DE1808745A1 - Verfahren und Vorrichtung zur saeulenchromatographischen Analyse von Stoffgemischen - Google Patents
Verfahren und Vorrichtung zur saeulenchromatographischen Analyse von StoffgemischenInfo
- Publication number
- DE1808745A1 DE1808745A1 DE19681808745 DE1808745A DE1808745A1 DE 1808745 A1 DE1808745 A1 DE 1808745A1 DE 19681808745 DE19681808745 DE 19681808745 DE 1808745 A DE1808745 A DE 1808745A DE 1808745 A1 DE1808745 A1 DE 1808745A1
- Authority
- DE
- Germany
- Prior art keywords
- column
- columns
- mixture
- sample
- constituent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 56
- 238000000034 method Methods 0.000 title claims description 25
- 238000004587 chromatography analysis Methods 0.000 title claims description 15
- 239000000126 substance Substances 0.000 title claims description 15
- 239000000470 constituent Substances 0.000 claims description 41
- 239000000463 material Substances 0.000 claims description 22
- 238000004458 analytical method Methods 0.000 claims description 18
- 238000003795 desorption Methods 0.000 claims description 18
- 239000012188 paraffin wax Substances 0.000 claims description 14
- 239000012159 carrier gas Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 13
- 238000011049 filling Methods 0.000 claims description 12
- 238000011068 loading method Methods 0.000 claims description 10
- 239000001307 helium Substances 0.000 claims description 9
- 229910052734 helium Inorganic materials 0.000 claims description 9
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 230000008929 regeneration Effects 0.000 claims description 7
- 238000011069 regeneration method Methods 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000001179 sorption measurement Methods 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 230000000717 retained effect Effects 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 238000004440 column chromatography Methods 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 239000011261 inert gas Substances 0.000 claims 2
- 230000003111 delayed effect Effects 0.000 claims 1
- 239000000523 sample Substances 0.000 description 82
- 239000007789 gas Substances 0.000 description 21
- 238000010926 purge Methods 0.000 description 16
- 239000002808 molecular sieve Substances 0.000 description 10
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 10
- 238000013461 design Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000003463 adsorbent Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000010828 elution Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 241000209202 Bromus secalinus Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001331845 Equus asinus x caballus Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- JOWRFSPJFXLGGY-UHFFFAOYSA-N rimazolium Chemical compound C1CCC(C)N2C(=O)C(C(=O)OCC)=C[N+](C)=C21 JOWRFSPJFXLGGY-UHFFFAOYSA-N 0.000 description 1
- 230000036186 satiety Effects 0.000 description 1
- 235000019627 satiety Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- BLFQGGGGFNSJKA-XHXSRVRCSA-N sertraline hydrochloride Chemical compound Cl.C1([C@@H]2CC[C@@H](C3=CC=CC=C32)NC)=CC=C(Cl)C(Cl)=C1 BLFQGGGGFNSJKA-XHXSRVRCSA-N 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000004347 surface barrier Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/26—Conditioning of the fluid carrier; Flow patterns
- G01N30/38—Flow patterns
- G01N30/46—Flow patterns using more than one column
- G01N30/466—Flow patterns using more than one column with separation columns in parallel
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/16—Injection
Landscapes
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Sampling And Sample Adjustment (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68349767A | 1967-11-16 | 1967-11-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1808745A1 true DE1808745A1 (de) | 1969-09-04 |
Family
ID=24744298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19681808745 Pending DE1808745A1 (de) | 1967-11-16 | 1968-11-14 | Verfahren und Vorrichtung zur saeulenchromatographischen Analyse von Stoffgemischen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3550429A (https=) |
| BE (1) | BE723800A (https=) |
| BR (1) | BR6803984D0 (https=) |
| DE (1) | DE1808745A1 (https=) |
| ES (1) | ES360263A1 (https=) |
| FR (1) | FR1593182A (https=) |
| GB (1) | GB1230202A (https=) |
| NL (1) | NL6816253A (https=) |
| NO (1) | NO131622C (https=) |
| SE (1) | SE357307B (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1272638A (en) * | 1969-05-22 | 1972-05-03 | Shell Int Research | Chromatographic apparatus |
| US4086051A (en) * | 1972-03-07 | 1978-04-25 | Srivas Rangachar Srinivas | System for preparing packed columns and coated capillary tubes useful in gas chromatography |
| US3879181A (en) * | 1972-03-09 | 1975-04-22 | Showa Denko Kk | Gas chromatograph, specimen capsule for use therein and process for gas chromatography |
| US3881892A (en) * | 1972-04-28 | 1975-05-06 | Charles W Gehrke | Chromatograph system and method |
| US4154583A (en) * | 1977-10-25 | 1979-05-15 | Phillips Petroleum Company | Automated temperature programmed preparative chromatography |
| US4279618A (en) * | 1980-06-03 | 1981-07-21 | Versar, Inc. | Method and apparatus for analysis of total atmospheric sulfuric acid content |
| GB2116710A (en) * | 1982-03-12 | 1983-09-28 | Secr Defence | Detection of arson accelerants |
| US4553985A (en) * | 1984-02-24 | 1985-11-19 | Phillips Petroleum Company | Gas chromatography |
| US4869876A (en) * | 1984-04-30 | 1989-09-26 | International Business Machines Corp. | Multi-purpose plural-oven gas chromatography system with shared controls |
| DE3932282A1 (de) * | 1989-09-27 | 1991-04-04 | Hollingsworth Gmbh | Vorrichtung zum oeffnen und reinigen von fasergut |
| JP2002147948A (ja) * | 2000-11-10 | 2002-05-22 | Japan Organo Co Ltd | ガス分離装置及びガス分離方法 |
| US8021468B2 (en) * | 2008-06-23 | 2011-09-20 | Siemens Medical Solutions Usa, Inc. | Room temperature chemical trap for the purification of gaseous methane |
| CN104698115A (zh) * | 2015-02-09 | 2015-06-10 | 沈阳石蜡化工有限公司 | 液体石蜡正构烷烃含量测定法 |
| CN106124663B (zh) * | 2016-07-29 | 2019-04-02 | 黑龙江省劳动安全科学技术研究中心 | 一种空气中二氧化碳含量的检测方法 |
| US12360088B2 (en) * | 2020-02-21 | 2025-07-15 | Shimadzu Corporation | Liquid chromatograph |
| CN114047276B (zh) * | 2022-01-17 | 2022-04-15 | 华谱科仪(北京)科技有限公司 | 色谱仪控制方法及装置 |
-
1967
- 1967-11-16 US US683497A patent/US3550429A/en not_active Expired - Lifetime
-
1968
- 1968-10-29 GB GB1230202D patent/GB1230202A/en not_active Expired
- 1968-11-13 BR BR203984/68A patent/BR6803984D0/pt unknown
- 1968-11-13 BE BE723800D patent/BE723800A/xx unknown
- 1968-11-14 ES ES360263A patent/ES360263A1/es not_active Expired
- 1968-11-14 DE DE19681808745 patent/DE1808745A1/de active Pending
- 1968-11-14 NL NL6816253A patent/NL6816253A/xx unknown
- 1968-11-15 NO NO4548/68A patent/NO131622C/no unknown
- 1968-11-15 SE SE15572/68A patent/SE357307B/xx unknown
- 1968-11-15 FR FR1593182D patent/FR1593182A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE357307B (https=) | 1973-06-25 |
| BR6803984D0 (pt) | 1973-05-10 |
| US3550429A (en) | 1970-12-29 |
| BE723800A (https=) | 1969-05-13 |
| NO131622B (https=) | 1975-03-17 |
| NL6816253A (https=) | 1969-05-20 |
| NO131622C (https=) | 1975-06-25 |
| FR1593182A (https=) | 1970-05-25 |
| GB1230202A (https=) | 1971-04-28 |
| ES360263A1 (es) | 1970-07-01 |
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