DE2041204A1 - Verfahren zum Aufpfropfen einer alpha-aethylenischen Carbonsaeure auf ein Polyolefin - Google Patents
Verfahren zum Aufpfropfen einer alpha-aethylenischen Carbonsaeure auf ein PolyolefinInfo
- Publication number
- DE2041204A1 DE2041204A1 DE19702041204 DE2041204A DE2041204A1 DE 2041204 A1 DE2041204 A1 DE 2041204A1 DE 19702041204 DE19702041204 DE 19702041204 DE 2041204 A DE2041204 A DE 2041204A DE 2041204 A1 DE2041204 A1 DE 2041204A1
- Authority
- DE
- Germany
- Prior art keywords
- polyolefin
- temperature
- acrylic acid
- grafted
- grafting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 18
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 37
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 36
- 239000000843 powder Substances 0.000 claims description 25
- -1 polyethylene Polymers 0.000 claims description 24
- 239000004698 Polyethylene Substances 0.000 claims description 19
- 229920000573 polyethylene Polymers 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 7
- 229920001112 grafted polyolefin Polymers 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 230000005865 ionizing radiation Effects 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 2
- 230000007717 exclusion Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 36
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000003570 air Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 239000004700 high-density polyethylene Substances 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 229920000578 graft copolymer Polymers 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 206010073306 Exposure to radiation Diseases 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- YYXHRUSBEPGBCD-UHFFFAOYSA-N azanylidyneiron Chemical compound [N].[Fe] YYXHRUSBEPGBCD-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6929170A FR2056057A5 (enrdf_load_stackoverflow) | 1969-08-26 | 1969-08-26 | |
| CH1452970A CH526595A (fr) | 1969-08-26 | 1970-09-30 | Procédé de greffage sur une poudre de polyoléfine et produits en résultant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2041204A1 true DE2041204A1 (de) | 1971-03-04 |
Family
ID=25714676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702041204 Pending DE2041204A1 (de) | 1969-08-26 | 1970-08-19 | Verfahren zum Aufpfropfen einer alpha-aethylenischen Carbonsaeure auf ein Polyolefin |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE753703A (enrdf_load_stackoverflow) |
| CH (1) | CH526595A (enrdf_load_stackoverflow) |
| DE (1) | DE2041204A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2056057A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1293810A (enrdf_load_stackoverflow) |
| NL (1) | NL7011134A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2453155A1 (de) * | 1973-11-09 | 1975-05-15 | Commissariat Energie Atomique | Hydrophobes substrat mit aufgepfropften hydrophilen einschluessen und verfahren zur herstellung desselben |
| EP0437808A3 (en) * | 1989-12-21 | 1991-10-30 | Himont Incorporated | Graft copolymers of polyolefins and a method of producing same |
| EP0519341A1 (en) * | 1991-06-21 | 1992-12-23 | Montell North America Inc. | Process for grafting vinyl monomers on particulate olefin polymers |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113968941B (zh) * | 2021-12-06 | 2023-09-08 | 方昱炜 | 一种丙烯酸类改性聚α烯烃的聚合方法 |
-
1969
- 1969-08-26 FR FR6929170A patent/FR2056057A5/fr not_active Expired
-
1970
- 1970-07-20 BE BE753703D patent/BE753703A/xx unknown
- 1970-07-28 NL NL7011134A patent/NL7011134A/xx unknown
- 1970-08-19 DE DE19702041204 patent/DE2041204A1/de active Pending
- 1970-08-19 GB GB39974/70A patent/GB1293810A/en not_active Expired
- 1970-09-30 CH CH1452970A patent/CH526595A/fr not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2453155A1 (de) * | 1973-11-09 | 1975-05-15 | Commissariat Energie Atomique | Hydrophobes substrat mit aufgepfropften hydrophilen einschluessen und verfahren zur herstellung desselben |
| EP0437808A3 (en) * | 1989-12-21 | 1991-10-30 | Himont Incorporated | Graft copolymers of polyolefins and a method of producing same |
| EP0519341A1 (en) * | 1991-06-21 | 1992-12-23 | Montell North America Inc. | Process for grafting vinyl monomers on particulate olefin polymers |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7011134A (enrdf_load_stackoverflow) | 1971-03-02 |
| FR2056057A5 (enrdf_load_stackoverflow) | 1971-05-14 |
| CH526595A (fr) | 1972-08-15 |
| BE753703A (fr) | 1971-01-20 |
| GB1293810A (en) | 1972-10-25 |
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