DE2226657A1 - Verfahren zur selektiven Oxychlorierung von äthylenisch ungesättigten Kohlenwasserstoffen - Google Patents
Verfahren zur selektiven Oxychlorierung von äthylenisch ungesättigten KohlenwasserstoffenInfo
- Publication number
- DE2226657A1 DE2226657A1 DE19722226657 DE2226657A DE2226657A1 DE 2226657 A1 DE2226657 A1 DE 2226657A1 DE 19722226657 DE19722226657 DE 19722226657 DE 2226657 A DE2226657 A DE 2226657A DE 2226657 A1 DE2226657 A1 DE 2226657A1
- Authority
- DE
- Germany
- Prior art keywords
- copper
- catalysts
- oxychlorination
- magnesium
- ethylenically unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229930195735 unsaturated hydrocarbon Natural products 0.000 title claims description 8
- 238000000034 method Methods 0.000 title claims description 7
- 239000003054 catalyst Substances 0.000 claims description 43
- 239000010949 copper Substances 0.000 claims description 32
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 22
- 229910052802 copper Inorganic materials 0.000 claims description 22
- 239000011777 magnesium Substances 0.000 claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
- 239000005977 Ethylene Substances 0.000 claims description 14
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical class [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims description 3
- 235000011147 magnesium chloride Nutrition 0.000 claims 2
- 239000000969 carrier Substances 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 11
- 229910052749 magnesium Inorganic materials 0.000 description 11
- 239000012876 carrier material Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 239000004927 clay Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 5
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000009533 lab test Methods 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 241000157302 Bison bison athabascae Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7120051A FR2141452B1 (enrdf_load_stackoverflow) | 1971-06-03 | 1971-06-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2226657A1 true DE2226657A1 (de) | 1972-12-14 |
Family
ID=9078027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19722226657 Pending DE2226657A1 (de) | 1971-06-03 | 1972-05-31 | Verfahren zur selektiven Oxychlorierung von äthylenisch ungesättigten Kohlenwasserstoffen |
Country Status (10)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2543918A1 (de) * | 1974-10-04 | 1976-04-15 | Sir Soc Italiana Resine Spa | Oxychlorierungskatalysator und verfahren zur herstellung von dichloraethan |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0057796B1 (en) * | 1981-01-15 | 1985-11-27 | Imperial Chemical Industries Plc | Catalyst, catalyst support and oxychlorination process |
| IT1176719B (it) * | 1984-09-19 | 1987-08-18 | Ausind | Metodo per la preparazione di un catalizzatore per la sintesi di 1,2-dicloroetano |
| GB8829706D0 (en) * | 1988-12-20 | 1989-02-15 | Ici Plc | Oxychlorination catalyst composition |
| ITMI20030630A1 (it) | 2003-03-31 | 2004-10-01 | Sued Chemie Mt Srl | Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano. |
| ITMI20042317A1 (it) | 2004-12-02 | 2005-03-02 | Sued Chemie Mt Srl | Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano |
-
1971
- 1971-06-03 FR FR7120051A patent/FR2141452B1/fr not_active Expired
-
1972
- 1972-05-24 NL NL7206955A patent/NL7206955A/xx not_active Application Discontinuation
- 1972-05-30 ES ES403321A patent/ES403321A1/es not_active Expired
- 1972-05-31 IT IT5062372A patent/IT958164B/it active
- 1972-05-31 DE DE19722226657 patent/DE2226657A1/de active Pending
- 1972-06-02 AR AR24232672A patent/AR192943A1/es active
- 1972-06-02 GB GB2589372A patent/GB1345653A/en not_active Expired
- 1972-06-02 BR BR359072A patent/BR7203590D0/pt unknown
- 1972-06-02 BE BE784325A patent/BE784325A/xx unknown
- 1972-06-02 CA CA143,761A patent/CA991624A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2543918A1 (de) * | 1974-10-04 | 1976-04-15 | Sir Soc Italiana Resine Spa | Oxychlorierungskatalysator und verfahren zur herstellung von dichloraethan |
Also Published As
| Publication number | Publication date |
|---|---|
| ES403321A1 (es) | 1975-05-01 |
| FR2141452B1 (enrdf_load_stackoverflow) | 1973-06-29 |
| FR2141452A1 (enrdf_load_stackoverflow) | 1973-01-26 |
| CA991624A (en) | 1976-06-22 |
| BE784325A (fr) | 1972-12-04 |
| SU441693A3 (ru) | 1974-08-30 |
| GB1345653A (en) | 1974-01-30 |
| IT958164B (it) | 1973-10-20 |
| NL7206955A (enrdf_load_stackoverflow) | 1972-12-05 |
| BR7203590D0 (pt) | 1973-06-21 |
| AR192943A1 (es) | 1973-03-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3150205C2 (de) | Verfahren zur Herstellung eines Silberkatalysators für die Produktion von Ethylenoxid | |
| DE2448449C2 (de) | Silberkatalysator zur Herstellung von Äthylenoxid und seine Verwendung | |
| DE1417725B2 (de) | Verwendung eines Katalysators auf der Basis von Halogeniden des Kupfers, des Lanthans oder der Lanthaniden und der Alkalimetalle für die Oxychlorierung bzw. Oxybromierung von Kohlenwasserstoffen | |
| DD247388A5 (de) | Verfahren zur herstellung von silberhaltigen katalysatoren | |
| DE3885770T2 (de) | Oxychlorierungskatalysator und Verfahren zu seiner Herstellung. | |
| DE2935903C2 (de) | Oxidationskatalysator und seine Verwendung bei der Herstellung von Methacrolein | |
| DE1542327B2 (de) | Verfahren zur Herstellung von Katalysatoren | |
| DE2226657A1 (de) | Verfahren zur selektiven Oxychlorierung von äthylenisch ungesättigten Kohlenwasserstoffen | |
| DE69301368T2 (de) | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators und selektives Hydrierungsverfahren unter Verwendung eines solchen Katalysators | |
| DE2028350C2 (de) | Verfahren zur Herstellung von Aceton und/oder Methylisobuthylketon | |
| DE60208295T2 (de) | Katalysatoren enthaltend Kupfer und Magnesium zur Oxychlorierung von Ethylen in 1,2-Dichloroethan | |
| DE2207497C3 (de) | Träger für Katalysatoren | |
| DE3037047C2 (enrdf_load_stackoverflow) | ||
| DE1767096A1 (de) | Oxychlorierungskatalysator | |
| DE2257107A1 (de) | Verfahren zur herstellung von vinylidenchlorid | |
| DE2050061C3 (de) | Katalysator für die selektive Oxichlorierung von äthylenisch ungesättigten Kohlenwasserstoffen, vor allem Äthylen | |
| DE2156148A1 (de) | Verfahren zur Aktivierung eines Katalysators auf Silberbasis und dessen Verwendung zur Herstellung von Äthylenoxid | |
| DE4103431C2 (de) | Lanthan, Scandium oder Yttrium oder ein Alkali- oder Erdalkalimetall sowie gegebenenfalls Zinn enthaltender Katalysator sowie Verwendung desselben zur Umwandlung von Methan in höhere Kohlenwasserstoffe | |
| DE1222913B (de) | Verfahren zur Herstellung von Allylchorid und seinen Monomethylsubstitutionsprodukten | |
| DE1277846B (de) | Verfahren zur Herstellung von Vinylchlorid | |
| DE2232538A1 (de) | Chlor uebertragende kontaktmassen fuer die zweistufige herstellung von phosgen | |
| DE1768492C3 (de) | Verfahren zur gleichzeitigen Herstellung von 1,2-Dichloräthan, 1,1,2-Trichloräthan und 1,1,2,2-Tetrachloräthan durch Oxychlorieren von Äthylen | |
| DE1963379A1 (de) | Verfahren zur Oxychlorierung von Kohlenwasserstoffen | |
| DE1542327C (de) | Verfahren zur Herstellung von Kataly satoren \nm Monsanto Co St Louis, Mo (V St A.) | |
| DE1543151C (de) | Verfahren zur Herstellung von Car bonylverbindungen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| OHN | Withdrawal |