DE1696546B2 - Wiederaufladbares galvanisches thermalelement und verfahren zur herstellung einer elektrode dafuer - Google Patents
Wiederaufladbares galvanisches thermalelement und verfahren zur herstellung einer elektrode dafuerInfo
- Publication number
- DE1696546B2 DE1696546B2 DE1967ST026338 DEST026338A DE1696546B2 DE 1696546 B2 DE1696546 B2 DE 1696546B2 DE 1967ST026338 DE1967ST026338 DE 1967ST026338 DE ST026338 A DEST026338 A DE ST026338A DE 1696546 B2 DE1696546 B2 DE 1696546B2
- Authority
- DE
- Germany
- Prior art keywords
- electrode
- lithium
- aluminum
- cell
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 32
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 claims description 22
- 229910001148 Al-Li alloy Inorganic materials 0.000 claims description 21
- 229910052744 lithium Inorganic materials 0.000 claims description 20
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 13
- 238000007599 discharging Methods 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- -1 lithium halide salt Chemical class 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910001508 alkali metal halide Inorganic materials 0.000 claims description 2
- 150000008045 alkali metal halides Chemical class 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 210000004027 cell Anatomy 0.000 description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 28
- 238000004146 energy storage Methods 0.000 description 23
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 14
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 10
- 238000001994 activation Methods 0.000 description 9
- 230000004913 activation Effects 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 7
- 239000001103 potassium chloride Substances 0.000 description 7
- 235000011164 potassium chloride Nutrition 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 210000000352 storage cell Anatomy 0.000 description 6
- 230000005496 eutectics Effects 0.000 description 5
- 239000001989 lithium alloy Substances 0.000 description 5
- HCQWRNRRURULEY-UHFFFAOYSA-L lithium;potassium;dichloride Chemical compound [Li+].[Cl-].[Cl-].[K+] HCQWRNRRURULEY-UHFFFAOYSA-L 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 210000001787 dendrite Anatomy 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 208000032544 Cicatrix Diseases 0.000 description 1
- 229910020549 KCl—NaCl Inorganic materials 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910013365 LiBr—LiF Inorganic materials 0.000 description 1
- 229910013369 LiBr—NaBr Inorganic materials 0.000 description 1
- 229910013647 LiCl—LiF Inorganic materials 0.000 description 1
- 229910013697 LiCl—NaCl Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 241000530268 Lycaena heteronea Species 0.000 description 1
- 229910021258 NaF—RbF Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- VCHVXUQQZMQWIY-UHFFFAOYSA-N [AlH3].[Mg].[Li] Chemical compound [AlH3].[Mg].[Li] VCHVXUQQZMQWIY-UHFFFAOYSA-N 0.000 description 1
- WULWWVRGKDUITB-UHFFFAOYSA-L [Cl-].[Ca+2].[Cl-].[Li+] Chemical compound [Cl-].[Ca+2].[Cl-].[Li+] WULWWVRGKDUITB-UHFFFAOYSA-L 0.000 description 1
- DXAFGPUPGYKAAR-UHFFFAOYSA-K [Cl-].[Ca+2].[Cl-].[Na+].[Cl-].[Li+] Chemical compound [Cl-].[Ca+2].[Cl-].[Na+].[Cl-].[Li+] DXAFGPUPGYKAAR-UHFFFAOYSA-K 0.000 description 1
- BKJLSPKSPIMIAD-UHFFFAOYSA-L [Cl-].[Cs+].[Na+].[Cl-] Chemical compound [Cl-].[Cs+].[Na+].[Cl-] BKJLSPKSPIMIAD-UHFFFAOYSA-L 0.000 description 1
- FRRFXFCSMTUEMZ-UHFFFAOYSA-K [Cl-].[K+].[Cl-].[Li+].[Cl-].[Ca+2] Chemical compound [Cl-].[K+].[Cl-].[Li+].[Cl-].[Ca+2] FRRFXFCSMTUEMZ-UHFFFAOYSA-K 0.000 description 1
- CIHHRNQZUFCQRG-UHFFFAOYSA-L [Li+].[K+].[Br-].[Br-] Chemical compound [Li+].[K+].[Br-].[Br-] CIHHRNQZUFCQRG-UHFFFAOYSA-L 0.000 description 1
- CRYCBELFTGHLAD-UHFFFAOYSA-L [Li]F.[Li]Cl Chemical compound [Li]F.[Li]Cl CRYCBELFTGHLAD-UHFFFAOYSA-L 0.000 description 1
- DQPHOFCRIBAMEE-UHFFFAOYSA-K [Na+].[Cl-].[Li]Cl.Cl[K] Chemical compound [Na+].[Cl-].[Li]Cl.Cl[K] DQPHOFCRIBAMEE-UHFFFAOYSA-K 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011335 coal coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- YTAGWKNZVDGLMG-UHFFFAOYSA-K dilithium sodium dibromide chloride Chemical compound [Cl-].[Li+].[Br-].[Na+].[Br-].[Li+] YTAGWKNZVDGLMG-UHFFFAOYSA-K 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 description 1
- BDEWINKZKZJSQW-UHFFFAOYSA-L lithium potassium hydrogen sulfate chloride Chemical compound [Cl-].[K+].S(=O)(=O)([O-])O.[Li+] BDEWINKZKZJSQW-UHFFFAOYSA-L 0.000 description 1
- LBEWFUFVQRYRPT-UHFFFAOYSA-L lithium rubidium(1+) difluoride Chemical compound [F-].[Rb+].[F-].[Li+] LBEWFUFVQRYRPT-UHFFFAOYSA-L 0.000 description 1
- FHJCBUNTKMTNED-UHFFFAOYSA-L lithium strontium dichloride Chemical compound [Cl-].[Li+].[Cl-].[Sr+2] FHJCBUNTKMTNED-UHFFFAOYSA-L 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- JWQYBVZYJNWDQK-UHFFFAOYSA-L magnesium rubidium(1+) dichloride Chemical compound [Cl-].[Rb+].[Cl-].[Mg+2] JWQYBVZYJNWDQK-UHFFFAOYSA-L 0.000 description 1
- KXKFFNJPSQCIQR-UHFFFAOYSA-L magnesium sodium dichloride Chemical compound [Na+].[Mg+2].[Cl-].[Cl-] KXKFFNJPSQCIQR-UHFFFAOYSA-L 0.000 description 1
- ANZKPYPDQZRQBD-UHFFFAOYSA-L magnesium;potassium;dichloride Chemical compound [Mg+2].[Cl-].[Cl-].[K+] ANZKPYPDQZRQBD-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 230000036573 scar formation Effects 0.000 description 1
- 230000037390 scarring Effects 0.000 description 1
- 230000037387 scars Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/399—Cells with molten salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/46—Alloys based on magnesium or aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51847366A | 1966-01-03 | 1966-01-03 | |
| US51811366A | 1966-01-03 | 1966-01-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1696546A1 DE1696546A1 (de) | 1971-11-04 |
| DE1696546B2 true DE1696546B2 (de) | 1977-06-08 |
Family
ID=27059350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1967ST026338 Granted DE1696546B2 (de) | 1966-01-03 | 1967-01-03 | Wiederaufladbares galvanisches thermalelement und verfahren zur herstellung einer elektrode dafuer |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US3445288A (en, 2012) |
| JP (1) | JPS4630732B1 (en, 2012) |
| BE (1) | BE692056A (en, 2012) |
| DE (1) | DE1696546B2 (en, 2012) |
| FR (1) | FR1513461A (en, 2012) |
| GB (1) | GB1177011A (en, 2012) |
| NL (1) | NL139418B (en, 2012) |
| SE (1) | SE314423B (en, 2012) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3489659A (en) * | 1967-07-03 | 1970-01-13 | Gen Electric | Process for lithiding |
| US3506490A (en) * | 1968-05-08 | 1970-04-14 | Standard Oil Co | Solid electrolyte battery having lithium or lithium alloy anode |
| US3506491A (en) * | 1968-05-08 | 1970-04-14 | Standard Oil Co | Solid electrolyte battery having lithium or lithium alloy anode |
| US3506492A (en) * | 1968-05-08 | 1970-04-14 | Standard Oil Co | Solid electrolyte battery having lithium or lithium alloy anode |
| US3632448A (en) * | 1968-07-29 | 1972-01-04 | Exxon Research Engineering Co | Aluminum-halogen secondary battery method with molten electrolyte |
| US3607413A (en) * | 1968-09-10 | 1971-09-21 | Standard Oil Co Ohio | Method for electrochemical alloying of aluminum and lithium |
| US3607407A (en) * | 1969-08-07 | 1971-09-21 | Standard Oil Co Ohio | A method of purifying the electrolyte salt employed in an electrochemical cell |
| DE2010991B2 (de) * | 1970-03-09 | 1979-10-11 | The Standard Oil Co., Cleveland, Ohio (V.St.A.) | Elektrische Batterie mit flüssiger Füllung und Verfahren zu ihrer Herstellung |
| US3639174A (en) * | 1970-04-22 | 1972-02-01 | Du Pont | Voltaic cells with lithium-aluminum alloy anode and nonaqueous solvent electrolyte system |
| US3657017A (en) * | 1970-10-20 | 1972-04-18 | Albert E Ketler Jr | Self-feeding sea water battery |
| US3751298A (en) * | 1971-05-21 | 1973-08-07 | Union Carbide Corp | Thermal, rechargeable electrochemical cell having lithium monoaluminide electrode and lithium tetrachloroaluminate electrolyte |
| US3887396A (en) * | 1973-11-15 | 1975-06-03 | Us Energy | Modular electrochemical cell |
| US3907590A (en) * | 1974-07-05 | 1975-09-23 | Rockwell International Corp | Aluminum electrode |
| US3981743A (en) * | 1975-06-06 | 1976-09-21 | Esb Incorporated | Method of preparing a lithium-aluminum electrode |
| FR2572853B1 (fr) * | 1984-11-08 | 1986-12-19 | Aerospatiale | Anodes en alliages li-al a haut rendement energetique applicables aux generateurs electrochimiques |
| US4886715A (en) * | 1987-01-16 | 1989-12-12 | The Dow Chemical Company | Molten membrane electrolyte battery |
| US4929521A (en) * | 1988-09-28 | 1990-05-29 | The Dow Chemical Company | Solid electrolyte battery |
| US5900331A (en) * | 1997-08-27 | 1999-05-04 | The United States Of America As Represented By The Secretary Of The Army | Thermal battery with reduced self-discharge |
| GB0302834D0 (en) * | 2003-02-07 | 2003-03-12 | Aea Technology Battery Systems | Secondary cell with tin anode |
| US20110177468A1 (en) * | 2008-10-03 | 2011-07-21 | Fabiola Barbosa Ormiga Galvao | Method and device for removing metallic fragments and metallic elements from dental root canals |
| DE102013102867A1 (de) * | 2013-03-20 | 2014-10-09 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Temperiervorrichtung |
| CN104868179B (zh) * | 2015-05-13 | 2017-11-17 | 北京科技大学 | 一种可充放电铝离子熔盐电池及其制备方法 |
| CN109962185B (zh) * | 2019-03-27 | 2021-01-19 | 西安交通大学 | 一种小容量金属石墨中温储能电池及其制备方法 |
| CN112563128B (zh) * | 2020-12-10 | 2023-12-12 | 苏州工业园区纳米产业技术研究院有限公司 | 一种提高芯片Al电极打线成功率的工艺方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US732631A (en) * | 1903-01-19 | 1903-06-30 | Carl Hambuechen | Asymmetric conductor. |
| US939183A (en) * | 1903-04-18 | 1909-11-02 | Henry Spencer Blackmore | Process of generating electricity. |
| US1277389A (en) * | 1917-11-28 | 1918-09-03 | Emile Alexander Cotte | Electrical accumulator. |
| US1377722A (en) * | 1918-03-09 | 1921-05-10 | Marconi Guglielmo | Electric accumulator |
| US1357858A (en) * | 1919-03-20 | 1920-11-02 | Burpee Macleod Hay | Battery |
| US2079516A (en) * | 1935-03-01 | 1937-05-04 | Magnavox Co | Aluminum electrode and method of preparing |
| US2937219A (en) * | 1955-11-14 | 1960-05-17 | G And W H Corson Inc | Electric current producing cell and method of generating current with same |
| US3055960A (en) * | 1956-01-06 | 1962-09-25 | Isador D Yalom | Thermoelectric battery |
| US2880260A (en) * | 1956-05-07 | 1959-03-31 | Electric Storage Battery Co | Storage battery separator |
| FR1189268A (fr) * | 1957-11-26 | 1959-10-01 | Perfectionnements apportés aux piles et accumulateurs électriques | |
| US3053924A (en) * | 1959-03-23 | 1962-09-11 | Electric Storage Battery Co | Battery electrode and method of making the same |
| US3160531A (en) * | 1961-02-24 | 1964-12-08 | William C Spindler | Galvanic cell electrode |
| US3207630A (en) * | 1961-06-27 | 1965-09-21 | Yardney International Corp | Electrode assembly |
| FR1399752A (fr) * | 1964-04-04 | 1965-05-21 | Soc Gen Magnesium | Nouvel alliage à base d'aluminium et de mercure et son application à la réalisation d'anodes |
| US3236694A (en) * | 1964-09-29 | 1966-02-22 | Dow Chemical Co | Primary cell with non-aqueous electrolyte |
-
1966
- 1966-01-03 US US518473A patent/US3445288A/en not_active Expired - Lifetime
- 1966-01-03 US US518113A patent/US3428493A/en not_active Expired - Lifetime
- 1966-12-30 JP JP8596566A patent/JPS4630732B1/ja active Pending
- 1966-12-30 BE BE692056D patent/BE692056A/xx unknown
- 1966-12-30 FR FR89537A patent/FR1513461A/fr not_active Expired
-
1967
- 1967-01-02 GB GB084/67A patent/GB1177011A/en not_active Expired
- 1967-01-03 NL NL676700085A patent/NL139418B/xx unknown
- 1967-01-03 SE SE101/67A patent/SE314423B/xx unknown
- 1967-01-03 DE DE1967ST026338 patent/DE1696546B2/de active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1177011A (en) | 1970-01-07 |
| NL139418B (nl) | 1973-07-16 |
| JPS4630732B1 (en) | 1971-09-07 |
| NL6700085A (en, 2012) | 1967-07-04 |
| SE314423B (en, 2012) | 1969-09-08 |
| DE1696546A1 (de) | 1971-11-04 |
| US3428493A (en) | 1969-02-18 |
| US3445288A (en) | 1969-05-20 |
| BE692056A (en, 2012) | 1967-06-30 |
| FR1513461A (fr) | 1968-02-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |