DE1645469C2 - Verfahren zur Herstellung neuer Copolymerisate - Google Patents
Verfahren zur Herstellung neuer CopolymerisateInfo
- Publication number
- DE1645469C2 DE1645469C2 DE1645469A DE1645469A DE1645469C2 DE 1645469 C2 DE1645469 C2 DE 1645469C2 DE 1645469 A DE1645469 A DE 1645469A DE 1645469 A DE1645469 A DE 1645469A DE 1645469 C2 DE1645469 C2 DE 1645469C2
- Authority
- DE
- Germany
- Prior art keywords
- parts
- acrylonitrile
- polymer
- latex
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims description 28
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 description 41
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 31
- 239000004816 latex Substances 0.000 description 29
- 229920000126 latex Polymers 0.000 description 29
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 13
- 239000000178 monomer Substances 0.000 description 13
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 13
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 230000035699 permeability Effects 0.000 description 10
- 239000007795 chemical reaction product Substances 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 7
- 150000002825 nitriles Chemical class 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 4
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 4
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 4
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- IRCAZSRWCCDLJN-UHFFFAOYSA-N ethyl prop-2-enoate;prop-2-enenitrile Chemical compound C=CC#N.CCOC(=O)C=C IRCAZSRWCCDLJN-UHFFFAOYSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- DDXZFLFMKZXQOT-UHFFFAOYSA-N 2-fluoroprop-2-enenitrile Chemical compound FC(=C)C#N DDXZFLFMKZXQOT-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical class CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JFHJOMSTWVDDHW-UHFFFAOYSA-N methyl prop-2-enoate;prop-2-enenitrile Chemical compound C=CC#N.COC(=O)C=C JFHJOMSTWVDDHW-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- -1 nonylphenyl group Chemical group 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical class CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical class CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S206/00—Special receptacle or package
- Y10S206/819—Material
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48076665A | 1965-08-18 | 1965-08-18 | |
| US55370566A | 1966-05-31 | 1966-05-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1645469A1 DE1645469A1 (de) | 1970-05-21 |
| DE1645469B2 DE1645469B2 (de) | 1971-12-16 |
| DE1645469C2 true DE1645469C2 (de) | 1983-12-15 |
Family
ID=27046705
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1645469A Expired DE1645469C2 (de) | 1965-08-18 | 1966-08-13 | Verfahren zur Herstellung neuer Copolymerisate |
| DE1795624A Expired DE1795624C3 (de) | 1965-08-18 | 1966-08-13 | Verfahren zur Herstellung von Pfropfcopolymerisaten |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1795624A Expired DE1795624C3 (de) | 1965-08-18 | 1966-08-13 | Verfahren zur Herstellung von Pfropfcopolymerisaten |
Country Status (5)
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3542705A (en) * | 1966-11-21 | 1970-11-24 | Polymer Corp | Reconstituted leatherboard comprising leather fibers and alkyl-substituted nitrile/carboxyl containing rubber |
| US3891722A (en) * | 1970-02-16 | 1975-06-24 | Standard Oil Co | Process for manufacture of impact-resistant polymerizates of olefinic nitriles and diene rubbers |
| NL7113006A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-09-24 | 1972-03-28 | ||
| US3720339A (en) * | 1970-09-24 | 1973-03-13 | Monsanto Co | Plastic container for pressurized materials-a |
| US3726429A (en) * | 1970-12-28 | 1973-04-10 | Monsanto Co | Package for holding pressurized fluent materials |
| US3978232A (en) * | 1970-12-30 | 1976-08-31 | Edward Dodsworth | Thin walled containers for pressurized liquids |
| JPS51102040A (ja) * | 1971-01-14 | 1976-09-09 | Phillips Petroleum Co | Kokyodojugotaisoseibutsuchukubutsupin |
| US3981412A (en) * | 1971-03-29 | 1976-09-21 | Asmus Richard W | Container closure |
| US3862288A (en) * | 1971-08-12 | 1975-01-21 | Continental Can Co | Creep stabilization of plastic articles |
| JPS5029874B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-12-29 | 1975-09-26 | ||
| US3974239A (en) * | 1972-02-02 | 1976-08-10 | Standard Oil Company | Manufacture of impact-resistant olefinic-nitrile copolymers |
| US3984498A (en) * | 1972-04-28 | 1976-10-05 | American Can Company | Blown thermoplastic bottle and method for making same |
| US3949038A (en) * | 1972-04-28 | 1976-04-06 | American Can Company | Blown thermoplastic bottle and method for making same |
| US3940454A (en) * | 1972-07-17 | 1976-02-24 | Borg-Warner Corporation | Transparent high impact graft polymers |
| CH567534A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-07-27 | 1975-10-15 | Standard Oil Co | |
| US3863014A (en) * | 1972-11-08 | 1975-01-28 | Monsanto Co | High acrylonitrile terpolymer containers and packages |
| US3934743A (en) * | 1972-12-29 | 1976-01-27 | American Can Company | Blow molded, oriented plastic bottle and method for making same |
| US3900120A (en) * | 1973-02-12 | 1975-08-19 | Monsanto Co | Preforms for forming pressurized containers |
| CA1038795A (en) * | 1974-03-08 | 1978-09-19 | Paul D. Frayer | Composite sheet and method of making the same |
| US3931074A (en) * | 1974-03-14 | 1976-01-06 | Monsanto Company | Modifiers for high nitrile polymers |
| US3950454A (en) * | 1974-12-09 | 1976-04-13 | Standard Oil Company | Polymerizates of olefinic nitriles and diene rubbers |
| US3947527A (en) * | 1975-02-21 | 1976-03-30 | The Standard Oil Company | Polymerizates of olefinic nitriles and diene rubbers |
| US4000106A (en) * | 1975-02-26 | 1976-12-28 | Standard Oil Company | Processing aids for nitrile resins |
| US3984499A (en) * | 1975-04-28 | 1976-10-05 | Standard Oil Company | Thermally stable high nitrile resins and method for producing the same |
| FR2321520A1 (fr) * | 1975-08-22 | 1977-03-18 | Rhone Poulenc Ind | Latex de polymeres possedant des groupes-cn |
| US4043947A (en) * | 1976-01-15 | 1977-08-23 | Standard Oil Company | Impact improvement of rubber-modified nitrile resins |
| US4041005A (en) * | 1976-01-15 | 1977-08-09 | The Standard Oil Company | Impact improvement of rubber-modified nitrile resins |
| US4142630A (en) * | 1977-11-07 | 1979-03-06 | Ethyl Corporation | Collapsible dispensing tube |
| US4265948A (en) * | 1977-11-07 | 1981-05-05 | Ethyl Corporation | Collapsible dispensing tube |
| US4174043A (en) * | 1977-11-10 | 1979-11-13 | Monsanto Company | Nitrile preforms and containers and process improvements for forming same |
| US4206300A (en) * | 1978-06-12 | 1980-06-03 | Standand Oil Company | Method for improving color and impact strength of nitrile polymers |
| US4238263A (en) * | 1978-10-02 | 1980-12-09 | Ethyl Corporation | Edge sealing of laminate |
| US4359506A (en) * | 1979-03-15 | 1982-11-16 | Sohio | Tie layer for co-extruded acrylonitrile copolymers |
| US4355127A (en) * | 1979-08-29 | 1982-10-19 | Sohio | Physical property improvement in nitrile resins by use of certain processing aids and fillers |
| US4292228A (en) * | 1979-08-29 | 1981-09-29 | The Standard Oil Company | Physical property improvement in nitrile resins by use of certain processing aids and fillers |
| US4243725A (en) * | 1979-11-29 | 1981-01-06 | Standard Oil Company | Tie layer for co-extruded acrylonitrile copolymers |
| US4339502A (en) * | 1979-11-29 | 1982-07-13 | Sohio | Tie-layer for coextruded acrylonitrile copolymers |
| US4327002A (en) * | 1979-12-26 | 1982-04-27 | The Standard Oil Company | High nitrile copolymer resins containing epoxidized oil for improved impact resistance |
| US4400484A (en) * | 1980-05-15 | 1983-08-23 | The Standard Oil Company | Esters as processing aids for olefinic nitrile copolymers |
| US4450254A (en) * | 1980-11-03 | 1984-05-22 | Standard Oil Company | Impact improvement of high nitrile resins |
| US4375441A (en) * | 1980-12-18 | 1983-03-01 | The Standard Oil Company | Method for producing sintered porous polymeric articles |
| US4379875A (en) * | 1980-12-31 | 1983-04-12 | The Standard Oil Company | Coalescing aid for high nitrile copolymer latex coatings |
| US4390652A (en) * | 1981-05-26 | 1983-06-28 | Standard Oil Company | Nitrile barrier resins containing fillers and processing aids |
| US4374948A (en) * | 1981-05-26 | 1983-02-22 | The Standard Oil Company | High nitrile copolymer latex coating |
| US4505161A (en) * | 1983-03-24 | 1985-03-19 | The Standard Oil Company | Mineral sample preservation process |
| US5820876A (en) * | 1986-08-28 | 1998-10-13 | Lts Lohmann Therapie-Systeme Gmbh & Co. Kg | Transdermal therapeutic system |
| US6126963A (en) * | 1986-08-28 | 2000-10-03 | Lts Lohmann Therapie-Systeme Gmbh & Co. Kg | Transdermal therapeutic system, its use and production process |
| US5169675A (en) * | 1987-07-02 | 1992-12-08 | The Standard Oil Company | Bonding of high nitrile resins onto surface plasma treated plastics |
| US5055520A (en) * | 1988-08-22 | 1991-10-08 | The Standard Oil Company | Blends of high nitrile coploymers and thermoplastic polymers |
| US4914138A (en) * | 1988-08-22 | 1990-04-03 | The Standard Oil Company | Blends of high nitrile polymers and polyolefins and method for the preparation thereon |
| US4956412A (en) * | 1988-11-09 | 1990-09-11 | Shell Oil Company | Polymer blend |
| US4900789A (en) * | 1988-12-22 | 1990-02-13 | Shell Oil Company | Polymer blend of carbon monoxide/olefin copolymer and conjugated alkadiene |
| US5084510A (en) * | 1989-10-30 | 1992-01-28 | The B. F. Goodrich Company | Vinyl halide polymers modified with olefinic nitrile polymers |
| US5077104A (en) * | 1989-12-21 | 1991-12-31 | Alza Corporation | Nicotine packaging materials |
| US5274008A (en) * | 1990-11-27 | 1993-12-28 | Bausch & Lomb Incorporated | Mold materials for silicone containing lens materials |
| US5158717A (en) * | 1990-11-27 | 1992-10-27 | Bausch & Lomb Incorporated | Method of molding shaped polymeric articles |
| US5385982A (en) * | 1991-03-15 | 1995-01-31 | The Standard Oil Company | Material for refrigerator liners |
| US5264161A (en) * | 1991-09-05 | 1993-11-23 | Bausch & Lomb Incorporated | Method of using surfactants as contact lens processing aids |
| KR960002301B1 (ko) * | 1992-06-03 | 1996-02-16 | 주식회사엘지화학 | Hcfc내성이 우수한 열가소성수지 조성물의 제조방법 |
| DE19921416C2 (de) * | 1999-05-08 | 2001-02-15 | Inst Verbundwerkstoffe Gmbh | Verfahren zur Herstellung von Glycidyl-enthaltenden Nitril-Butadien-Polymeren, insbesondere Elastomeren |
| US6905016B2 (en) * | 2000-03-14 | 2005-06-14 | Noven Pharmaceuticals, Inc. | Packaging system for transdermal drug delivery systems |
| US20060205881A1 (en) | 2005-03-08 | 2006-09-14 | Michael Gozdiff | Blends of diene rubber with thermoplastic copolymer modifield with nitrile rubber |
| BRPI0710158A2 (pt) * | 2006-04-19 | 2011-08-23 | Colgate Palmolive Co | recipiente para substáncias |
| US20090108479A1 (en) * | 2007-10-26 | 2009-04-30 | Bausch & Lomb Incorporated | Method for Making Biomedical Devices |
| US8906187B2 (en) * | 2008-06-25 | 2014-12-09 | Colgate-Palmolive Company | Method of making shoulder/nozzles with film barrier liners |
| US20100149482A1 (en) * | 2008-12-12 | 2010-06-17 | Ammon Jr Daniel M | Contact lens |
| US8920392B2 (en) | 2009-05-05 | 2014-12-30 | Watson Laboratories, Inc. | Method for treating overactive bladders and a device for storage and administration of topical oxybutynin compositions |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2802809A (en) * | 1953-11-30 | 1957-08-13 | Firestone Tire & Rubber Co | Compositions of vinyl chloride resins and graft copolymers of acrylonitrile-type monomer compositions upon diene polymers and articles formed therefrom |
| NL100508C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1957-01-30 | |||
| US3133135A (en) * | 1960-07-29 | 1964-05-12 | Du Pont | Process for preparing solid shaped articles |
| NL269000A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1960-09-10 | |||
| NL286435A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1961-12-08 | |||
| US3370105A (en) * | 1963-05-07 | 1968-02-20 | Bell & Richardson Inc De | Process for manufacture of impact polymers |
| US3262993A (en) * | 1963-08-09 | 1966-07-26 | Eastman Kodak Co | Graft copolymers of 2, 2-dimethylalkyl methacrylate and acrylonitrile with butadiene polymers |
| GB1143408A (en) * | 1965-04-09 | 1969-02-19 | Ici Ltd | Thermoplastic compositions derived from a diene rubber and a resin |
-
1966
- 1966-05-31 US US553705A patent/US3426102A/en not_active Expired - Lifetime
- 1966-08-04 NL NL666611027A patent/NL144296B/xx not_active IP Right Cessation
- 1966-08-13 DE DE1645469A patent/DE1645469C2/de not_active Expired
- 1966-08-13 DE DE1795624A patent/DE1795624C3/de not_active Expired
- 1966-08-17 BE BE685625A patent/BE685625A/xx not_active IP Right Cessation
- 1966-08-18 GB GB37075/66A patent/GB1156961A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL6611027A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-02-20 |
| DE1795624A1 (de) | 1972-11-09 |
| US3426102A (en) | 1969-02-04 |
| BE685625A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1967-02-01 |
| DE1795624C3 (de) | 1979-09-13 |
| DE1645469B2 (de) | 1971-12-16 |
| NL144296B (nl) | 1974-12-16 |
| DE1795624B2 (de) | 1979-01-18 |
| GB1156961A (en) | 1969-07-02 |
| DE1645469A1 (de) | 1970-05-21 |
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