DE2230310C3 - Verfahren zur Gewinnung von Äthylenoxid aus einem Reaktionsgemisch, das durch Umsetzung von Äthylen mit molekularem Sauerstoff hergestellt worden ist - Google Patents
Verfahren zur Gewinnung von Äthylenoxid aus einem Reaktionsgemisch, das durch Umsetzung von Äthylen mit molekularem Sauerstoff hergestellt worden istInfo
- Publication number
- DE2230310C3 DE2230310C3 DE2230310A DE2230310A DE2230310C3 DE 2230310 C3 DE2230310 C3 DE 2230310C3 DE 2230310 A DE2230310 A DE 2230310A DE 2230310 A DE2230310 A DE 2230310A DE 2230310 C3 DE2230310 C3 DE 2230310C3
- Authority
- DE
- Germany
- Prior art keywords
- ethylene oxide
- ethylene
- zone
- column
- pretreatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title claims description 86
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 30
- 239000005977 Ethylene Substances 0.000 title claims description 29
- 230000008569 process Effects 0.000 title claims description 12
- 239000011541 reaction mixture Substances 0.000 title claims description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 title claims description 4
- 229910001882 dioxygen Inorganic materials 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000926 separation method Methods 0.000 claims description 60
- 239000007788 liquid Substances 0.000 claims description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 24
- 230000009102 absorption Effects 0.000 claims description 24
- 238000010521 absorption reaction Methods 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 12
- 239000001569 carbon dioxide Substances 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 11
- 239000012535 impurity Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 238000009833 condensation Methods 0.000 claims description 9
- 230000005494 condensation Effects 0.000 claims description 9
- 238000007906 compression Methods 0.000 claims description 8
- 230000006835 compression Effects 0.000 claims description 8
- 238000011282 treatment Methods 0.000 claims description 8
- 239000012808 vapor phase Substances 0.000 claims description 8
- 239000012071 phase Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 230000009103 reabsorption Effects 0.000 claims description 5
- 238000010626 work up procedure Methods 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000006227 byproduct Substances 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 2
- 238000007086 side reaction Methods 0.000 claims 2
- 238000010790 dilution Methods 0.000 claims 1
- 239000012895 dilution Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 210000002784 stomach Anatomy 0.000 claims 1
- 229940093470 ethylene Drugs 0.000 description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 238000012545 processing Methods 0.000 description 9
- 238000001816 cooling Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 238000002203 pretreatment Methods 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
- 208000004998 Abdominal Pain Diseases 0.000 description 1
- 208000002881 Colic Diseases 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 210000003918 fraction a Anatomy 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 101150059999 pro gene Proteins 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- MBYLVOKEDDQJDY-UHFFFAOYSA-N tris(2-aminoethyl)amine Chemical compound NCCN(CCN)CCN MBYLVOKEDDQJDY-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/32—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Gas Separation By Absorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15595971A | 1971-06-23 | 1971-06-23 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2230310A1 DE2230310A1 (de) | 1972-12-28 |
| DE2230310B2 DE2230310B2 (enExample) | 1974-11-07 |
| DE2230310C3 true DE2230310C3 (de) | 1975-06-26 |
Family
ID=22557471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2230310A Expired DE2230310C3 (de) | 1971-06-23 | 1972-06-21 | Verfahren zur Gewinnung von Äthylenoxid aus einem Reaktionsgemisch, das durch Umsetzung von Äthylen mit molekularem Sauerstoff hergestellt worden ist |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3729899A (enExample) |
| AU (1) | AU458806B2 (enExample) |
| BE (1) | BE784830A (enExample) |
| CA (1) | CA978198A (enExample) |
| CS (1) | CS176201B2 (enExample) |
| DD (1) | DD98514A5 (enExample) |
| DE (1) | DE2230310C3 (enExample) |
| ES (1) | ES404095A1 (enExample) |
| FR (1) | FR2143181B1 (enExample) |
| GB (1) | GB1331207A (enExample) |
| IT (1) | IT959884B (enExample) |
| NL (1) | NL7208325A (enExample) |
| PL (1) | PL78050B1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4028070A (en) * | 1974-04-11 | 1977-06-07 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method of recovering ethylene oxide |
| US3964980A (en) * | 1975-03-24 | 1976-06-22 | Halcon International, Inc. | Process for the recovery of ethylene oxide |
| IT1144657B (it) * | 1981-03-02 | 1986-10-29 | Snam Progetti | Procedimento per l'assorbimento isotermico dell'ossido di etilene mediante l'impiego di assorbitori a film |
| FR2558069B1 (fr) * | 1984-01-17 | 1986-04-25 | Atochem | Procede d'elimination de gaz dissous dans une solution aqueuse d'oxyde d'ethylene |
| CA1284334C (en) | 1985-06-27 | 1991-05-21 | Masayuki Sawada | Method for recovery of ethylene oxide |
| US5171158A (en) * | 1990-04-11 | 1992-12-15 | Cairns James L | Underwater multiple contact electrical connector |
| US6533843B2 (en) | 2001-06-05 | 2003-03-18 | Scientific Design Company, Inc. | Two stage flash for hydrocarbon removal |
| TWI402093B (zh) * | 2005-05-10 | 2013-07-21 | Shell Int Research | 環氧乙烷之製備 |
| WO2008133121A1 (ja) * | 2007-04-17 | 2008-11-06 | Arkray, Inc. | 基質濃度測定方法および基質濃度測定装置 |
| EP2247355B1 (en) | 2008-01-25 | 2014-03-26 | Dow Technology Investments LLC | Reflux condenser |
| US8129551B2 (en) * | 2008-07-31 | 2012-03-06 | Dow Technology Investments Llc | Alkylene oxide recovery systems |
| CN113559540A (zh) * | 2020-04-29 | 2021-10-29 | 北京诺维新材科技有限公司 | 一种环氧乙烷的汽提方法和汽提装置 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3174262A (en) * | 1965-03-23 | Chemical process and apparatus for recovery of ethylene oxide | ||
| US3165539A (en) * | 1960-07-08 | 1965-01-12 | Halcon International Inc | Recovery of ethylene oxide from a liquid mixture thereof with normally gaseous impurities |
| US3217466A (en) * | 1962-05-22 | 1965-11-16 | Lummus Co | Recovery of ethylene oxide |
-
1971
- 1971-06-23 US US00155959A patent/US3729899A/en not_active Expired - Lifetime
-
1972
- 1972-05-04 CA CA141,339A patent/CA978198A/en not_active Expired
- 1972-06-14 BE BE784830A patent/BE784830A/nl not_active IP Right Cessation
- 1972-06-19 NL NL7208325A patent/NL7208325A/xx active Search and Examination
- 1972-06-21 CS CS4378A patent/CS176201B2/cs unknown
- 1972-06-21 PL PL1972156181A patent/PL78050B1/pl unknown
- 1972-06-21 DE DE2230310A patent/DE2230310C3/de not_active Expired
- 1972-06-21 ES ES404095A patent/ES404095A1/es not_active Expired
- 1972-06-21 DD DD163872A patent/DD98514A5/xx unknown
- 1972-06-21 AU AU43722/72A patent/AU458806B2/en not_active Expired
- 1972-06-21 FR FR7222341A patent/FR2143181B1/fr not_active Expired
- 1972-06-21 GB GB2908072A patent/GB1331207A/en not_active Expired
- 1972-06-21 IT IT26006/72A patent/IT959884B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| GB1331207A (en) | 1973-09-26 |
| DD98514A5 (enExample) | 1973-06-20 |
| FR2143181B1 (enExample) | 1977-12-23 |
| AU4372272A (en) | 1974-01-03 |
| CA978198A (en) | 1975-11-18 |
| CS176201B2 (enExample) | 1977-06-30 |
| PL78050B1 (enExample) | 1975-04-30 |
| DE2230310B2 (enExample) | 1974-11-07 |
| ES404095A1 (es) | 1975-05-16 |
| US3729899A (en) | 1973-05-01 |
| NL7208325A (enExample) | 1972-12-28 |
| DE2230310A1 (de) | 1972-12-28 |
| AU458806B2 (en) | 1975-03-06 |
| IT959884B (it) | 1973-11-10 |
| FR2143181A1 (enExample) | 1973-02-02 |
| BE784830A (nl) | 1972-12-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| 8339 | Ceased/non-payment of the annual fee |