DE2008426A1 - - Google Patents
Info
- Publication number
- DE2008426A1 DE2008426A1 DE19702008426 DE2008426A DE2008426A1 DE 2008426 A1 DE2008426 A1 DE 2008426A1 DE 19702008426 DE19702008426 DE 19702008426 DE 2008426 A DE2008426 A DE 2008426A DE 2008426 A1 DE2008426 A1 DE 2008426A1
- Authority
- DE
- Germany
- Prior art keywords
- carbon atoms
- groups
- general formula
- molecular weight
- alkyl groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 125000004432 carbon atom Chemical group C* 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- -1 siloxanes Chemical class 0.000 claims description 9
- 125000005442 diisocyanate group Chemical group 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000000732 arylene group Chemical group 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 4
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 125000004001 thioalkyl group Chemical group 0.000 claims description 3
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 claims description 2
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 claims description 2
- 101150065749 Churc1 gene Proteins 0.000 claims description 2
- 102100038239 Protein Churchill Human genes 0.000 claims description 2
- 239000000010 aprotic solvent Substances 0.000 claims description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 2
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 238000007348 radical reaction Methods 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 8
- 229910018557 Si O Inorganic materials 0.000 claims 5
- 240000007124 Brassica oleracea Species 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 17
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229920006037 cross link polymer Polymers 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000004055 thiomethyl group Chemical group [H]SC([H])([H])* 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- NHVHYFAWHCJELN-UHFFFAOYSA-N benzene;n,n-dimethylformamide Chemical compound CN(C)C=O.C1=CC=CC=C1 NHVHYFAWHCJELN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000004662 dithiols Chemical class 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 125000004035 thiopropyl group Chemical group [H]SC([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS143469 | 1969-02-27 | ||
| CS143569 | 1969-02-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2008426A1 true DE2008426A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-09-10 |
Family
ID=25745427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19702008426 Pending DE2008426A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-02-27 | 1970-02-24 |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE2008426A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
| FR (1) | FR2033086A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2649854A1 (de) * | 1975-11-10 | 1977-05-12 | Sws Silicones Corp | Verfahren zur herstellung von thiofunktionelle gruppen aufweisenden organopolysiloxanen |
| US4107390A (en) | 1977-12-02 | 1978-08-15 | Dow Corning Corporation | Radiation-curable organopolysiloxane coating composition comprising mercaptoalkyl and silacyclopentenyl radicals, method of coating and article therefrom |
| FR2446850A1 (fr) * | 1979-01-18 | 1980-08-14 | Dow Corning | Procede de preparation d'un polydiorganosiloxane reticule |
| US4265792A (en) | 1979-12-03 | 1981-05-05 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes and stannic salts of carboxylic acids |
| US4268655A (en) | 1979-12-03 | 1981-05-19 | Dow Corning Corporation | Ferrocene catalyzed elastomer formation |
| US4269963A (en) | 1979-12-03 | 1981-05-26 | Dow Corning Corporation | Mercaptoorganopolysiloxanes and curable compositions including same |
| US4272415A (en) | 1979-12-03 | 1981-06-09 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes and metal salts of carboxylic acids |
| US4272623A (en) | 1979-12-03 | 1981-06-09 | Dow Corning Corporation | Mercaptoorganopolysiloxane elastomers catalyzed by metallic compounds in the presence of peroxides |
| US4279792A (en) | 1979-12-03 | 1981-07-21 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes and stannous salts of carboxylic acids |
| US4284539A (en) | 1979-12-03 | 1981-08-18 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes, aliphatically unsaturated polydiorganosiloxanes and carboxylic acid salts of metals |
| EP0237757A3 (de) * | 1986-02-06 | 1990-01-24 | Wacker-Chemie GmbH | Durch Strahlung zu Elastomeren vernetzbare Massen |
| US5378790A (en) * | 1992-09-16 | 1995-01-03 | E. I. Du Pont De Nemours & Co. | Single component inorganic/organic network materials and precursors thereof |
| CN105849175A (zh) * | 2013-12-27 | 2016-08-10 | 株式会社普利司通 | 由包含巯基官能化硅氧烷的组合物制备的硫化橡胶和轮胎组件 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4002794A (en) * | 1975-07-18 | 1977-01-11 | Nashua Corporation | Adhesive material and articles incorporating same |
-
1970
- 1970-02-24 DE DE19702008426 patent/DE2008426A1/de active Pending
- 1970-02-26 FR FR7006887A patent/FR2033086A5/fr not_active Expired
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2649854A1 (de) * | 1975-11-10 | 1977-05-12 | Sws Silicones Corp | Verfahren zur herstellung von thiofunktionelle gruppen aufweisenden organopolysiloxanen |
| US4107390A (en) | 1977-12-02 | 1978-08-15 | Dow Corning Corporation | Radiation-curable organopolysiloxane coating composition comprising mercaptoalkyl and silacyclopentenyl radicals, method of coating and article therefrom |
| FR2446850A1 (fr) * | 1979-01-18 | 1980-08-14 | Dow Corning | Procede de preparation d'un polydiorganosiloxane reticule |
| US4234697A (en) | 1979-01-18 | 1980-11-18 | Dow Corning Corporation | Method of preparing cross-linked polydiorganosiloxane using organic isocyanates and products prepared therefrom |
| US4265792A (en) | 1979-12-03 | 1981-05-05 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes and stannic salts of carboxylic acids |
| US4268655A (en) | 1979-12-03 | 1981-05-19 | Dow Corning Corporation | Ferrocene catalyzed elastomer formation |
| US4269963A (en) | 1979-12-03 | 1981-05-26 | Dow Corning Corporation | Mercaptoorganopolysiloxanes and curable compositions including same |
| US4272415A (en) | 1979-12-03 | 1981-06-09 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes and metal salts of carboxylic acids |
| US4272623A (en) | 1979-12-03 | 1981-06-09 | Dow Corning Corporation | Mercaptoorganopolysiloxane elastomers catalyzed by metallic compounds in the presence of peroxides |
| US4279792A (en) | 1979-12-03 | 1981-07-21 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes and stannous salts of carboxylic acids |
| US4284539A (en) | 1979-12-03 | 1981-08-18 | Dow Corning Corporation | Compositions including mercaptoorganopolysiloxanes, aliphatically unsaturated polydiorganosiloxanes and carboxylic acid salts of metals |
| EP0237757A3 (de) * | 1986-02-06 | 1990-01-24 | Wacker-Chemie GmbH | Durch Strahlung zu Elastomeren vernetzbare Massen |
| US5378790A (en) * | 1992-09-16 | 1995-01-03 | E. I. Du Pont De Nemours & Co. | Single component inorganic/organic network materials and precursors thereof |
| US5548051A (en) * | 1992-09-16 | 1996-08-20 | E. I Du Pont De Nemours And Company | Single component inorganic/organic network materials and precursors thereof |
| CN105849175A (zh) * | 2013-12-27 | 2016-08-10 | 株式会社普利司通 | 由包含巯基官能化硅氧烷的组合物制备的硫化橡胶和轮胎组件 |
| US10150845B2 (en) | 2013-12-27 | 2018-12-11 | Bridgestone Corporation | Vulcanizates and tire components prepared from compositions including mercapto-functional siloxanes |
| US10662298B2 (en) | 2013-12-27 | 2020-05-26 | Bridgestone Corporation | Vulcanizates and tire components prepared from compositions including mercapto-functional siloxanes |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2033086A5 (en) | 1970-11-27 |
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