DE19949592A1 - Thermisch härtbare Polymerdipersion - Google Patents
Thermisch härtbare PolymerdipersionInfo
- Publication number
- DE19949592A1 DE19949592A1 DE19949592A DE19949592A DE19949592A1 DE 19949592 A1 DE19949592 A1 DE 19949592A1 DE 19949592 A DE19949592 A DE 19949592A DE 19949592 A DE19949592 A DE 19949592A DE 19949592 A1 DE19949592 A1 DE 19949592A1
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- weight
- acid
- polymer dispersion
- dispersion according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004815 dispersion polymer Substances 0.000 title claims abstract description 49
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims description 126
- 239000000203 mixture Substances 0.000 claims description 87
- 239000011230 binding agent Substances 0.000 claims description 75
- 239000000835 fiber Substances 0.000 claims description 47
- 239000000178 monomer Substances 0.000 claims description 42
- 150000001412 amines Chemical class 0.000 claims description 33
- 238000006243 chemical reaction Methods 0.000 claims description 31
- 150000002148 esters Chemical class 0.000 claims description 25
- 239000004971 Cross linker Substances 0.000 claims description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 17
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 16
- 239000007799 cork Substances 0.000 claims description 15
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000003365 glass fiber Substances 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 12
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 11
- 229920002522 Wood fibre Polymers 0.000 claims description 11
- 239000002025 wood fiber Substances 0.000 claims description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 10
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 10
- 239000002023 wood Substances 0.000 claims description 10
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 9
- 150000003973 alkyl amines Chemical class 0.000 claims description 7
- 150000005690 diesters Chemical class 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000011976 maleic acid Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 5
- 239000001530 fumaric acid Substances 0.000 claims description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 239000002557 mineral fiber Substances 0.000 claims description 4
- 239000004753 textile Substances 0.000 claims description 4
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 3
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 3
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 3
- 150000002431 hydrogen Chemical group 0.000 claims 1
- 239000006185 dispersion Substances 0.000 abstract description 29
- 238000004519 manufacturing process Methods 0.000 abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 63
- -1 vinyl aromatic compounds Chemical class 0.000 description 39
- 239000002253 acid Substances 0.000 description 30
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 27
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 24
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 18
- 239000007864 aqueous solution Substances 0.000 description 16
- 239000004745 nonwoven fabric Substances 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 14
- 150000003254 radicals Chemical class 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 238000001723 curing Methods 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
- 238000001035 drying Methods 0.000 description 10
- 229920000126 latex Polymers 0.000 description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000011521 glass Substances 0.000 description 9
- 238000009413 insulation Methods 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 8
- 239000004816 latex Substances 0.000 description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 6
- 239000002609 medium Substances 0.000 description 6
- 150000003077 polyols Chemical class 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical class CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 5
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 150000008064 anhydrides Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 5
- 238000007046 ethoxylation reaction Methods 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229940063557 methacrylate Drugs 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000008961 swelling Effects 0.000 description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- 244000198134 Agave sisalana Species 0.000 description 4
- 235000011777 Corchorus aestuans Nutrition 0.000 description 4
- 235000010862 Corchorus capsularis Nutrition 0.000 description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 4
- 239000004908 Emulsion polymer Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000011093 chipboard Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000011094 fiberboard Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 3
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- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- 240000006240 Linum usitatissimum Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
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Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19949592A DE19949592A1 (de) | 1999-10-14 | 1999-10-14 | Thermisch härtbare Polymerdipersion |
| ES00967867T ES2231273T3 (es) | 1999-10-14 | 2000-10-13 | Dispersion plimera termicamente endurecible. |
| KR1020027004775A KR100747905B1 (ko) | 1999-10-14 | 2000-10-13 | 열경화성 중합체 분산액 |
| AT00967867T ATE261456T1 (de) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
| BRPI0014703-6A BR0014703B1 (pt) | 1999-10-14 | 2000-10-13 | dispersão polimérica aquosa, processo para preparação da mesma, substrato ligado, e, uso de uma dispersão polimérica aquosa. |
| MXPA02003692 MX225920B (es) | 1999-10-14 | 2000-10-13 | Dispersion polimerica termoendurecedora. |
| PCT/EP2000/010108 WO2001027163A1 (de) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
| EP00967867A EP1240205B1 (de) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
| JP2001530381A JP4987202B2 (ja) | 1999-10-14 | 2000-10-13 | 熱硬化性ポリマー分散液 |
| DE50005625T DE50005625D1 (en) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
| US10/110,106 US6841608B1 (en) | 1999-10-14 | 2000-10-13 | Thermohardening polymer dispersion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19949592A DE19949592A1 (de) | 1999-10-14 | 1999-10-14 | Thermisch härtbare Polymerdipersion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19949592A1 true DE19949592A1 (de) | 2001-04-19 |
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| DE19949592A Withdrawn DE19949592A1 (de) | 1999-10-14 | 1999-10-14 | Thermisch härtbare Polymerdipersion |
| DE50005625T Expired - Lifetime DE50005625D1 (en) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE50005625T Expired - Lifetime DE50005625D1 (en) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6841608B1 (https=) |
| EP (1) | EP1240205B1 (https=) |
| JP (1) | JP4987202B2 (https=) |
| KR (1) | KR100747905B1 (https=) |
| AT (1) | ATE261456T1 (https=) |
| BR (1) | BR0014703B1 (https=) |
| DE (2) | DE19949592A1 (https=) |
| ES (1) | ES2231273T3 (https=) |
| MX (1) | MX225920B (https=) |
| WO (1) | WO2001027163A1 (https=) |
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| EP1260530A1 (de) * | 2001-05-22 | 2002-11-27 | Basf Aktiengesellschaft | Thermisch härtbare Bindemittel |
| DE10247847A1 (de) * | 2002-10-14 | 2004-04-22 | Bollig & Kemper Gmbh & Co. Kg | Phosphonsäuremodifizierte Mikrogeldispersion |
| US7001528B2 (en) | 2003-03-11 | 2006-02-21 | Basf Aktiengesellschaft | Use of aqueous binders in producing filter materials |
| US7008312B2 (en) | 2003-02-06 | 2006-03-07 | Basf Aktiengesellschaft | Using aqueous binders in producing abrasive materials |
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-
1999
- 1999-10-14 DE DE19949592A patent/DE19949592A1/de not_active Withdrawn
-
2000
- 2000-10-13 BR BRPI0014703-6A patent/BR0014703B1/pt not_active IP Right Cessation
- 2000-10-13 KR KR1020027004775A patent/KR100747905B1/ko not_active Expired - Fee Related
- 2000-10-13 AT AT00967867T patent/ATE261456T1/de active
- 2000-10-13 MX MXPA02003692 patent/MX225920B/es active IP Right Grant
- 2000-10-13 US US10/110,106 patent/US6841608B1/en not_active Expired - Lifetime
- 2000-10-13 EP EP00967867A patent/EP1240205B1/de not_active Expired - Lifetime
- 2000-10-13 WO PCT/EP2000/010108 patent/WO2001027163A1/de not_active Ceased
- 2000-10-13 DE DE50005625T patent/DE50005625D1/de not_active Expired - Lifetime
- 2000-10-13 JP JP2001530381A patent/JP4987202B2/ja not_active Expired - Fee Related
- 2000-10-13 ES ES00967867T patent/ES2231273T3/es not_active Expired - Lifetime
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1260530A1 (de) * | 2001-05-22 | 2002-11-27 | Basf Aktiengesellschaft | Thermisch härtbare Bindemittel |
| US6730729B2 (en) | 2001-05-22 | 2004-05-04 | Basf Aktiengesellschaft | Heat curable binders |
| US7323242B2 (en) | 2001-10-23 | 2008-01-29 | Basf Aktiengesellschaft | Thermally curable binding agents |
| DE10247847A1 (de) * | 2002-10-14 | 2004-04-22 | Bollig & Kemper Gmbh & Co. Kg | Phosphonsäuremodifizierte Mikrogeldispersion |
| US7550206B2 (en) | 2002-10-14 | 2009-06-23 | Bollig & Kemper Gmbh & Co. Kg | Phosphonic acid-modified microgel dispersion |
| US7008312B2 (en) | 2003-02-06 | 2006-03-07 | Basf Aktiengesellschaft | Using aqueous binders in producing abrasive materials |
| US7001528B2 (en) | 2003-03-11 | 2006-02-21 | Basf Aktiengesellschaft | Use of aqueous binders in producing filter materials |
| US7399818B2 (en) | 2004-03-16 | 2008-07-15 | Rohm And Haas Company | Curable composition and use thereof |
| US8038014B2 (en) | 2005-02-03 | 2011-10-18 | Basf Aktiengesellschaft | Use of an aqueous polymer dispersion as a binding agent for cellulose fibers and for the production of filter materials |
| WO2012031922A1 (de) | 2010-09-10 | 2012-03-15 | Basf Se | Mehrschichtige lignocellulosehaltige formkörper mit geringer formaldehydemission |
| WO2012080338A1 (de) | 2010-12-17 | 2012-06-21 | Basf Se | Mehrschichtige lignocellulosehaltige formkörper mit geringer formaldehydemission |
| US10391669B2 (en) | 2014-01-13 | 2019-08-27 | Basf Se | Method for the production of lignocellulose materials |
| WO2016156226A1 (de) | 2015-03-27 | 2016-10-06 | Basf Se | Verfahren zur herstellung von lignocellulosewerkstoffen |
| US10399246B2 (en) | 2015-03-27 | 2019-09-03 | Basf Se | Method for producing lignocellulose materials |
| WO2018054732A1 (de) | 2016-09-23 | 2018-03-29 | Basf Se | Verfahren zur herstellung von lignocellulosewerkstoffen |
| US10876001B2 (en) | 2016-09-23 | 2020-12-29 | Basf Se | Method for producing lignocellulose materials |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1240205B1 (de) | 2004-03-10 |
| EP1240205A1 (de) | 2002-09-18 |
| JP4987202B2 (ja) | 2012-07-25 |
| MX225920B (es) | 2005-01-31 |
| BR0014703A (pt) | 2002-06-18 |
| DE50005625D1 (en) | 2004-04-15 |
| KR100747905B1 (ko) | 2007-08-08 |
| BR0014703B1 (pt) | 2011-10-18 |
| ES2231273T3 (es) | 2005-05-16 |
| JP2003511520A (ja) | 2003-03-25 |
| MXPA02003692A (es) | 2002-08-30 |
| ATE261456T1 (de) | 2004-03-15 |
| WO2001027163A1 (de) | 2001-04-19 |
| US6841608B1 (en) | 2005-01-11 |
| KR20020041457A (ko) | 2002-06-01 |
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