DE2013100A1 - Verbesserte Silber-Silberchlorid-Elektrode - Google Patents
Verbesserte Silber-Silberchlorid-ElektrodeInfo
- Publication number
- DE2013100A1 DE2013100A1 DE19702013100 DE2013100A DE2013100A1 DE 2013100 A1 DE2013100 A1 DE 2013100A1 DE 19702013100 DE19702013100 DE 19702013100 DE 2013100 A DE2013100 A DE 2013100A DE 2013100 A1 DE2013100 A1 DE 2013100A1
- Authority
- DE
- Germany
- Prior art keywords
- silver chloride
- silver
- layer
- chloride electrode
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 title description 3
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 56
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 55
- 239000010410 layer Substances 0.000 claims description 41
- 230000000694 effects Effects 0.000 claims description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 22
- 238000005259 measurement Methods 0.000 claims description 21
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 15
- 150000002500 ions Chemical class 0.000 claims description 13
- 230000035945 sensitivity Effects 0.000 claims description 13
- 230000032683 aging Effects 0.000 claims description 11
- 239000011241 protective layer Substances 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- 239000000523 sample Substances 0.000 claims description 6
- 238000002848 electrochemical method Methods 0.000 claims description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 230000001771 impaired effect Effects 0.000 claims 1
- 239000012768 molten material Substances 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 description 21
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 10
- 239000012086 standard solution Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 6
- -1 butyl-methacryl- Chemical group 0.000 description 3
- 230000007850 degeneration Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- FEPMHVLSLDOMQC-UHFFFAOYSA-N virginiamycin-S1 Natural products CC1OC(=O)C(C=2C=CC=CC=2)NC(=O)C2CC(=O)CCN2C(=O)C(CC=2C=CC=CC=2)N(C)C(=O)C2CCCN2C(=O)C(CC)NC(=O)C1NC(=O)C1=NC=CC=C1O FEPMHVLSLDOMQC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/301—Reference electrodes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/333—Ion-selective electrodes or membranes
- G01N27/3335—Ion-selective electrodes or membranes the membrane containing at least one organic component
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/333—Ion-selective electrodes or membranes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
- Y10T428/2942—Plural coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81860869A | 1969-04-23 | 1969-04-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2013100A1 true DE2013100A1 (de) | 1970-11-12 |
Family
ID=25225933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702013100 Pending DE2013100A1 (de) | 1969-04-23 | 1970-03-19 | Verbesserte Silber-Silberchlorid-Elektrode |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3591482A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS497517B1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE2013100A1 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2042946A5 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1242997A (cg-RX-API-DMAC7.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3247575A1 (de) * | 1981-12-22 | 1983-07-07 | Olympus Optical Co., Ltd., Tokyo | Elektrodenmesseinrichtung |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3856649A (en) * | 1973-03-16 | 1974-12-24 | Miles Lab | Solid state electrode |
| DE2503176C2 (de) * | 1975-01-27 | 1983-11-10 | Fresenius AG, 6380 Bad Homburg | Ionenselektive Elektrode |
| US4073053A (en) * | 1976-02-27 | 1978-02-14 | Honeywell Inc. | Method of making an ion responsive electrode |
| JPS5825221B2 (ja) * | 1977-12-12 | 1983-05-26 | 株式会社クラレ | Fet比較電極 |
| JPS54173796U (cg-RX-API-DMAC7.html) * | 1978-05-26 | 1979-12-07 | ||
| US4199412A (en) * | 1978-10-31 | 1980-04-22 | Eastman Kodak Company | Halide ion-selective devices and method |
| US4199411A (en) * | 1978-10-31 | 1980-04-22 | Eastman Kodak Company | Halide ion-selective devices and methods of determining halides |
| US4217195A (en) * | 1979-05-02 | 1980-08-12 | General Electric Company | Electrophoretic electrode for use in laser doppler shift spectroscopy, and method |
| US4259164A (en) * | 1979-08-13 | 1981-03-31 | Eastman Kodak Company | Silver/silver halide electrodes comprising chromium or nickel |
| US4263343A (en) * | 1979-08-13 | 1981-04-21 | Eastman Kodak Company | Reference elements for ion-selective membrane electrodes |
| US4340457A (en) * | 1980-01-28 | 1982-07-20 | Kater John A R | Ion selective electrodes |
| EP0101687A1 (en) * | 1982-02-22 | 1984-03-07 | Beckman Instruments, Inc. | Ion-selective electrode and method for making same |
| JPS607064U (ja) * | 1983-06-25 | 1985-01-18 | 株式会社 堀場製作所 | 流通型液膜電極 |
| JPS629264A (ja) * | 1985-07-05 | 1987-01-17 | Fuji Photo Film Co Ltd | イオン活量測定方法および測定器具 |
| JPS62169044A (ja) * | 1986-01-22 | 1987-07-25 | Fuji Photo Film Co Ltd | 塩素イオン選択電極 |
| US4876109A (en) * | 1987-04-13 | 1989-10-24 | Cardiac Pacemakers, Inc. | Soluble covering for cardiac pacing electrode |
| WO1989004959A1 (en) * | 1987-11-24 | 1989-06-01 | Terumo Kabushiki Kaisha | Reference electrode |
| US4933048A (en) * | 1988-02-16 | 1990-06-12 | I-Stat Corporation | Reference electrode, method of making and method of using same |
| US5405522A (en) * | 1994-03-10 | 1995-04-11 | Mannesmann Aktiengesellschaft | Reference electrode and method of making the same |
| US8574413B2 (en) | 2011-03-18 | 2013-11-05 | Digital Concepts Of Missouri, Inc. | Electrodes, sensors and methods for measuring components in water |
| DE102015005472A1 (de) * | 2015-04-29 | 2016-11-03 | Sartorius Stedim Biotech Gmbh | Schutzbeschichtung für eine potentiometrische Messkette |
-
1969
- 1969-04-23 US US818608A patent/US3591482A/en not_active Expired - Lifetime
-
1970
- 1970-03-12 GB GB01796/70A patent/GB1242997A/en not_active Expired
- 1970-03-19 DE DE19702013100 patent/DE2013100A1/de active Pending
- 1970-04-03 FR FR7012254A patent/FR2042946A5/fr not_active Expired
- 1970-04-14 JP JP45031287A patent/JPS497517B1/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3247575A1 (de) * | 1981-12-22 | 1983-07-07 | Olympus Optical Co., Ltd., Tokyo | Elektrodenmesseinrichtung |
Also Published As
| Publication number | Publication date |
|---|---|
| US3591482A (en) | 1971-07-06 |
| GB1242997A (en) | 1971-08-18 |
| FR2042946A5 (cg-RX-API-DMAC7.html) | 1971-02-12 |
| JPS497517B1 (cg-RX-API-DMAC7.html) | 1974-02-20 |
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