKNDYAZTP-UHFFFAOYSA-N 1,2-epoxy-3-(4-nitrophenoxy)propane Chemical compound C1=CC([N+](=O)[O-])=CC=C1OCC1OC1 FPIGOBKNDYAZTP-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- RVGLUKRYMXEQAH-UHFFFAOYSA-N 3,3-dimethyloxetane Chemical compound CC1(C)COC1 RVGLUKRYMXEQAH-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- VAKABUBSGYOQIM-UHFFFAOYSA-N 4-(oxiran-2-ylmethoxy)benzaldehyde Chemical compound C1=CC(C=O)=CC=C1OCC1OC1 VAKABUBSGYOQIM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical class [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000001976 hemiacetal group Chemical group 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- PELJISAVHGXLAL-UHFFFAOYSA-N iodomethyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OCI PELJISAVHGXLAL-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- HGWFYWSOANKCMB-UHFFFAOYSA-N methyl 3-[4-(oxiran-2-ylmethoxy)phenyl]prop-2-enoate Chemical compound C1=CC(C=CC(=O)OC)=CC=C1OCC1OC1 HGWFYWSOANKCMB-UHFFFAOYSA-N 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004557 technical material Substances 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
- C08L59/02—Polyacetals containing polyoxymethylene sequences only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Priority Applications (17)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL727200398A NL151421B (nl) | 1971-01-15 | 1972-01-11 | Werkwijze voor het bereiden van een thermoplastische vormmassa door een lineair polyoxymethyleen met een kiemvormingsmiddel te mengen. |
| DE2233143A DE2233143C3 (de) | 1972-07-06 | 1972-07-06 | Thermoplastische Formmassen auf Poly(oxymethylen)-Basis |
| NLAANVRAGE7309132,A NL171070C (nl) | 1971-01-15 | 1973-06-29 | Werkwijze voor het bereiden van een thermoplastisch vormmateriaal, alsmede uit dit vormmateriaal vervaardigde, gevormde voortbrengselen. |
| YU01826/73A YU182673A (en) | 1972-07-06 | 1973-07-03 | Process for preparing molding thermoplastic masses on the base of polyoxymethylene |
| CH971073A CH590895A5 (OSRAM) | 1972-07-06 | 1973-07-03 | |
| CA175,633A CA1002223A (en) | 1972-07-06 | 1973-07-04 | Thermoplastic moulding compositions based on poly(oxymethylene) |
| JP7493973A JPS5642623B2 (OSRAM) | 1972-07-06 | 1973-07-04 | |
| AU57675/73A AU474507B2 (en) | 1972-07-06 | 1973-07-04 | Thermoplastic moulding compounds based on poly(oxymethylene) |
| IT26213/73A IT1045373B (it) | 1972-07-06 | 1973-07-04 | Masse termoplastiche per formatura a base di poli ossimeti leni |
| AT592773A AT328187B (de) | 1972-07-06 | 1973-07-05 | Thermoplastische formmasse auf poly(oxymethylen)-basis |
| BR5023/73A BR7305023D0 (pt) | 1972-07-06 | 1973-07-05 | Massas de moldacao termoplasticas e processo para a obtencao das mesmas |
| ZA734553A ZA734553B (en) | 1972-07-06 | 1973-07-05 | Thermoplastic moulding compositions based on poly(oxymethylene) |
| SE7309468A SE406772B (sv) | 1972-07-06 | 1973-07-05 | Termoplastiska pressmassor pa poly(oximetylen)-basis samt forfarande for framstellning derav |
| BE133220A BE802031R (fr) | 1972-07-06 | 1973-07-06 | Matieres a mouler thermoplastiques |
| GB3241273A GB1431586A (en) | 1972-07-06 | 1973-07-06 | Thermoplastic moulding compositions based on poly -oxymethylene- |
| FR7324953A FR2192138B2 (OSRAM) | 1972-07-06 | 1973-07-06 | |
| US05/579,472 US3980734A (en) | 1972-07-06 | 1975-05-21 | Thermoplastic moulding compositions based on poly (oxymethylene) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2233143A DE2233143C3 (de) | 1972-07-06 | 1972-07-06 | Thermoplastische Formmassen auf Poly(oxymethylen)-Basis |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2233143A1 DE2233143A1 (de) | 1974-01-31 |
| DE2233143B2 DE2233143B2 (de) | 1980-01-24 |
| DE2233143C3 true DE2233143C3 (de) | 1980-09-18 |
Family
ID=5849847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2233143A Expired DE2233143C3 (de) | 1971-01-15 | 1972-07-06 | Thermoplastische Formmassen auf Poly(oxymethylen)-Basis |
Country Status (14)
| Country | Link |
|---|---|
| JP (1) | JPS5642623B2 (OSRAM) |
| AT (1) | AT328187B (OSRAM) |
| AU (1) | AU474507B2 (OSRAM) |
| BE (1) | BE802031R (OSRAM) |
| BR (1) | BR7305023D0 (OSRAM) |
| CA (1) | CA1002223A (OSRAM) |
| CH (1) | CH590895A5 (OSRAM) |
| DE (1) | DE2233143C3 (OSRAM) |
| FR (1) | FR2192138B2 (OSRAM) |
| GB (1) | GB1431586A (OSRAM) |
| IT (1) | IT1045373B (OSRAM) |
| SE (1) | SE406772B (OSRAM) |
| YU (1) | YU182673A (OSRAM) |
| ZA (1) | ZA734553B (OSRAM) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1603205A (en) | 1977-04-12 | 1981-11-18 | Raychem Ltd | Polymer compositions |
| DE2818240A1 (de) * | 1978-04-26 | 1979-11-08 | Hoechst Ag | Thermoplastische formmassen auf basis von polyoxymethylenen |
| GB2035335B (en) * | 1978-10-25 | 1983-01-19 | Asahi Chemical Ind | Polyacetal resin composition excellent in heat stability and surface processability and process for surface treating same |
| JP2743303B2 (ja) * | 1993-01-12 | 1998-04-22 | 旭化成工業株式会社 | ポリアセタール樹脂成形材料 |
| NL2000218C2 (nl) | 2006-09-07 | 2008-03-12 | Bravilor Holding Bv | Bereidingsinrichting. |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1252204A (OSRAM) * | 1968-06-10 | 1971-11-03 |
-
1972
- 1972-07-06 DE DE2233143A patent/DE2233143C3/de not_active Expired
-
1973
- 1973-07-03 CH CH971073A patent/CH590895A5/xx not_active IP Right Cessation
- 1973-07-03 YU YU01826/73A patent/YU182673A/xx unknown
- 1973-07-04 CA CA175,633A patent/CA1002223A/en not_active Expired
- 1973-07-04 AU AU57675/73A patent/AU474507B2/en not_active Expired
- 1973-07-04 JP JP7493973A patent/JPS5642623B2/ja not_active Expired
- 1973-07-04 IT IT26213/73A patent/IT1045373B/it active
- 1973-07-05 BR BR5023/73A patent/BR7305023D0/pt unknown
- 1973-07-05 SE SE7309468A patent/SE406772B/sv unknown
- 1973-07-05 ZA ZA734553A patent/ZA734553B/xx unknown
- 1973-07-05 AT AT592773A patent/AT328187B/de not_active IP Right Cessation
- 1973-07-06 FR FR7324953A patent/FR2192138B2/fr not_active Expired
- 1973-07-06 BE BE133220A patent/BE802031R/xx active
- 1973-07-06 GB GB3241273A patent/GB1431586A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AU5767573A (en) | 1975-01-09 |
| AU474507B2 (en) | 1976-07-22 |
| IT1045373B (it) | 1980-05-10 |
| JPS5642623B2 (OSRAM) | 1981-10-06 |
| YU182673A (en) | 1983-04-27 |
| JPS4958145A (OSRAM) | 1974-06-05 |
| ZA734553B (en) | 1974-06-26 |
| DE2233143B2 (de) | 1980-01-24 |
| SE406772B (sv) | 1979-02-26 |
| FR2192138A2 (OSRAM) | 1974-02-08 |
| BE802031R (fr) | 1974-01-07 |
| DE2233143A1 (de) | 1974-01-31 |
| FR2192138B2 (OSRAM) | 1978-10-06 |
| ATA592773A (de) | 1975-05-15 |
| CH590895A5 (OSRAM) | 1977-08-31 |
| CA1002223A (en) | 1976-12-21 |
| AT328187B (de) | 1976-03-10 |
| BR7305023D0 (pt) | 1974-09-05 |
| GB1431586A (en) | 1976-04-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3752169T2 (de) | Stabilisierte Polyacetalzubereitungen | |
| DE3037520C2 (OSRAM) | ||
| EP0153587B1 (de) | Elastomere thermoplastische Formmassen und deren Herstellung | |
| DE2330022C2 (de) | Thermoplastische Massen auf Basis von thermoplastischem Material, Olefinpolymerisat und einem reaktionsfähigen anorganischen Füllstoff | |
| DE2948615A1 (de) | Polymermassen auf basis von aromatischen alkenylharzen und deren verwendung zur herstellung von formteilen | |
| DE69023571T2 (de) | Polyoxymethylenmulticopolymer und abgeleitete Harzmischung. | |
| DE3105328A1 (de) | Thermoplastische styrolpolymermasse und ihre verwendung | |
| EP0061692B1 (de) | Antistatische thermoplastische Formmassen | |
| DE3421864A1 (de) | Thermoplastische formmassen auf der basis von polyoxymethylen und polymeren adipatcarbonatmischestern | |
| DE2233143C3 (de) | Thermoplastische Formmassen auf Poly(oxymethylen)-Basis | |
| DE2150038C3 (de) | Thermoplastische Formmassen auf Polyoxymethylenbasis | |
| EP0081144B1 (de) | Warmverformbares flächiges Halbzeug aus faserverstärktem Polyethylenterephthalat | |
| DE2425903C2 (de) | Verfahren zur Herstellung eines geformten Gegenstandes aus hydrolysiertem Äthylen-Vinylacetatmischpolymerisat | |
| DE3715117A1 (de) | Poly-ss-alanin-verbindung, verfahren zu ihrer herstellung und diese verbindung enthaltende polyacetalharz-zusammensetzung | |
| DE2108127C3 (de) | Formmassen auf Basis von PoIyphenylenoxid-Pfropfcopolymeren und ihre Verwendung zur Herstellung von Formkörpern | |
| DE2855512A1 (de) | Verbesserte ungefuellte thermoplastische formmassen | |
| DE2208168C3 (de) | Thermoplastische Formmasse auf Polyoxymethylen-Basis und Verfahren zu ihrer Herstellung | |
| EP0386597A2 (de) | Kunststoffmischungen | |
| DE69518711T2 (de) | Polyvinylalkohol enthaltende, schmelzverarbeitete Polymermischungen | |
| DE69413684T2 (de) | Formkörper aus polyesterharzen | |
| DE2037823C3 (de) | Thermoplastische Formmassen auf Polyoxymethylenbasis | |
| DE2645870C3 (de) | Stabilisierte Polyvinylchlorid-Formmassen | |
| AT295860B (de) | Polymermischung aus Polyäthylenterephthalat und Butadien-Styrol-Mischpolymerisat sowie Verfahren zu deren Herstellung | |
| DE2259564A1 (de) | Thermoplastische formmassen | |
| DE4227742A1 (de) | Thermoplastische Haftvermittlermischung |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |