DE2035706C3 - Verfahren zur Herstellung von Oxidationsprodukten von Äthylenpolymeren - Google Patents
Verfahren zur Herstellung von Oxidationsprodukten von ÄthylenpolymerenInfo
- Publication number
- DE2035706C3 DE2035706C3 DE2035706A DE2035706A DE2035706C3 DE 2035706 C3 DE2035706 C3 DE 2035706C3 DE 2035706 A DE2035706 A DE 2035706A DE 2035706 A DE2035706 A DE 2035706A DE 2035706 C3 DE2035706 C3 DE 2035706C3
- Authority
- DE
- Germany
- Prior art keywords
- oxidation
- reaction
- water
- products
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 22
- 229920000573 polyethylene Polymers 0.000 title claims description 21
- 230000003647 oxidation Effects 0.000 title description 42
- 238000007254 oxidation reaction Methods 0.000 title description 42
- 238000002360 preparation method Methods 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000003054 catalyst Substances 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 20
- 230000008018 melting Effects 0.000 claims description 20
- 239000004698 Polyethylene Substances 0.000 claims description 18
- -1 polyethylenes Polymers 0.000 claims description 18
- 239000002270 dispersing agent Substances 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- 210000003734 kidney Anatomy 0.000 claims 1
- 239000000047 product Substances 0.000 description 40
- 229920000098 polyolefin Polymers 0.000 description 35
- 238000006243 chemical reaction Methods 0.000 description 31
- 239000002253 acid Substances 0.000 description 20
- 230000035484 reaction time Effects 0.000 description 16
- 239000001993 wax Substances 0.000 description 14
- 238000003756 stirring Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 230000015556 catabolic process Effects 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- 238000007127 saponification reaction Methods 0.000 description 6
- 238000006731 degradation reaction Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 4
- 210000003298 dental enamel Anatomy 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 239000013505 freshwater Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical class CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 2
- 241000158147 Sator Species 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OSVKHTYJGSWIBJ-UHFFFAOYSA-N 1,6-ditert-butyl-4-methylcyclohexa-2,4-dien-1-ol Chemical compound CC1=CC(C(C)(C)C)C(O)(C(C)(C)C)C=C1 OSVKHTYJGSWIBJ-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241001653634 Russula vesca Species 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004476 plant protection product Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2035706A DE2035706C3 (de) | 1970-07-18 | 1970-07-18 | Verfahren zur Herstellung von Oxidationsprodukten von Äthylenpolymeren |
| NL7109639.A NL157606B (nl) | 1970-07-18 | 1971-07-13 | Werkwijze voor het bereiden van carbonzuurgroepen houdende oxydaten van polyethenen of copolymeren van etheen. |
| CH1037971A CH549610A (de) | 1970-07-18 | 1971-07-14 | Verfahren zur oxidation von aethylenpolymerisaten. |
| US00162723A US3756999A (en) | 1970-07-18 | 1971-07-14 | Sprocess for the preparation of oxidation products of ethylene polymer |
| CA118,171A CA987049A (en) | 1970-07-18 | 1971-07-14 | Process for the preparation of oxidation products of ethylene polymers |
| FR7126144A FR2101828A5 (cg-RX-API-DMAC7.html) | 1970-07-18 | 1971-07-16 | |
| BE770163A BE770163A (fr) | 1970-07-18 | 1971-07-16 | Procede de preparation de produits d'oxydation de polymeres d'ethylene |
| AT623471A AT317535B (de) | 1970-07-18 | 1971-07-16 | Verfahren zur Oxydation von Polyäthylenen oder Copolymeren des Äthylens mit α-Olefinen |
| SE09243/71A SE361890B (cg-RX-API-DMAC7.html) | 1970-07-18 | 1971-07-16 | |
| GB3348571A GB1339360A (en) | 1970-07-18 | 1971-07-16 | Process for the preparation of oxidation products of ethylene polymers |
| AU31316/71A AU450827B2 (en) | 1970-07-18 | 1971-07-16 | Process for the preparation of oxidation products of ethylene polymers |
| JP46052845A JPS521439B1 (cg-RX-API-DMAC7.html) | 1970-07-18 | 1971-07-17 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2035706A DE2035706C3 (de) | 1970-07-18 | 1970-07-18 | Verfahren zur Herstellung von Oxidationsprodukten von Äthylenpolymeren |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2035706A1 DE2035706A1 (de) | 1972-01-20 |
| DE2035706B2 DE2035706B2 (de) | 1975-01-09 |
| DE2035706C3 true DE2035706C3 (de) | 1975-09-11 |
Family
ID=5777152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2035706A Expired DE2035706C3 (de) | 1970-07-18 | 1970-07-18 | Verfahren zur Herstellung von Oxidationsprodukten von Äthylenpolymeren |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US3756999A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS521439B1 (cg-RX-API-DMAC7.html) |
| AT (1) | AT317535B (cg-RX-API-DMAC7.html) |
| AU (1) | AU450827B2 (cg-RX-API-DMAC7.html) |
| BE (1) | BE770163A (cg-RX-API-DMAC7.html) |
| CA (1) | CA987049A (cg-RX-API-DMAC7.html) |
| CH (1) | CH549610A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2035706C3 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2101828A5 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1339360A (cg-RX-API-DMAC7.html) |
| NL (1) | NL157606B (cg-RX-API-DMAC7.html) |
| SE (1) | SE361890B (cg-RX-API-DMAC7.html) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2201863A1 (de) * | 1972-01-15 | 1973-07-19 | Hoechst Ag | Gleitmittel fuer pvc |
| CH596244A5 (cg-RX-API-DMAC7.html) * | 1973-04-03 | 1978-03-15 | Sandoz Ag | |
| JPS53135784A (en) * | 1977-05-02 | 1978-11-27 | Hiyuitsuto Kenii Kk | Needle attaching element |
| US4156062A (en) * | 1977-05-09 | 1979-05-22 | National Distillers And Chemical Corporation | Process for toughening ethylene-vinyl acetate copolymers and resins obtained thereby |
| US4145493A (en) * | 1977-12-01 | 1979-03-20 | Standard Oil Company (Indiana) | Oxidation of rubbery polymeric hydrocarbons |
| US4336356A (en) * | 1978-12-15 | 1982-06-22 | Allied Corporation | Production of ozonides from unsaturated polymers |
| DE3066715D1 (en) * | 1979-11-02 | 1984-03-29 | Hoechst Ag | Oxidation products of ethylene copolymers and their use |
| JPS6020946A (ja) * | 1983-07-14 | 1985-02-02 | Nissan Chem Ind Ltd | 改良された中空成形用樹脂の製造方法 |
| DE3434668A1 (de) * | 1984-09-21 | 1986-04-03 | Henkel KGaA, 4000 Düsseldorf | Konservierungsmittel fuer aluminium-oberflaechen |
| US5075173A (en) * | 1987-01-29 | 1991-12-24 | Copolymer Rubber & Chemical Corp. | Directly painted article fabricated from a thermoplastic polyolefin and ethylene polymers blend |
| US4990568A (en) * | 1987-01-29 | 1991-02-05 | Copolymer Rubber & Chemical Corporation | Thermoplastic polyolefin and ethylene copolymers with oxidized polyolefin |
| US5103061A (en) * | 1989-02-10 | 1992-04-07 | Bp Chemicals Limited | Synthesis of hydrocarbyl amines |
| ATE156506T1 (de) * | 1993-02-12 | 1997-08-15 | Hoechst Ag | Verwendung eines copolymerisats zur herstellung wässriger emulsionen |
| DK0713510T3 (da) * | 1993-08-11 | 1997-09-01 | Allied Signal Inc | Eksterne smøremiddelsammensætninger til stive vinylpolymerer |
| US5426144A (en) * | 1993-08-11 | 1995-06-20 | Alliedsignal Inc. | External lubricant and stabilizer compositions for rigid vinyl polymers |
| DE19617230A1 (de) * | 1996-04-30 | 1997-11-06 | Basf Ag | Oxidierte Metallocen-Polyolefin-Wachse |
| DE19700892A1 (de) | 1997-01-14 | 1998-07-16 | Basf Ag | Verfahren zur Herstellung oxidierter Polyolefinwachse |
| ES2209008T3 (es) | 1997-07-11 | 2004-06-16 | Clariant Gmbh | Procedimiento para la oxidacion de ceras polietilenicas. |
| DE19860174A1 (de) | 1998-12-24 | 2000-06-29 | Clariant Gmbh | Polymeroxidate und ihre Verwendung |
| US6231656B1 (en) * | 1999-02-18 | 2001-05-15 | Allied Signal Inc. | Release agents for use in lignocellulosic processes and process for preparing molded lignocellulosic composites |
| US6469093B1 (en) | 1999-11-12 | 2002-10-22 | General Electric Company | Conductive polyphenylene ether-polyamide blend |
| ATE239057T1 (de) * | 2000-02-15 | 2003-05-15 | Asahi Chemical Ind | Polyamidzusammensetzung |
| US6365677B1 (en) | 2000-03-01 | 2002-04-02 | General Electric | Reduction of carbonized particles |
| US6414084B1 (en) * | 2000-04-13 | 2002-07-02 | General Electric Company | High flow polyphenylene ether formulations with dendritic polymers |
| US6353050B1 (en) | 2000-10-13 | 2002-03-05 | General Electric Co. | Thermoplastic blend comprising poly(arylene ether) and polyamide |
| US6500895B1 (en) | 2000-10-13 | 2002-12-31 | General Electric Company | Thermoplastic blend comprising poly(arylene ether) and polyamide |
| US7022776B2 (en) * | 2001-11-07 | 2006-04-04 | General Electric | Conductive polyphenylene ether-polyamide composition, method of manufacture thereof, and article derived therefrom |
| DE10206015A1 (de) * | 2002-02-14 | 2003-08-28 | Clariant Gmbh | Verwendung von oxidierten Polyolefinwachsen für die textile Ausrüstung |
| US6794450B2 (en) | 2002-03-06 | 2004-09-21 | General Electric Company | High flow compositions of compatibilized poly(arylene ether) polyamide blends |
| US6776929B2 (en) * | 2002-03-15 | 2004-08-17 | General Electric Company | Method of forming a conductive thermoplastic composition |
| US20040000741A1 (en) * | 2002-06-26 | 2004-01-01 | Lindner Robert A. | Manufacture of polyvinylchloride articles |
| US7071970B2 (en) * | 2003-03-10 | 2006-07-04 | Charles Benton | Video augmented orientation sensor |
| US7241403B2 (en) | 2003-05-29 | 2007-07-10 | General Electric Company | Method for making a conductive thermoplastic composition |
| US20060025507A1 (en) | 2004-07-26 | 2006-02-02 | Moore David T | Low wear resin composition having improved surface appearance |
| US7709425B2 (en) * | 2005-10-27 | 2010-05-04 | Chevron Phillips Chemical Company Lp | Oxidized olefin wax pour point depressants |
| DE102008000595A1 (de) | 2008-03-11 | 2009-09-17 | Evonik Degussa Gmbh | Nachvernetzendes Wachs und Verfahren zu seiner Herstellung |
| EP2184324A1 (en) * | 2008-11-06 | 2010-05-12 | Clariant International Ltd. | Compositions comprising propylene-olefin-copolymer waxes and carbon nanotubes |
| CN104277167A (zh) * | 2013-07-10 | 2015-01-14 | 胡永生 | 一种高密度氧化聚乙烯蜡的制备方法 |
| DE102018206484A1 (de) * | 2018-04-26 | 2019-10-31 | Contitech Antriebssysteme Gmbh | Artikel mit Textilauflage, die mit partiell oxidiertem Polyethylen behandelt ist |
| WO2020092606A1 (en) * | 2018-11-01 | 2020-05-07 | Exxonmobil Chemical Patents Inc. | On-line adjustment of mixed catalyst ratio and olefin polymerization |
| DE102021133861A1 (de) | 2021-12-20 | 2023-06-22 | Universität Konstanz, Körperschaft des öffentlichen Rechts | Verwertung von Polyethylen-haltigen Gemischen zu langkettigen Alkyldicarbonsäuren mittels oxidativer Spaltung |
-
1970
- 1970-07-18 DE DE2035706A patent/DE2035706C3/de not_active Expired
-
1971
- 1971-07-13 NL NL7109639.A patent/NL157606B/xx not_active IP Right Cessation
- 1971-07-14 CA CA118,171A patent/CA987049A/en not_active Expired
- 1971-07-14 US US00162723A patent/US3756999A/en not_active Expired - Lifetime
- 1971-07-14 CH CH1037971A patent/CH549610A/xx not_active IP Right Cessation
- 1971-07-16 GB GB3348571A patent/GB1339360A/en not_active Expired
- 1971-07-16 SE SE09243/71A patent/SE361890B/xx unknown
- 1971-07-16 FR FR7126144A patent/FR2101828A5/fr not_active Expired
- 1971-07-16 AU AU31316/71A patent/AU450827B2/en not_active Expired
- 1971-07-16 BE BE770163A patent/BE770163A/xx unknown
- 1971-07-16 AT AT623471A patent/AT317535B/de not_active IP Right Cessation
- 1971-07-17 JP JP46052845A patent/JPS521439B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US3756999A (en) | 1973-09-04 |
| FR2101828A5 (cg-RX-API-DMAC7.html) | 1972-03-31 |
| BE770163A (fr) | 1972-01-17 |
| DE2035706A1 (de) | 1972-01-20 |
| JPS521439B1 (cg-RX-API-DMAC7.html) | 1977-01-14 |
| NL157606B (nl) | 1978-08-15 |
| DE2035706B2 (de) | 1975-01-09 |
| CA987049A (en) | 1976-04-06 |
| AU450827B2 (en) | 1974-07-18 |
| NL7109639A (cg-RX-API-DMAC7.html) | 1972-01-20 |
| AT317535B (de) | 1974-09-10 |
| GB1339360A (en) | 1973-12-05 |
| AU3131671A (en) | 1973-01-18 |
| CH549610A (de) | 1974-05-31 |
| SE361890B (cg-RX-API-DMAC7.html) | 1973-11-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 |