DE2029925C3 - Verfahren zum katalytischen Reformieren von Schwerbenzin - Google Patents

Verfahren zum katalytischen Reformieren von Schwerbenzin

Info

Publication number
DE2029925C3
DE2029925C3 DE2029925A DE2029925A DE2029925C3 DE 2029925 C3 DE2029925 C3 DE 2029925C3 DE 2029925 A DE2029925 A DE 2029925A DE 2029925 A DE2029925 A DE 2029925A DE 2029925 C3 DE2029925 C3 DE 2029925C3
Authority
DE
Germany
Prior art keywords
catalyst
copper
catalysts
silica
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2029925A
Other languages
German (de)
English (en)
Other versions
DE2029925A1 (enExample
DE2029925B2 (de
Inventor
Allan E. Westfield Barnett
James L. Chatham Carter
John H. Berkeley Heights Sinfelt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Esso Research and Engineering Co filed Critical Esso Research and Engineering Co
Publication of DE2029925A1 publication Critical patent/DE2029925A1/de
Publication of DE2029925B2 publication Critical patent/DE2029925B2/de
Application granted granted Critical
Publication of DE2029925C3 publication Critical patent/DE2029925C3/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2724—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C07C5/325—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE2029925A 1969-06-20 1970-06-18 Verfahren zum katalytischen Reformieren von Schwerbenzin Expired DE2029925C3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US83523969A 1969-06-20 1969-06-20

Publications (3)

Publication Number Publication Date
DE2029925A1 DE2029925A1 (enExample) 1970-12-23
DE2029925B2 DE2029925B2 (de) 1977-11-03
DE2029925C3 true DE2029925C3 (de) 1978-07-06

Family

ID=25269005

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2029925A Expired DE2029925C3 (de) 1969-06-20 1970-06-18 Verfahren zum katalytischen Reformieren von Schwerbenzin

Country Status (7)

Country Link
US (1) US3617518A (enExample)
JP (1) JPS496523B1 (enExample)
CA (1) CA944299A (enExample)
DE (1) DE2029925C3 (enExample)
FR (1) FR2046980B1 (enExample)
GB (1) GB1309862A (enExample)
NL (1) NL7009023A (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1456369A (en) * 1972-11-30 1976-11-24 Stamicarbon Catalyst preparation
FR2223337B1 (enExample) * 1973-03-26 1977-04-29 Inst Francais Du Petrole
US3876557A (en) * 1973-06-29 1975-04-08 Jackie Lou Bland Metallic catalyst
US3969221A (en) * 1974-01-04 1976-07-13 Exxon Research And Engineering Company Iridium-containing catalysts
JPS5221730U (enExample) * 1975-08-04 1977-02-16
LU76107A1 (enExample) * 1976-10-29 1978-05-16
US4199436A (en) * 1979-02-12 1980-04-22 Institut Francais Du Petrole Process for steam-dealkylating alkylaromatic hydrocarbons
US4738771A (en) * 1984-12-11 1988-04-19 Union Oil Company Of California Hydrocarbon upgrading process
JPS62269751A (ja) * 1986-05-16 1987-11-24 Nippon Engeruharudo Kk 白金−銅合金電極触媒およびそれを使用した酸電解質燃料電池用電極
US5208405A (en) * 1992-03-03 1993-05-04 Phillips Petroleum Company Selective hydrogenation of diolefins
US5435984A (en) * 1992-04-28 1995-07-25 Degussa Corporation Catalyst for the synthesis of chlorine dioxide
US5393413A (en) * 1992-09-08 1995-02-28 Pac Rim Products, Inc. Method for catalytic low temperature and pressure reforming of light hydrocarbon fuels for selective production of aromatics, olefins and saturates
US5849652A (en) * 1994-03-14 1998-12-15 Northeastern University Metal containing catalysts and methods for making same
US5905180A (en) 1996-01-22 1999-05-18 Regents Of The University Of Minnesota Catalytic oxidative dehydrogenation process and catalyst
US5977013A (en) * 1996-12-19 1999-11-02 Battelle Memorial Institute Catalyst and method for aqueous phase reactions
EP2666540A1 (de) * 2012-05-22 2013-11-27 Karlsruher Institut für Technologie Verfahren zur katalytischen Hydrodesoxygenierung von Furan-Derivaten und/oder Pyrolyseölen, der entsprechende Katalysator und dessen Herstellungsverfahren.
EP3323506A4 (en) 2015-07-15 2019-05-08 Furukawa Electric Co. Ltd. CATALYST OF A NANOCRYSTAL COMPOUNT FOR HYDROGEN STORAGE / SUPPLY, CATALYST MIXTURE OF A NANOCRYSTAL COMPLEX FOR HYDROGEN STORAGE / SUPPLY AND METHOD OF SUPPLEMENTING HYDROGEN
WO2017010492A1 (ja) 2015-07-15 2017-01-19 古河電気工業株式会社 基材一体型ナノ結晶金属酸化物複合体含有触媒およびその製造方法ならびに触媒部品

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2911357A (en) * 1955-12-30 1959-11-03 Phillips Petroleum Co Catalysts for the conversion and reforming of hydrocarbons comprising a platinum group metal with a stabilizing metal
US2897135A (en) * 1957-01-31 1959-07-28 Union Oil Co Hydrocarbon conversion process and catalyst
US2926130A (en) * 1957-11-12 1960-02-23 Phillips Petroleum Co Hydrocarbon conversion catalyst for use in the hydrocracking of hydrocarbon oils
US3000811A (en) * 1958-04-28 1961-09-19 Universal Oil Prod Co Conversion process
US3193349A (en) * 1962-04-13 1965-07-06 Sinclair Research Inc Method of producing boehmite of 50 to 80 a. crystal size
BE631769A (enExample) * 1962-04-30
US3367885A (en) * 1966-02-21 1968-02-06 Union Carbide Corp Hydrocarbon conversion catalysts
US3442973A (en) * 1966-11-14 1969-05-06 Exxon Research Engineering Co Isomerization process utilizing a gold-palladium alloy in the catalyst

Also Published As

Publication number Publication date
FR2046980B1 (enExample) 1974-05-03
FR2046980A1 (enExample) 1971-03-12
JPS496523B1 (enExample) 1974-02-14
DE2029925A1 (enExample) 1970-12-23
NL7009023A (enExample) 1970-12-22
GB1309862A (en) 1973-03-14
DE2029925B2 (de) 1977-11-03
US3617518A (en) 1971-11-02
CA944299A (en) 1974-03-26

Similar Documents

Publication Publication Date Title
DE3122157C2 (enExample)
DE2029925B2 (de) Verfahren zum katalytischen reformieren von schwerbenzin
DE69630401T2 (de) Verwendung eines gemeinsam ausgefällten modifizierten festen Oxides zur Isomerisierung von Paraffinen
DE69315466T2 (de) Gruppe-VIII Metal und Gruppe-IIIA Metal an einem Träger enthaltender Katalysator
WO1999029420A1 (de) Katalysator zur umwandlung paraffinischer kohlenwasserstoffe in korrespondierende olefine
DE69516917T2 (de) Feste supersaure Katalysatoren die ein Platinum Metall enthalten und Verfahren zur Umwandlung von Kohlenwasserstoffen unter Verwendung derselben
DE3226518C2 (enExample)
DE112019004677T5 (de) AUF ZEOLITHEN GETRÄGERTE BIMETALLISCHE KATALYSATOREN ZUR SELEKTIVEN UMWANDLUNG VON n-BUTAN IN ETHAN
DE2162442A1 (de) Katalytisches Reformierverfahren
DE3524317C2 (enExample)
DE2121765A1 (de) Verfahren zur Herstellung von regenerierbaren Katalysatoren und ihre Verwendung für Kohlenwasserstoff-Umwandlungsverfahren
DE19546514B9 (de) Katalysator und dessen Verwendung
DE1151082B (de) Reformierungskatalysator
DE1442850A1 (de) Katalysator zur Umwandlung von Kohlenwasserstoffen
DE2628958C3 (de) Verfahren zur Herstellung von Äthan durch selektive, katalytische Hydrogenolyse von Alkanen
EP0048378A1 (de) Verfahren zur Herstellung ungesättigter Kohlenwasserstoffe
DE1067013B (de) Ver fahren zur katalytischen Umwandlung \on Kohlenwasserstoffen in Gegenwart von Wasserstoff und zum Regenerieren der verwandten Katalysatoren
DE2818308A1 (de) Verfahren zur herstellung von kohlenwasserstoffen
DE2636282A1 (de) Verfahren und darin verwendeter katalysator zur herstellung von kohlenwasserstoffen
DE69022879T2 (de) Verfahren zur Isomerisierung von Kohlenwasserstoffen.
DE69513346T2 (de) Verfahren zur Hydrierung von Benzen in Kohlenwasserstoffölen
EP0659723B1 (de) Verfahren zur Herstellung von Alkyl-tert.-alkyl-ether enthaltenden Kohlenwasserstoffgemischen
DE2513756A1 (de) Katalysator fuer die wasserstoffbehandlung von kohlenwasserstoffen und dessen herstellung
DE69718670T2 (de) Wasserstoffumwandlungsträgerkatalysator und verfahren zu seiner herstellung
DE19521222A1 (de) Verfahren zur Herstellung von Alkylbenzolen

Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
EHJ Ceased/non-payment of the annual fee