DE1470533A1 - Verfahren zur Entschwefelung von hochsiedenden fluessigen Kohlenwasserstoffen durch weitstufige Behandlung mit Wasserstoff - Google Patents
Verfahren zur Entschwefelung von hochsiedenden fluessigen Kohlenwasserstoffen durch weitstufige Behandlung mit WasserstoffInfo
- Publication number
- DE1470533A1 DE1470533A1 DE1961E0021880 DEE0021880A DE1470533A1 DE 1470533 A1 DE1470533 A1 DE 1470533A1 DE 1961E0021880 DE1961E0021880 DE 1961E0021880 DE E0021880 A DEE0021880 A DE E0021880A DE 1470533 A1 DE1470533 A1 DE 1470533A1
- Authority
- DE
- Germany
- Prior art keywords
- stage
- hydrogen
- desulfurization
- catalyst
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000001257 hydrogen Substances 0.000 title claims description 51
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 51
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 47
- 238000000034 method Methods 0.000 title claims description 32
- 229930195733 hydrocarbon Natural products 0.000 title claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 21
- 238000009835 boiling Methods 0.000 title claims description 13
- 239000007788 liquid Substances 0.000 title claims description 11
- 239000003054 catalyst Substances 0.000 claims description 28
- 238000006477 desulfuration reaction Methods 0.000 claims description 16
- 230000023556 desulfurization Effects 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000003009 desulfurizing effect Effects 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 239000011593 sulfur Substances 0.000 description 13
- 229910052717 sulfur Inorganic materials 0.000 description 13
- 239000012535 impurity Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 150000001491 aromatic compounds Chemical class 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000004523 catalytic cracking Methods 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 150000003464 sulfur compounds Chemical class 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical class C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/06—Gasoil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72998A US3155608A (en) | 1960-12-01 | 1960-12-01 | Process for reducing metals content of catalytic cracking feedstock |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1470533A1 true DE1470533A1 (de) | 1969-10-23 |
Family
ID=22111065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1961E0021880 Pending DE1470533A1 (de) | 1960-12-01 | 1961-10-28 | Verfahren zur Entschwefelung von hochsiedenden fluessigen Kohlenwasserstoffen durch weitstufige Behandlung mit Wasserstoff |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3155608A (enrdf_load_stackoverflow) |
| DE (1) | DE1470533A1 (enrdf_load_stackoverflow) |
| GB (1) | GB960440A (enrdf_load_stackoverflow) |
| NL (1) | NL271102A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0128250A1 (en) * | 1983-06-08 | 1984-12-19 | Mobil Oil Corporation | Catalytic dewaxing process |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3340178A (en) * | 1964-08-25 | 1967-09-05 | Air Prod & Chem | Process for catalytically cracking pyrolysis condensates |
| US3349027A (en) * | 1965-02-08 | 1967-10-24 | Gulf Research Development Co | Multi-stage hydrodesulfurization process |
| US3936370A (en) * | 1973-08-22 | 1976-02-03 | Gulf Research & Development Company | Process for producing a zeolite riser cracker feed from a residual oil |
| US3926784A (en) * | 1973-08-22 | 1975-12-16 | Gulf Research Development Co | Plural stage residue hydrodesulfurization process with hydrogen sulfide addition and removal |
| US3860510A (en) * | 1973-08-22 | 1975-01-14 | Gulf Research Development Co | Combination residue hydrodesulfurization and zeolite riser cracking process |
| US3907667A (en) * | 1973-08-22 | 1975-09-23 | Gulf Research Development Co | Process for producing a lubricating oil from a residue feed |
| US3905893A (en) * | 1973-08-22 | 1975-09-16 | Gulf Research Development Co | Plural stage residue hydrodesulfurization process |
| JPS5850636B2 (ja) * | 1977-07-15 | 1983-11-11 | 千代田化工建設株式会社 | 重質炭化水素油の脱硫処理方法 |
| CA1195278A (en) * | 1981-09-28 | 1985-10-15 | Chevron Research And Technology Company | Layered residua treatment catalyst process and temperature profile |
| US4801373A (en) * | 1986-03-18 | 1989-01-31 | Exxon Research And Engineering Company | Process oil manufacturing process |
| CA2109541A1 (en) * | 1992-12-04 | 1994-06-05 | Thomas J. Ford | Aromatic oil and process for manufacture |
| JPH06299168A (ja) * | 1993-02-15 | 1994-10-25 | Shell Internatl Res Maatschappij Bv | 水素化処理法 |
| US6592748B2 (en) | 1996-06-28 | 2003-07-15 | Exxonmobil Research And Engineering Company | Reffinate hydroconversion process |
| US6325918B1 (en) | 1996-06-28 | 2001-12-04 | Exxonmobile Research And Engineering Company | Raffinate hydroconversion process |
| US6974535B2 (en) | 1996-12-17 | 2005-12-13 | Exxonmobil Research And Engineering Company | Hydroconversion process for making lubricating oil basestockes |
| JP4050364B2 (ja) * | 1997-09-11 | 2008-02-20 | 日揮株式会社 | 石油の処理方法および石油の処理装置 |
| CN101434866B (zh) * | 2007-11-15 | 2012-09-12 | 中国石油化工股份有限公司 | 一种重质馏分油加氢处理与催化裂化组合方法 |
| CN101434865B (zh) * | 2007-11-15 | 2012-12-26 | 中国石油化工股份有限公司 | 重质馏分油加氢处理与催化裂化联合方法 |
| US8210411B2 (en) | 2008-09-23 | 2012-07-03 | Ethicon Endo-Surgery, Inc. | Motor-driven surgical cutting instrument |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2760907A (en) * | 1953-09-01 | 1956-08-28 | Union Oil Co | Hydrocarbon conversion process and catalyst |
| US2769754A (en) * | 1954-05-03 | 1956-11-06 | Exxon Research Engineering Co | Process for hydrodesulfurization of coker products |
| US2901417A (en) * | 1954-05-17 | 1959-08-25 | Exxon Research Engineering Co | Hydrodesulfurization of a coked hydrocarbon stream comprising gasoline constituents and gas oil constituents |
| US2771401A (en) * | 1954-08-05 | 1956-11-20 | Exxon Research Engineering Co | Desulfurization of crude oil and crude oil fractions |
| US2889264A (en) * | 1954-12-27 | 1959-06-02 | California Research Corp | Hydrocarbon conversion process |
| US2917448A (en) * | 1956-11-15 | 1959-12-15 | Gulf Research Development Co | Hydrogenation and distillation of lubricating oils |
| US2937134A (en) * | 1957-10-28 | 1960-05-17 | Socony Mobil Oil Co Inc | Cascaded pretreater for removal of nitrogen |
| US3071542A (en) * | 1958-07-16 | 1963-01-01 | Socony Mobil Oil Co Inc | Two-stage pretreatment of reformer charge naphtha |
-
0
- NL NL271102D patent/NL271102A/xx unknown
-
1960
- 1960-12-01 US US72998A patent/US3155608A/en not_active Expired - Lifetime
-
1961
- 1961-10-13 GB GB36799/61A patent/GB960440A/en not_active Expired
- 1961-10-28 DE DE1961E0021880 patent/DE1470533A1/de active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0128250A1 (en) * | 1983-06-08 | 1984-12-19 | Mobil Oil Corporation | Catalytic dewaxing process |
Also Published As
| Publication number | Publication date |
|---|---|
| NL271102A (enrdf_load_stackoverflow) | |
| US3155608A (en) | 1964-11-03 |
| GB960440A (en) | 1964-06-10 |
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