DE1287763B - - Google Patents
Info
- Publication number
- DE1287763B DE1287763B DENDAT1287763D DE1287763DA DE1287763B DE 1287763 B DE1287763 B DE 1287763B DE NDAT1287763 D DENDAT1287763 D DE NDAT1287763D DE 1287763D A DE1287763D A DE 1287763DA DE 1287763 B DE1287763 B DE 1287763B
- Authority
- DE
- Germany
- Prior art keywords
- glass
- ceramic
- potassium
- ions
- crystal phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013078 crystal Substances 0.000 claims description 84
- 239000002241 glass-ceramic Substances 0.000 claims description 66
- 150000002500 ions Chemical class 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 31
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 30
- 239000011591 potassium Substances 0.000 claims description 30
- 229910052664 nepheline Inorganic materials 0.000 claims description 29
- 239000010434 nepheline Substances 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- 229910001416 lithium ion Inorganic materials 0.000 claims description 22
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 19
- 229910000174 eucryptite Inorganic materials 0.000 claims description 17
- 239000010453 quartz Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 229910001414 potassium ion Inorganic materials 0.000 claims description 13
- 239000002344 surface layer Substances 0.000 claims description 11
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims description 8
- 229910001415 sodium ion Inorganic materials 0.000 claims description 8
- 229910052642 spodumene Inorganic materials 0.000 claims description 8
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 6
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 6
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 238000011282 treatment Methods 0.000 description 58
- 239000011521 glass Substances 0.000 description 47
- 238000005342 ion exchange Methods 0.000 description 37
- 239000000203 mixture Substances 0.000 description 31
- 239000011734 sodium Substances 0.000 description 28
- 238000010438 heat treatment Methods 0.000 description 27
- 229910052700 potassium Inorganic materials 0.000 description 27
- 150000003839 salts Chemical class 0.000 description 26
- 208000035874 Excoriation Diseases 0.000 description 25
- 238000005299 abrasion Methods 0.000 description 25
- 229910004298 SiO 2 Inorganic materials 0.000 description 22
- 239000006112 glass ceramic composition Substances 0.000 description 20
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 16
- 229910052708 sodium Inorganic materials 0.000 description 16
- 238000007711 solidification Methods 0.000 description 15
- 230000008023 solidification Effects 0.000 description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 10
- 229910052744 lithium Inorganic materials 0.000 description 9
- 229910018068 Li 2 O Inorganic materials 0.000 description 8
- 239000001103 potassium chloride Substances 0.000 description 8
- 235000011164 potassium chloride Nutrition 0.000 description 8
- 239000006104 solid solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000007596 consolidation process Methods 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- -1 magnesium Chemical class 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 229910052644 β-spodumene Inorganic materials 0.000 description 6
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000033001 locomotion Effects 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910000500 β-quartz Inorganic materials 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000009863 impact test Methods 0.000 description 3
- 229910003002 lithium salt Inorganic materials 0.000 description 3
- 159000000002 lithium salts Chemical class 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 description 3
- 235000011151 potassium sulphates Nutrition 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 229910020068 MgAl Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910001597 celsian Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
- 239000011222 crystalline ceramic Substances 0.000 description 2
- 229910002106 crystalline ceramic Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 229910017121 AlSiO Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910008828 WSiO Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006121 base glass Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000003426 chemical strengthening reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 229910001462 kalsilite Inorganic materials 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 238000011369 optimal treatment Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 210000004127 vitreous body Anatomy 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B23/00—Re-forming shaped glass
- C03B23/04—Re-forming tubes or rods
- C03B23/08—Re-forming tubes or rods to exact dimensions, e.g. calibrating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
- C03C10/0045—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Ceramic Engineering (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36519864A | 1964-05-05 | 1964-05-05 | |
| US36503564A | 1964-05-05 | 1964-05-05 | |
| US36520264A | 1964-05-05 | 1964-05-05 | |
| US36516164A | 1964-05-05 | 1964-05-05 | |
| US36517864A | 1964-05-05 | 1964-05-05 | |
| US36520164A | 1964-05-05 | 1964-05-05 | |
| US36517764A | 1964-05-05 | 1964-05-05 | |
| US36517964A | 1964-05-05 | 1964-05-05 | |
| US36519964A | 1964-05-05 | 1964-05-05 | |
| US36520364A | 1964-05-05 | 1964-05-05 | |
| US36511764A | 1964-05-05 | 1964-05-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1287763B true DE1287763B (en)) | 1969-01-23 |
Family
ID=27582786
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT1287763D Pending DE1287763B (en)) | 1964-05-05 | ||
| DE1965C0035748 Pending DE1284065B (de) | 1964-05-05 | 1965-05-04 | Verfahren zur Herstellung verstaerkter glaskeramischer Gegenstaende |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1965C0035748 Pending DE1284065B (de) | 1964-05-05 | 1965-05-04 | Verfahren zur Herstellung verstaerkter glaskeramischer Gegenstaende |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS4831738B1 (en)) |
| BE (2) | BE663486A (en)) |
| CH (2) | CH471048A (en)) |
| DE (2) | DE1284065B (en)) |
| GB (2) | GB1105434A (en)) |
| NL (4) | NL6505742A (en)) |
| SE (2) | SE315704B (en)) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4074992A (en) | 1964-05-05 | 1978-02-21 | Corning Glass Works | Sodium ion-exchange on surface of beta-spodumene |
| JPS50125276A (en)) * | 1974-03-22 | 1975-10-02 | ||
| JPS5837592U (ja) * | 1981-09-04 | 1983-03-11 | 東芝熱器具株式会社 | ダイアル表示装置 |
| JPS58101117U (ja) * | 1981-12-28 | 1983-07-09 | 東京光学機械株式会社 | 経緯儀 |
| GB2172282B (en) * | 1985-03-11 | 1988-10-05 | English Electric Co Ltd | Toughened glass-ceramics |
| GB2190077B (en) * | 1987-11-10 | 1990-12-19 | Ceramic Developments | Armour materials. |
| DE102006056088B9 (de) * | 2006-11-28 | 2013-05-08 | Schott Ag | Verfahren zur Festigkeitssteigerung von Lithium-Alumino-Silikat-Glaskeramik durch Oberflächenmodifikation und durch dieses Verfahren hergestellte Lithium-Alumino-Silikat-Glaskeramik |
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| US20140345325A1 (en) * | 2013-05-24 | 2014-11-27 | Corning Incorporated | Double ion exchange process |
| US9409815B2 (en) | 2014-04-04 | 2016-08-09 | Corning Incorporated | Opaque colored glass-ceramics comprising nepheline crystal phases |
| TWI705889B (zh) | 2014-06-19 | 2020-10-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| US10730791B2 (en) | 2014-10-08 | 2020-08-04 | Corning Incorporated | Glasses and glass ceramics including a metal oxide concentration gradient |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| ES2879650T3 (es) | 2015-12-11 | 2021-11-22 | Corning Inc | Artículos a base de vidrio formables por fusión que incluyen un gradiente de concentración de óxido de metal |
| KR20210068158A (ko) | 2016-04-08 | 2021-06-08 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함하는 유리-계 제품 |
| EP4269368A3 (en) | 2016-04-08 | 2023-11-22 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
| CN112299707A (zh) * | 2016-05-31 | 2021-02-02 | 康宁股份有限公司 | 展现出改进的破裂性能的玻璃制品 |
| WO2019191358A1 (en) * | 2018-03-29 | 2019-10-03 | Corning Incorporated | Ion exchanged glass-ceramic articles |
| CN112823145B (zh) * | 2018-09-28 | 2023-10-31 | 康宁股份有限公司 | 增强的离子交换方法 |
| CN111606572A (zh) * | 2020-04-29 | 2020-09-01 | 深圳精匠云创科技有限公司 | 钠铝硅酸盐纳米晶透明陶瓷、其制备方法及产品 |
-
0
- NL NL132232D patent/NL132232C/xx active
- DE DENDAT1287763D patent/DE1287763B/de active Pending
- NL NL132488D patent/NL132488C/xx active
-
1965
- 1965-04-26 GB GB1748865A patent/GB1105434A/en not_active Expired
- 1965-04-26 GB GB1748765A patent/GB1105433A/en not_active Expired
- 1965-05-03 CH CH609765A patent/CH471048A/de not_active IP Right Cessation
- 1965-05-03 CH CH609665A patent/CH471047A/de not_active IP Right Cessation
- 1965-05-04 JP JP2598965A patent/JPS4831738B1/ja active Pending
- 1965-05-04 DE DE1965C0035748 patent/DE1284065B/de active Pending
- 1965-05-05 BE BE663486D patent/BE663486A/xx unknown
- 1965-05-05 BE BE663485D patent/BE663485A/xx unknown
- 1965-05-05 SE SE587665A patent/SE315704B/xx unknown
- 1965-05-05 SE SE587765A patent/SE305727B/xx unknown
- 1965-05-06 NL NL6505742A patent/NL6505742A/xx unknown
- 1965-05-06 NL NL6505743A patent/NL6505743A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6505742A (en)) | 1965-11-08 |
| BE663485A (en)) | 1965-11-05 |
| GB1105434A (en) | 1968-03-06 |
| NL132232C (en)) | |
| NL132488C (en)) | |
| GB1105433A (en) | 1968-03-06 |
| JPS4831738B1 (en)) | 1973-10-01 |
| NL6505743A (en)) | 1965-11-08 |
| DE1284065B (de) | 1968-11-28 |
| CH471048A (de) | 1969-04-15 |
| CH471047A (de) | 1969-04-15 |
| SE305727B (en)) | 1968-11-04 |
| SE315704B (en)) | 1969-10-06 |
| BE663486A (en)) | 1965-11-05 |
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