DE19962130A1 - Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien - Google Patents
Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten FolienInfo
- Publication number
- DE19962130A1 DE19962130A1 DE19962130A DE19962130A DE19962130A1 DE 19962130 A1 DE19962130 A1 DE 19962130A1 DE 19962130 A DE19962130 A DE 19962130A DE 19962130 A DE19962130 A DE 19962130A DE 19962130 A1 DE19962130 A1 DE 19962130A1
- Authority
- DE
- Germany
- Prior art keywords
- temperature
- weight
- propylene polymer
- fractions
- polymer composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 122
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 107
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- -1 propylene, ethylene Chemical group 0.000 claims abstract description 31
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 21
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 9
- 238000000465 moulding Methods 0.000 claims abstract description 9
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims description 64
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 27
- 239000008096 xylene Substances 0.000 claims description 27
- 238000002844 melting Methods 0.000 claims description 23
- 230000008018 melting Effects 0.000 claims description 23
- 238000010828 elution Methods 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 20
- 238000005227 gel permeation chromatography Methods 0.000 claims description 19
- 238000010438 heat treatment Methods 0.000 claims description 19
- 238000005194 fractionation Methods 0.000 claims description 15
- 238000009826 distribution Methods 0.000 claims description 14
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 6
- 230000000630 rising effect Effects 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 238000011156 evaluation Methods 0.000 claims description 5
- 238000012512 characterization method Methods 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 description 23
- 239000007789 gas Substances 0.000 description 18
- 229940095050 propylene Drugs 0.000 description 18
- 239000010936 titanium Substances 0.000 description 17
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 229910052719 titanium Inorganic materials 0.000 description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 13
- 239000005977 Ethylene Substances 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 13
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 12
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 12
- 239000000155 melt Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 239000013078 crystal Substances 0.000 description 8
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
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- 239000002904 solvent Substances 0.000 description 5
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- 239000011777 magnesium Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
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- 230000003287 optical effect Effects 0.000 description 4
- 239000005026 oriented polypropylene Substances 0.000 description 4
- 229920001384 propylene homopolymer Polymers 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
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- 230000035699 permeability Effects 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000012967 coordination catalyst Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
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- 150000008040 ionic compounds Chemical class 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 1
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- WGAGZUJPKROMTJ-UHFFFAOYSA-N 3-(3,5-ditert-butylphenyl)-2-hydroxypropanoic acid Chemical compound CC(C)(C)C1=CC(CC(O)C(O)=O)=CC(C(C)(C)C)=C1 WGAGZUJPKROMTJ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- NWYAYUUUUMPAEF-UHFFFAOYSA-N C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C Chemical compound C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C.C=C(C(C(=O)O)O)C1=CC(=CC(=C1)C(C)(C)C)C(C)(C)C NWYAYUUUUMPAEF-UHFFFAOYSA-N 0.000 description 1
- RGPSRYWDFHAWOT-UHFFFAOYSA-N CCCCCCCC[Mg]CCCC Chemical compound CCCCCCCC[Mg]CCCC RGPSRYWDFHAWOT-UHFFFAOYSA-N 0.000 description 1
- 241000408710 Hansa Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
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- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
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- 238000005336 cracking Methods 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
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- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229920001580 isotactic polymer Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
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- 229920006301 statistical copolymer Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 210000002105 tongue Anatomy 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
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- 239000003643 water by type Substances 0.000 description 1
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- 238000005303 weighing Methods 0.000 description 1
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- 150000003751 zinc Chemical class 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/90—Direct application of fluid pressure differential to shape, reshape, i.e. distort, or sustain an article or preform and heat-setting, i.e. crystallizing of stretched or molecularly oriented portion thereof
- Y10S264/901—Heat-setting of stretched or molecularly oriented article formed from planar preform, e.g. sheet, film
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/91—Product with molecular orientation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Artificial Filaments (AREA)
Priority Applications (21)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19962130A DE19962130A1 (de) | 1999-12-21 | 1999-12-21 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
| BR0016590-5A BR0016590A (pt) | 1999-12-21 | 2000-12-11 | Composição semicristalina de polìmero de propileno, processo para preparar a mesma, uso da mesma, pelìcula, fibra ou moldagem, e, pelìcula biaxialmente estirada |
| CNB008183368A CN1222550C (zh) | 1999-12-21 | 2000-12-11 | 用于制备双轴拉伸聚丙烯膜的半结晶丙烯聚合物组合物 |
| JP2001547181A JP5121108B2 (ja) | 1999-12-21 | 2000-12-11 | 二軸延伸ポリプロピレンフィルム製造用の半結晶性プロピレンポリマー組成物 |
| AT00981361T ATE318276T1 (de) | 1999-12-21 | 2000-12-11 | Teilkristalline propylenpolymerisat- zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
| PL00355712A PL355712A1 (en) | 1999-12-21 | 2000-12-11 | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
| EP00981361A EP1252202B1 (de) | 1999-12-21 | 2000-12-11 | Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
| US10/168,215 US20030130443A1 (en) | 1999-12-21 | 2000-12-11 | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
| KR1020027008080A KR20020062984A (ko) | 1999-12-21 | 2000-12-11 | 이축 연신 폴리프로필렌 필름 제조용의 반정질 프로필렌중합체 조성물 |
| RU2002120467/04A RU2002120467A (ru) | 1999-12-21 | 2000-12-11 | Частично кристаллическая пропилен-полимерная композиция для получения биаксиально вытянутых полипропиленовых пленок |
| DE50012267T DE50012267D1 (de) | 1999-12-21 | 2000-12-11 | Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
| AU18632/01A AU1863201A (en) | 1999-12-21 | 2000-12-11 | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
| PCT/EP2000/012511 WO2001046274A1 (de) | 1999-12-21 | 2000-12-11 | Teilkristalline propylenpolymerisat-zusammensetzung zur herstellung von biaxial gereckten polypropylenfolien |
| CA002395218A CA2395218A1 (en) | 1999-12-21 | 2000-12-11 | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
| EP00127654A EP1110976B1 (de) | 1999-12-21 | 2000-12-18 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
| DE50012976T DE50012976D1 (de) | 1999-12-21 | 2000-12-18 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
| AT00127654T ATE329942T1 (de) | 1999-12-21 | 2000-12-18 | Teilkristalline propylenpolymerisat- zusammensetzungen mit guter eignung zur herstellung von biaxial orientierten folien |
| US09/737,848 US6593442B2 (en) | 1999-12-21 | 2000-12-18 | Semicrystalline propylene polymer compositions with good suitability for producing biaxially oriented films |
| JP2000387995A JP2001247729A (ja) | 1999-12-21 | 2000-12-21 | 2軸配向フィルムに好適な半結晶性プロピレン重合体組成物 |
| US11/624,606 US7816456B2 (en) | 1999-12-21 | 2007-01-18 | Semicrystalline propylene polymer composition for producing biaxially stretched polypropylene films |
| JP2012181351A JP5719332B2 (ja) | 1999-12-21 | 2012-08-20 | 二軸延伸ポリプロピレンフィルム製造用の半結晶性プロピレンポリマー組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19962130A DE19962130A1 (de) | 1999-12-21 | 1999-12-21 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19962130A1 true DE19962130A1 (de) | 2001-07-05 |
Family
ID=7933883
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19962130A Withdrawn DE19962130A1 (de) | 1999-12-21 | 1999-12-21 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
| DE50012976T Expired - Lifetime DE50012976D1 (de) | 1999-12-21 | 2000-12-18 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE50012976T Expired - Lifetime DE50012976D1 (de) | 1999-12-21 | 2000-12-18 | Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6593442B2 (enExample) |
| EP (1) | EP1110976B1 (enExample) |
| JP (1) | JP2001247729A (enExample) |
| AT (1) | ATE329942T1 (enExample) |
| DE (2) | DE19962130A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7732530B2 (en) * | 2002-06-12 | 2010-06-08 | Basell Polyolefine Gmbh | Flexible propylene copolymer compositions having a high transparency |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004516373A (ja) * | 2000-12-22 | 2004-06-03 | バセル ポリオレフィン イタリア エス.ピー.エー. | 熱成形用ポリオレフィンシート |
| JP2002294010A (ja) * | 2001-03-30 | 2002-10-09 | Sumitomo Chem Co Ltd | 延伸フィルム用ポリプロピレン系樹脂組成物および延伸フィルム |
| EP1270627B1 (en) | 2001-06-27 | 2005-01-12 | Borealis Technology Oy | Propylene polymer resin with improved properties |
| US20060167185A1 (en) * | 2002-06-12 | 2006-07-27 | Basell Polyolefine Gmbh | Propylene copolymer compositions having a good low-temperature impact toughness and a high transparency |
| CN1294160C (zh) | 2002-07-24 | 2007-01-10 | 巴塞尔聚烯烃股份有限公司 | 丙烯聚合物组合物的至少两阶段制备工艺 |
| EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US6995213B2 (en) * | 2003-09-29 | 2006-02-07 | Fina Technology, Inc. | Oriented films prepared using impact copolymer polypropylene |
| US7217772B2 (en) * | 2005-03-25 | 2007-05-15 | Sunoco, Inc. (R&M) | Process for production of propylene homopolymers |
| PL2152768T3 (pl) * | 2007-05-22 | 2013-01-31 | Borealis Tech Oy | Kopolimer polipropylenu |
| FR2994510B1 (fr) * | 2012-08-09 | 2014-08-08 | Renault Sa | Procede pour la preparation de materiaux actifs proteges partiellement en surface pour des batteries au lithium |
| WO2022081271A1 (en) | 2020-10-13 | 2022-04-21 | Cabot Corporation | Conductive photo-curable compositions for additive manufacturing |
| JP7596127B2 (ja) | 2020-11-25 | 2024-12-09 | 住友化学株式会社 | プロピレン重合体組成物、および、フィルム |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3461811D1 (en) | 1983-01-25 | 1987-02-05 | Mitsui Petrochemical Ind | Film-forming propylene copolymer, film thereof and process for production of the film |
| US4950720A (en) | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
| IT1240417B (it) | 1990-02-28 | 1993-12-15 | Himont Inc | Procedimento per la produzione di film e corpi laminari polipropilenici e prodotti cosi' ottenuti |
| EP0657476B2 (en) | 1993-12-06 | 2007-12-19 | Sumitomo Chemical Company, Limited | Alpha-olefin polymers, alpha-olefin polymerizing catalyst and process for producing alpha-olefin polymers |
| WO1996020225A2 (en) | 1994-12-20 | 1996-07-04 | Montell Technology Company B.V. | Reactor blend polypropylene, process for the preparation thereof and process for preparing metallocene ligands |
| JPH1053675A (ja) | 1996-08-09 | 1998-02-24 | Sumitomo Chem Co Ltd | 延伸フィルム用ポリプロピレン系樹脂組成物 |
| DE19710761A1 (de) * | 1997-03-14 | 1998-09-17 | Basf Ag | Hochkristalline Propylenhomopolymerisate |
| IT1292138B1 (it) | 1997-06-12 | 1999-01-25 | Montell Technology Company Bv | Film multistrato estensibili |
| JP4037468B2 (ja) | 1997-06-24 | 2008-01-23 | ボレアリス エー/エス | プロピレンを含む異相ポリマーの製造方法 |
| DE19726796A1 (de) * | 1997-06-24 | 1999-01-07 | Basf Ag | Propylenpolymerisate |
| JP4748827B2 (ja) * | 1997-08-20 | 2011-08-17 | 電気化学工業株式会社 | ストレッチフィルム用軟質フィルム |
| FI973816A0 (fi) * | 1997-09-26 | 1997-09-26 | Borealis As | Polypropen med hoeg smaeltstyrka |
-
1999
- 1999-12-21 DE DE19962130A patent/DE19962130A1/de not_active Withdrawn
-
2000
- 2000-12-18 DE DE50012976T patent/DE50012976D1/de not_active Expired - Lifetime
- 2000-12-18 EP EP00127654A patent/EP1110976B1/de not_active Expired - Lifetime
- 2000-12-18 AT AT00127654T patent/ATE329942T1/de active
- 2000-12-18 US US09/737,848 patent/US6593442B2/en not_active Expired - Lifetime
- 2000-12-21 JP JP2000387995A patent/JP2001247729A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7732530B2 (en) * | 2002-06-12 | 2010-06-08 | Basell Polyolefine Gmbh | Flexible propylene copolymer compositions having a high transparency |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001247729A (ja) | 2001-09-11 |
| ATE329942T1 (de) | 2006-07-15 |
| DE50012976D1 (de) | 2006-07-27 |
| EP1110976B1 (de) | 2006-06-14 |
| US6593442B2 (en) | 2003-07-15 |
| EP1110976A1 (de) | 2001-06-27 |
| US20010004662A1 (en) | 2001-06-21 |
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