DE1276264B - Verfahren zur Herstellung von Schmieroelfraktionen mit hohem Viskositaetsindex - Google Patents
Verfahren zur Herstellung von Schmieroelfraktionen mit hohem ViskositaetsindexInfo
- Publication number
- DE1276264B DE1276264B DES102875A DES0102875A DE1276264B DE 1276264 B DE1276264 B DE 1276264B DE S102875 A DES102875 A DE S102875A DE S0102875 A DES0102875 A DE S0102875A DE 1276264 B DE1276264 B DE 1276264B
- Authority
- DE
- Germany
- Prior art keywords
- oil
- hydrogen
- reaction zone
- lubricating oil
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010687 lubricating oil Substances 0.000 title claims description 57
- 238000000034 method Methods 0.000 title claims description 37
- 230000008569 process Effects 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000003921 oil Substances 0.000 claims description 90
- 238000006243 chemical reaction Methods 0.000 claims description 70
- 239000007789 gas Substances 0.000 claims description 60
- 239000003054 catalyst Substances 0.000 claims description 50
- 239000001257 hydrogen Substances 0.000 claims description 50
- 229910052739 hydrogen Inorganic materials 0.000 claims description 50
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 49
- 229930195733 hydrocarbon Natural products 0.000 claims description 42
- 150000002430 hydrocarbons Chemical class 0.000 claims description 42
- 238000009835 boiling Methods 0.000 claims description 41
- 238000003776 cleavage reaction Methods 0.000 claims description 35
- 230000007017 scission Effects 0.000 claims description 34
- 239000004215 Carbon black (E152) Substances 0.000 claims description 30
- 239000007795 chemical reaction product Substances 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 23
- 238000000926 separation method Methods 0.000 claims description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- 239000011593 sulfur Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 9
- 238000005984 hydrogenation reaction Methods 0.000 claims description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 239000011737 fluorine Substances 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 239000011541 reaction mixture Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052810 boron oxide Inorganic materials 0.000 claims 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 30
- 229910021529 ammonia Inorganic materials 0.000 description 15
- 239000000047 product Substances 0.000 description 11
- 239000003502 gasoline Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000004821 distillation Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 239000007858 starting material Substances 0.000 description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910017464 nitrogen compound Inorganic materials 0.000 description 4
- 150000002830 nitrogen compounds Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011874 heated mixture Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011436 cob Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- -1 platinum metals Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL656504066A NL144326B (nl) | 1965-03-31 | 1965-03-31 | Werkwijze voor het hydrogenerend kraken van een koolwaterstofolie. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1276264B true DE1276264B (de) | 1968-08-29 |
Family
ID=19792799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES102875A Pending DE1276264B (de) | 1965-03-31 | 1966-03-29 | Verfahren zur Herstellung von Schmieroelfraktionen mit hohem Viskositaetsindex |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3444071A (enrdf_load_stackoverflow) |
| BE (1) | BE678609A (enrdf_load_stackoverflow) |
| CH (1) | CH479687A (enrdf_load_stackoverflow) |
| DE (1) | DE1276264B (enrdf_load_stackoverflow) |
| ES (1) | ES324827A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1121443A (enrdf_load_stackoverflow) |
| NL (1) | NL144326B (enrdf_load_stackoverflow) |
| NO (1) | NO115222B (enrdf_load_stackoverflow) |
| SE (1) | SE308936B (enrdf_load_stackoverflow) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3617484A (en) * | 1968-11-29 | 1971-11-02 | Sun Oil Co | Increasing the v.i. of hydrocracked light lubes |
| BE754805A (fr) * | 1969-09-05 | 1971-02-15 | Atlantic Richfield Co | Procede perfectionne de preparation d'huile minerale lubrifiante a partir de nouvelles matieres premieres |
| US3617482A (en) * | 1969-11-10 | 1971-11-02 | Chevron Res | Process for the production of lubricating oils |
| US3666657A (en) * | 1970-11-16 | 1972-05-30 | Sun Oil Co Pennsylvania | Oil stabilizing sequential hydrocracking and hydrogenation treatment |
| US3992283A (en) * | 1974-09-23 | 1976-11-16 | Universal Oil Products Company | Hydrocracking process for the maximization of an improved viscosity lube oil |
| US4743355A (en) * | 1979-10-15 | 1988-05-10 | Union Oil Company Of California | Process for producing a high quality lube oil stock |
| US4743354A (en) * | 1979-10-15 | 1988-05-10 | Union Oil Company Of California | Process for producing a product hydrocarbon having a reduced content of normal paraffins |
| US4419271A (en) * | 1979-10-15 | 1983-12-06 | Union Oil Company Of California | Hydrocarbon conversion catalyst |
| US4592828A (en) * | 1984-05-07 | 1986-06-03 | Mobil Oil Corporation | Process for upgrading petroleum residua |
| US5250588A (en) * | 1990-01-16 | 1993-10-05 | Ceram Sna Inc. | Organic friction material composition for use to produce friction linings |
| US5358628A (en) * | 1990-07-05 | 1994-10-25 | Mobil Oil Corporation | Production of high viscosity index lubricants |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3047490A (en) * | 1958-11-04 | 1962-07-31 | Phillips Petroleum Co | Hydrocracking process |
| FR1327395A (fr) * | 1962-05-29 | 1963-05-17 | California Research Corp | Procédé de craquage hydrogénant d'hydrocarbures pétroliers |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242068A (en) * | 1962-12-24 | 1966-03-22 | Chevron Res | Production of lubricating oil |
| US3308055A (en) * | 1964-04-13 | 1967-03-07 | Chevron Res | Hydrocracking process producing lubricating oil |
-
1965
- 1965-03-31 NL NL656504066A patent/NL144326B/xx unknown
-
1966
- 1966-03-18 US US535354A patent/US3444071A/en not_active Expired - Lifetime
- 1966-03-29 SE SE4170/66A patent/SE308936B/xx unknown
- 1966-03-29 ES ES0324827A patent/ES324827A1/es not_active Expired
- 1966-03-29 GB GB13785/66A patent/GB1121443A/en not_active Expired
- 1966-03-29 BE BE678609D patent/BE678609A/xx unknown
- 1966-03-29 CH CH455566A patent/CH479687A/de not_active IP Right Cessation
- 1966-03-29 NO NO162334A patent/NO115222B/no unknown
- 1966-03-29 DE DES102875A patent/DE1276264B/de active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3047490A (en) * | 1958-11-04 | 1962-07-31 | Phillips Petroleum Co | Hydrocracking process |
| FR1327395A (fr) * | 1962-05-29 | 1963-05-17 | California Research Corp | Procédé de craquage hydrogénant d'hydrocarbures pétroliers |
Also Published As
| Publication number | Publication date |
|---|---|
| BE678609A (enrdf_load_stackoverflow) | 1966-09-29 |
| NL6504066A (enrdf_load_stackoverflow) | 1966-10-03 |
| GB1121443A (en) | 1968-07-24 |
| SE308936B (enrdf_load_stackoverflow) | 1969-03-03 |
| ES324827A1 (es) | 1967-02-16 |
| NL144326B (nl) | 1974-12-16 |
| US3444071A (en) | 1969-05-13 |
| CH479687A (de) | 1969-10-15 |
| NO115222B (enrdf_load_stackoverflow) | 1968-09-02 |
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