DE2159139C3 - Verfahren zur Herstellung von Methylestern gesättigter aliphatischer Carbonsäuren - Google Patents

Verfahren zur Herstellung von Methylestern gesättigter aliphatischer Carbonsäuren

Info

Publication number
DE2159139C3
DE2159139C3 DE2159139A DE2159139A DE2159139C3 DE 2159139 C3 DE2159139 C3 DE 2159139C3 DE 2159139 A DE2159139 A DE 2159139A DE 2159139 A DE2159139 A DE 2159139A DE 2159139 C3 DE2159139 C3 DE 2159139C3
Authority
DE
Germany
Prior art keywords
cobalt
catalyst
methanol
reaction
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2159139A
Other languages
German (de)
English (en)
Other versions
DE2159139A1 (de
DE2159139B2 (de
Inventor
Kestutis Aloyzas Southfield Mich. Keblys (V.St.A.)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ethyl Corp
Original Assignee
Ethyl Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ethyl Corp filed Critical Ethyl Corp
Publication of DE2159139A1 publication Critical patent/DE2159139A1/de
Publication of DE2159139B2 publication Critical patent/DE2159139B2/de
Application granted granted Critical
Publication of DE2159139C3 publication Critical patent/DE2159139C3/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE2159139A 1970-12-07 1971-11-29 Verfahren zur Herstellung von Methylestern gesättigter aliphatischer Carbonsäuren Expired DE2159139C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US9595870A 1970-12-07 1970-12-07

Publications (3)

Publication Number Publication Date
DE2159139A1 DE2159139A1 (de) 1972-06-22
DE2159139B2 DE2159139B2 (de) 1977-09-08
DE2159139C3 true DE2159139C3 (de) 1978-05-11

Family

ID=22254371

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2159139A Expired DE2159139C3 (de) 1970-12-07 1971-11-29 Verfahren zur Herstellung von Methylestern gesättigter aliphatischer Carbonsäuren

Country Status (6)

Country Link
JP (1) JPS5147676B1 (index.php)
CA (1) CA996948A (index.php)
DE (1) DE2159139C3 (index.php)
FR (1) FR2117323A5 (index.php)
GB (1) GB1344669A (index.php)
NL (1) NL7116542A (index.php)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0038919A1 (de) * 1980-04-30 1981-11-04 Chemische Werke Hüls Ag Verfahren zur Rückgewinnung und Reaktivierung von bei der Umsetzung von Olefinen mit Kohlenmonoxid und Alkanolen eingesetzten kobalthaltigen Katalysatoren
US4310686A (en) 1979-06-20 1982-01-12 Basf Aktiengesellschaft Preparation of butanedicarboxylic esters

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2949939A1 (de) * 1979-12-12 1981-06-19 Huels Chemische Werke Ag Verfahren zur extraktiven aufarbeitung der bei der hydrocarboxylierung eingesetzten kobalthaltigen katalysatoren
US4312781A (en) * 1980-08-06 1982-01-26 Standard Oil Company Process for the separation of catalyst from products obtained in the hydrocarboxylation of unsaturated nitriles
DE3034422A1 (de) * 1980-09-12 1982-05-06 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von ueberwiegend linearen aliphatischen carbonsaeureestern
CN107497489B (zh) * 2016-06-14 2020-06-09 中国石油化工股份有限公司 乙烯合成丙酸甲酯用催化剂组合物及其合成方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4310686A (en) 1979-06-20 1982-01-12 Basf Aktiengesellschaft Preparation of butanedicarboxylic esters
EP0038919A1 (de) * 1980-04-30 1981-11-04 Chemische Werke Hüls Ag Verfahren zur Rückgewinnung und Reaktivierung von bei der Umsetzung von Olefinen mit Kohlenmonoxid und Alkanolen eingesetzten kobalthaltigen Katalysatoren

Also Published As

Publication number Publication date
JPS5147676B1 (index.php) 1976-12-16
FR2117323A5 (index.php) 1972-07-21
DE2159139A1 (de) 1972-06-22
CA996948A (en) 1976-09-14
DE2159139B2 (de) 1977-09-08
NL7116542A (index.php) 1972-06-09
GB1344669A (en) 1974-01-23

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
8339 Ceased/non-payment of the annual fee