DE1569234A1 - Harzmischung auf Phenolbasis - Google Patents
Harzmischung auf PhenolbasisInfo
- Publication number
- DE1569234A1 DE1569234A1 DE19651569234 DE1569234A DE1569234A1 DE 1569234 A1 DE1569234 A1 DE 1569234A1 DE 19651569234 DE19651569234 DE 19651569234 DE 1569234 A DE1569234 A DE 1569234A DE 1569234 A1 DE1569234 A1 DE 1569234A1
- Authority
- DE
- Germany
- Prior art keywords
- resin
- weight
- fibers
- phenol
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 title claims description 135
- 239000011347 resin Substances 0.000 title claims description 135
- 239000000203 mixture Substances 0.000 title claims description 64
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims description 27
- 239000011230 binding agent Substances 0.000 claims description 53
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 51
- 229920003987 resole Polymers 0.000 claims description 35
- 229920003986 novolac Polymers 0.000 claims description 34
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 28
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 14
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 14
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- 239000002557 mineral fiber Substances 0.000 claims description 7
- 238000005187 foaming Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 description 69
- 239000000243 solution Substances 0.000 description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- 235000019441 ethanol Nutrition 0.000 description 20
- 229960004011 methenamine Drugs 0.000 description 13
- 239000006260 foam Substances 0.000 description 12
- 239000000843 powder Substances 0.000 description 11
- 238000005266 casting Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000001476 alcoholic effect Effects 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 241000252141 Semionotiformes Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- PVAONLSZTBKFKM-UHFFFAOYSA-N diphenylmethanediol Chemical compound C=1C=CC=CC=1C(O)(O)C1=CC=CC=C1 PVAONLSZTBKFKM-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002989 phenols Chemical group 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- XYSQXZCMOLNHOI-UHFFFAOYSA-N s-[2-[[4-(acetylsulfamoyl)phenyl]carbamoyl]phenyl] 5-pyridin-1-ium-1-ylpentanethioate;bromide Chemical compound [Br-].C1=CC(S(=O)(=O)NC(=O)C)=CC=C1NC(=O)C1=CC=CC=C1SC(=O)CCCC[N+]1=CC=CC=C1 XYSQXZCMOLNHOI-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0085—Use of fibrous compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/34—Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US79210A US3207652A (en) | 1960-12-29 | 1960-12-29 | Phenolic compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
DE1569234A1 true DE1569234A1 (de) | 1969-06-12 |
DE1569234B2 DE1569234B2 (en, 2012) | 1970-11-26 |
Family
ID=22149117
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19651569234 Pending DE1569234A1 (de) | 1960-12-29 | 1965-09-17 | Harzmischung auf Phenolbasis |
Country Status (6)
Country | Link |
---|---|
US (1) | US3207652A (en, 2012) |
BE (1) | BE669776A (en, 2012) |
DE (1) | DE1569234A1 (en, 2012) |
GB (1) | GB1098029A (en, 2012) |
LU (1) | LU49496A1 (en, 2012) |
NL (1) | NL6512244A (en, 2012) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3409581A (en) * | 1964-06-29 | 1968-11-05 | Union Carbide Corp | Polyhydroxyether modified resole phenolic resins |
US3410718A (en) * | 1965-02-23 | 1968-11-12 | Rogers Corp | Phenol-formaldehyde novolak-phenolformaldehyde resole molding surface for a reinforced matrix base sheet |
US3872033A (en) * | 1970-03-13 | 1975-03-18 | Fibreglass Ltd | Foamed reaction product of a resale with a sulfonated novolac |
US3944703A (en) * | 1971-07-21 | 1976-03-16 | Union Carbide Corporation | Fibrous batts impregnated with aqueous dispersions based on heat-hardenable phenolic resins |
BE786953A (fr) * | 1971-07-30 | 1973-01-29 | Pilkington Brothers Ltd | Novolaques sulfonees et produits expanses. |
US3879338A (en) * | 1971-10-12 | 1975-04-22 | Hooker Chemicals Plastics Corp | Friction element composition |
US3873490A (en) * | 1971-10-12 | 1975-03-25 | Hooker Chemicals Plastics Corp | Friction particle for brake lining |
US3966670A (en) * | 1972-12-27 | 1976-06-29 | Hooker Chemicals & Plastics Corporation | Friction particle for brake lining |
CA1025579A (en) | 1973-09-17 | 1978-01-31 | Alfred G. Edwards | Resin compositions |
US3927140A (en) * | 1973-10-24 | 1975-12-16 | Research Corp | Adhesive composition |
GB2051097B (en) * | 1979-05-23 | 1983-05-18 | Redland Technology Ltd | Moulding compositions |
US4306410A (en) * | 1980-11-12 | 1981-12-22 | Kureha Kagaku Kogyo Kabushiki Kaisha | String construction for athletic rackets |
US4526924A (en) * | 1982-07-01 | 1985-07-02 | Plastics Engineering Company | Thermosettable compositions convertible to vitreous carbon and process for preparation thereof |
USRE32319E (en) * | 1983-03-21 | 1986-12-30 | Plastics Engineering Company | Vitreous carbon and process for preparation thereof |
US4550015A (en) * | 1983-03-21 | 1985-10-29 | Plastics Engineering Company | Vitreous carbon and process for preparation thereof |
US4624984A (en) * | 1984-02-24 | 1986-11-25 | Plastics Engineering Company | Moldable composition suitable for the preparation of vitreous carbon |
US4668496A (en) * | 1984-11-05 | 1987-05-26 | Plastics Engineering Company | Vitreous carbon |
US4624811A (en) * | 1984-11-05 | 1986-11-25 | Plastics Engineering Company | Process for preparing a vitreous carbon |
DE3625443A1 (de) * | 1986-07-28 | 1988-02-11 | Ruetgerswerke Ag | Verfahren zur herstellung von textilvliesstoffen |
US4904516A (en) * | 1988-01-12 | 1990-02-27 | Certain Teed Corp | Phenol-formaldehyde resin solution containing water soluble alkaline earth metal salt |
GB8812512D0 (en) * | 1988-05-26 | 1988-06-29 | Tba Industrial Products Ltd | Phenolic moulding compositions |
DK0512908T3 (da) * | 1991-05-09 | 2000-01-31 | Saint Gobain Isover | Fremgangsmåde til fremstilling af et phenolisk bindemiddel |
US5473012A (en) * | 1991-05-09 | 1995-12-05 | Certainteed Corporation | Process for preparing phenolic binder |
GB2283764A (en) * | 1993-11-09 | 1995-05-17 | Tba Composites Limited | Resin and carbon fibre moulding material |
JP4756683B2 (ja) * | 2005-06-01 | 2011-08-24 | 旭有機材工業株式会社 | 発泡性レゾール型フェノール樹脂成形材料およびフェノール樹脂発泡体 |
US7605189B1 (en) * | 2006-05-22 | 2009-10-20 | Brotz Gregory R | Process for producing a phenolic foam |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2732368A (en) * | 1956-01-24 | Type hi phenolic resins and their | ||
US2527581A (en) * | 1945-08-01 | 1950-10-31 | Durez Plastics And Chemicals I | Treatment of earth formations |
US2683697A (en) * | 1951-01-27 | 1954-07-13 | United Aircraft Corp | Nylon-reinforced copolymer resins |
US2728741A (en) * | 1952-11-01 | 1955-12-27 | Lockheed Aircraft Corp | Phenol-formaldehyde resins for foaming compositions |
US2999833A (en) * | 1954-04-09 | 1961-09-12 | Ford Motor Co | Process for mixing a novalak resin and sand with an a-stage resin and sand to obtain a shell molding sand |
US2856381A (en) * | 1955-06-01 | 1958-10-14 | Borden Co | Foundry sand binder composition containing at least three phenol-formaldehyde resins |
US3002948A (en) * | 1957-09-12 | 1961-10-03 | American Steel Foundries | Shell mold |
US2985614A (en) * | 1958-05-01 | 1961-05-23 | Air Logistics Corp | Composition comprising a phenolic novolak, a phenolic resol, and diallyl phthalate |
US2993871A (en) * | 1958-07-03 | 1961-07-25 | Owens Corning Fiberglass Corp | Foamable silicone-glycol copolymer novolac compositions, method of preparing same and articles produced therefrom |
-
1960
- 1960-12-29 US US79210A patent/US3207652A/en not_active Expired - Lifetime
-
1965
- 1965-09-17 DE DE19651569234 patent/DE1569234A1/de active Pending
- 1965-09-17 BE BE669776A patent/BE669776A/xx unknown
- 1965-09-20 NL NL6512244A patent/NL6512244A/xx unknown
- 1965-09-20 LU LU49496A patent/LU49496A1/xx unknown
- 1965-09-20 GB GB40039/65A patent/GB1098029A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB1098029A (en) | 1968-01-03 |
DE1569234B2 (en, 2012) | 1970-11-26 |
NL6512244A (en, 2012) | 1967-03-21 |
BE669776A (en, 2012) | 1966-03-17 |
US3207652A (en) | 1965-09-21 |
LU49496A1 (en, 2012) | 1966-03-21 |
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