DE2159444A1 - Verfahren zur herstellung von phosphornitriddiamiden - Google Patents
Verfahren zur herstellung von phosphornitriddiamidenInfo
- Publication number
- DE2159444A1 DE2159444A1 DE2159444A DE2159444A DE2159444A1 DE 2159444 A1 DE2159444 A1 DE 2159444A1 DE 2159444 A DE2159444 A DE 2159444A DE 2159444 A DE2159444 A DE 2159444A DE 2159444 A1 DE2159444 A1 DE 2159444A1
- Authority
- DE
- Germany
- Prior art keywords
- phosphorus
- ammonia gas
- chlorine
- reaction product
- diamides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 19
- 150000001470 diamides Chemical class 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 26
- 239000000460 chlorine Substances 0.000 claims description 22
- 229910052698 phosphorus Inorganic materials 0.000 claims description 17
- 239000011574 phosphorus Substances 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 11
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- -1 phosphorus nitride diamides Chemical class 0.000 claims description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011541 reaction mixture Substances 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KMLJVJRQAFXKKA-UHFFFAOYSA-N Cl[P](Cl)(Cl)Cl Chemical compound Cl[P](Cl)(Cl)Cl KMLJVJRQAFXKKA-UHFFFAOYSA-N 0.000 description 1
- 101100028689 Drosophila melanogaster rho-7 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
- C01B21/092—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms containing also one or more metal atoms
- C01B21/0923—Metal imides or amides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2159444A DE2159444A1 (de) | 1971-12-01 | 1971-12-01 | Verfahren zur herstellung von phosphornitriddiamiden |
| NL7216132A NL7216132A (enExample) | 1971-12-01 | 1972-11-28 | |
| BE791996D BE791996A (fr) | 1971-12-01 | 1972-11-28 | Procede de preparation de diamides de nitrure de phosphore |
| GB5482872A GB1378337A (en) | 1971-12-01 | 1972-11-28 | Process for the manufacture of aminophosphazenes |
| FR7242458A FR2162077B1 (enExample) | 1971-12-01 | 1972-11-29 | |
| IT54350/72A IT973784B (it) | 1971-12-01 | 1972-11-29 | Procedimento per produrre nitruro diammidi di fosforo |
| US310593A US3859418A (en) | 1971-12-01 | 1972-11-29 | Process for the manufacture of phosphorus nitride diamides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2159444A DE2159444A1 (de) | 1971-12-01 | 1971-12-01 | Verfahren zur herstellung von phosphornitriddiamiden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2159444A1 true DE2159444A1 (de) | 1973-06-07 |
Family
ID=5826626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2159444A Pending DE2159444A1 (de) | 1971-12-01 | 1971-12-01 | Verfahren zur herstellung von phosphornitriddiamiden |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3859418A (enExample) |
| BE (1) | BE791996A (enExample) |
| DE (1) | DE2159444A1 (enExample) |
| FR (1) | FR2162077B1 (enExample) |
| GB (1) | GB1378337A (enExample) |
| IT (1) | IT973784B (enExample) |
| NL (1) | NL7216132A (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4289539A (en) * | 1977-02-28 | 1981-09-15 | International Business Machines Corporation | Phosphorus-nitrogen-oxygen composition and method for making such composition and applications of the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2980506A (en) * | 1956-09-27 | 1961-04-18 | Henkel & Compagnie G M B H | Nitrogen-phosphoric acid compounds containing active chlorine |
-
1971
- 1971-12-01 DE DE2159444A patent/DE2159444A1/de active Pending
-
1972
- 1972-11-28 NL NL7216132A patent/NL7216132A/xx unknown
- 1972-11-28 BE BE791996D patent/BE791996A/xx unknown
- 1972-11-28 GB GB5482872A patent/GB1378337A/en not_active Expired
- 1972-11-29 FR FR7242458A patent/FR2162077B1/fr not_active Expired
- 1972-11-29 IT IT54350/72A patent/IT973784B/it active
- 1972-11-29 US US310593A patent/US3859418A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2162077B1 (enExample) | 1976-06-04 |
| FR2162077A1 (enExample) | 1973-07-13 |
| NL7216132A (enExample) | 1973-06-05 |
| IT973784B (it) | 1974-06-10 |
| BE791996A (fr) | 1973-05-28 |
| GB1378337A (en) | 1974-12-27 |
| US3859418A (en) | 1975-01-07 |
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