DE1593660B1 - Verfahren zur Herstellung von 5-Alkylidenbicyclo[2,2,1]-hept-2-enen - Google Patents

Verfahren zur Herstellung von 5-Alkylidenbicyclo[2,2,1]-hept-2-enen

Info

Publication number
DE1593660B1
DE1593660B1 DE19661593660 DE1593660A DE1593660B1 DE 1593660 B1 DE1593660 B1 DE 1593660B1 DE 19661593660 DE19661593660 DE 19661593660 DE 1593660 A DE1593660 A DE 1593660A DE 1593660 B1 DE1593660 B1 DE 1593660B1
Authority
DE
Germany
Prior art keywords
hept
mixture
nitrogen
alkali metal
mol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19661593660
Other languages
German (de)
English (en)
Inventor
Atkins Kenneth Earl
Fritz Henry Edward
O'connor George Lawrence
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of DE1593660B1 publication Critical patent/DE1593660B1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2556—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2562—Catalytic processes with hydrides or organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE19661593660 1965-10-01 1966-09-22 Verfahren zur Herstellung von 5-Alkylidenbicyclo[2,2,1]-hept-2-enen Withdrawn DE1593660B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49229765A 1965-10-01 1965-10-01
US550120A US3347944A (en) 1965-10-01 1966-05-16 Production of alkylidenebicycloheptenes

Publications (1)

Publication Number Publication Date
DE1593660B1 true DE1593660B1 (de) 1971-04-29

Family

ID=27050715

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19661593660 Withdrawn DE1593660B1 (de) 1965-10-01 1966-09-22 Verfahren zur Herstellung von 5-Alkylidenbicyclo[2,2,1]-hept-2-enen

Country Status (7)

Country Link
US (1) US3347944A (US07579456-20090825-P00002.png)
BE (1) BE687569A (US07579456-20090825-P00002.png)
DE (1) DE1593660B1 (US07579456-20090825-P00002.png)
ES (1) ES331560A1 (US07579456-20090825-P00002.png)
GB (1) GB1111924A (US07579456-20090825-P00002.png)
IL (1) IL26604A (US07579456-20090825-P00002.png)
NL (1) NL149147B (US07579456-20090825-P00002.png)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0219637A1 (en) * 1985-10-21 1987-04-29 Sumitomo Chemical Company, Limited Process for preparing 5-ethylidene-2-norbornene

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3501540A (en) * 1969-01-27 1970-03-17 Phillips Petroleum Co Isomerization of acylic trienes
US3535396A (en) * 1969-04-07 1970-10-20 Goodrich Co B F Isomerization of 5-vinylbicyclo (2.2.1) hept-2-enes with titanium catalyst
US3535395A (en) * 1969-04-07 1970-10-20 Goodrich Co B F Catalytic process for the isomerization of 5-vinylbicyclo(2.2.1)hept-2-enes
US3538171A (en) * 1969-04-07 1970-11-03 Goodrich Co B F Process for the isomerization of 5-vinylbicyclo(2.2.1)hept-2-ene
BE754447A (fr) * 1969-08-08 1971-02-05 Uniroyal Inc Procede de fabrication de 5-alcoylidene-2-
US3894999A (en) * 1970-01-12 1975-07-15 Copolymer Rubber & Chem Corp Interpolymer of at least two monoolefins and certain 5-alkylidene-2-norbornenes
BE761681A (fr) * 1970-01-22 1971-07-01 Snam Progetti Hydrocarbures polyeniques et leur procede de fabrication
CA977375A (en) * 1970-01-22 1975-11-04 Sergio Arrighetti Polyene hydrocarbons containing at least two conjugated double bonds and process for obtaining same
US3742076A (en) * 1970-03-06 1973-06-26 H Imai Process for the production of 5-ethylidene norbornene-2
US3897509A (en) * 1970-07-02 1975-07-29 Sumitomo Chemical Co Preparation of alkylidene bicyclic compounds
JPS5035075B1 (US07579456-20090825-P00002.png) * 1970-12-22 1975-11-13
US3696157A (en) * 1971-06-14 1972-10-03 Goodrich Co B F Preparation of 5-ethylidenebicyclo(2.2.1)hept-2-enes
US3683039A (en) * 1971-06-14 1972-08-08 Goodrich Co B F Process for the isomerization of 5-vinylbicyclo (2.2.1) hept-2-enes
US3694517A (en) * 1971-06-14 1972-09-26 Goodrich Co B F Isomerization of 5-vinylbicyclo{8 2.2.1{9 hept-2-enes
JPS5547017B2 (US07579456-20090825-P00002.png) * 1972-12-12 1980-11-27
JPS5710848B2 (US07579456-20090825-P00002.png) * 1974-03-05 1982-03-01
US4079091A (en) * 1975-03-11 1978-03-14 Nippon Oil Co., Ltd. Method for the production of vinyl norbornene
JPS53121753A (en) * 1977-03-31 1978-10-24 Japan Synthetic Rubber Co Ltd Preparation of 5-alkylidenenorbornene
DE3863195D1 (de) * 1987-02-16 1991-07-18 Sumitomo Chemical Co Feste base, verfahren zu deren herstellung und ihre anwendung fuer die herstellung von olefinen mit innerer doppelbindung.
US5849966A (en) * 1991-05-14 1998-12-15 Exxon Chemical Patents Inc. Catalyst and process for the isomerization of olefins in the presence of reactive impurities
US5292985A (en) * 1991-05-14 1994-03-08 Exxon Chemical Patents, Inc. Multi-stage olefin isomerization
US5321180A (en) * 1993-05-05 1994-06-14 Union Carbide Chemicals & Plastics Technology Corporation Conversion of vinylcyclohexene to ethylbenzene
WO2005051839A2 (en) * 2003-11-24 2005-06-09 Michael Lefenfeld Silica gel compositions containing alkali metals and alkali metal alloys
US7259128B2 (en) * 2004-09-22 2007-08-21 Signa Chemistry, Llc Titanium oxide and alumina alkali metal compositions
CN105461505B (zh) * 2015-12-07 2017-12-19 上海派尔科化工材料股份有限公司 一种乙叉降冰片烯的生产方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3151173A (en) * 1961-07-18 1964-09-29 Du Pont Process for producing 5-alkylidene norbornene

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3124621A (en) * 1964-03-10 Isomerization of cyclooctadiene
US3016409A (en) * 1959-04-27 1962-01-09 Universal Oil Prod Co Preparation of 1-alkyl-1-cyclohexenes
US3009001A (en) * 1960-03-31 1961-11-14 Phillips Petroleum Co Isomerization of cyclo triene compounds
US3213155A (en) * 1961-05-19 1965-10-19 Exxon Research Engineering Co Monoolefin isomerization process
US3217050A (en) * 1961-06-07 1965-11-09 Exxon Research Engineering Co Alkali metal catalyzed conversion of organic compounds
US3076855A (en) * 1961-09-25 1963-02-05 Phillips Petroleum Co Preparation of methylbenzosuberane
US3251894A (en) * 1962-07-28 1966-05-17 Amagasa Masataka Process for the production of 1-methylcyclohexene-(1)

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3151173A (en) * 1961-07-18 1964-09-29 Du Pont Process for producing 5-alkylidene norbornene

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0219637A1 (en) * 1985-10-21 1987-04-29 Sumitomo Chemical Company, Limited Process for preparing 5-ethylidene-2-norbornene

Also Published As

Publication number Publication date
ES331560A1 (es) 1967-08-01
GB1111924A (en) 1968-05-01
IL26604A (en) 1971-11-29
US3347944A (en) 1967-10-17
NL6613870A (US07579456-20090825-P00002.png) 1967-04-03
NL149147B (nl) 1976-04-15
BE687569A (US07579456-20090825-P00002.png) 1967-03-29

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Legal Events

Date Code Title Description
E77 Valid patent as to the heymanns-index 1977
8327 Change in the person/name/address of the patent owner

Owner name: UNION CARBIDE CORP., 06817 DANBURY, CONN., US

8328 Change in the person/name/address of the agent

Free format text: DANNENBERG, G., DIPL.-ING., 6000 FRANKFURT SCHMIED-KOWARZIK, V., DR., PAT.-ANW., 8000 MUENCHEN

8339 Ceased/non-payment of the annual fee