DE1232685B - Katalysatoren zum Spalten von Kohlenwasserstoffen - Google Patents
Katalysatoren zum Spalten von KohlenwasserstoffenInfo
- Publication number
- DE1232685B DE1232685B DEE15807A DEE0015807A DE1232685B DE 1232685 B DE1232685 B DE 1232685B DE E15807 A DEE15807 A DE E15807A DE E0015807 A DEE0015807 A DE E0015807A DE 1232685 B DE1232685 B DE 1232685B
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- sodium
- metal
- catalysts
- generation factor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims description 62
- 229930195733 hydrocarbon Natural products 0.000 title claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 239000011734 sodium Substances 0.000 claims description 23
- 239000011148 porous material Substances 0.000 claims description 20
- -1 aluminum silicates Chemical class 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 238000003776 cleavage reaction Methods 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 7
- 230000007017 scission Effects 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 239000003245 coal Substances 0.000 claims description 5
- 239000000571 coke Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 241001000287 Helvetia Species 0.000 claims 1
- 239000003502 gasoline Substances 0.000 claims 1
- 238000010998 test method Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000000243 solution Substances 0.000 description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 16
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 15
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 15
- 239000000047 product Substances 0.000 description 13
- 229910004298 SiO 2 Inorganic materials 0.000 description 12
- 239000000395 magnesium oxide Substances 0.000 description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 10
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 229910001388 sodium aluminate Inorganic materials 0.000 description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
- 239000004115 Sodium Silicate Substances 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- 229910052911 sodium silicate Inorganic materials 0.000 description 8
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 7
- 229910001948 sodium oxide Inorganic materials 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 235000019795 sodium metasilicate Nutrition 0.000 description 6
- 239000000017 hydrogel Substances 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000000274 adsorptive effect Effects 0.000 description 3
- 150000004645 aluminates Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910020175 SiOH Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- YFONKFDEZLYQDH-BOURZNODSA-N indaziflam Chemical compound CC(F)C1=NC(N)=NC(N[C@H]2C3=CC(C)=CC=C3C[C@@H]2C)=N1 YFONKFDEZLYQDH-BOURZNODSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- AGIMJDFJHWOHBM-UHFFFAOYSA-N magnesium oxygen(2-) silicic acid Chemical compound [O-2].[Mg+2].O[Si](O)(O)O AGIMJDFJHWOHBM-UHFFFAOYSA-N 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 125000004436 sodium atom Chemical group 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
- C07C5/222—Catalytic processes not covered by C07C5/23 - C07C5/31 with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
- C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US638232A US2971903A (en) | 1957-02-05 | 1957-02-05 | Hydrocarbon conversion catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1232685B true DE1232685B (de) | 1967-01-19 |
Family
ID=26183418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEE15807A Pending DE1232685B (de) | 1957-02-05 | 1958-04-29 | Katalysatoren zum Spalten von Kohlenwasserstoffen |
Country Status (7)
Country | Link |
---|---|
US (2) | US2971903A (en, 2012) |
BE (1) | BE608029A (en, 2012) |
CA (1) | CA645825A (en, 2012) |
DE (1) | DE1232685B (en, 2012) |
FR (2) | FR1198719A (en, 2012) |
GB (1) | GB824543A (en, 2012) |
IT (1) | IT588545A1 (en, 2012) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1297271B (de) * | 1963-05-13 | 1969-06-12 | Mobil Oil Corp | Verfahren zum katalytischen Kracken von Kohlenwasserstoffen |
Families Citing this family (90)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3207803A (en) * | 1965-09-21 | Desorption of molecular sieves by | ||
US3236761A (en) * | 1951-01-28 | 1966-02-22 | Union Carbide Corp | Hydrocarbon conversion process and catalyst |
US3098032A (en) * | 1957-05-22 | 1963-07-16 | Exxon Research Engineering Co | Hydrodesulfurization process employing cobalt-molybdenum-molecular sieve catalyst |
US4054510A (en) * | 1958-06-13 | 1977-10-18 | Exxon Research And Engineering Company | Selective conversion of normal paraffins |
US3114696A (en) * | 1958-10-03 | 1963-12-17 | Socony Mobil Oil Co Inc | Upgrading of naphthas |
US3114695A (en) * | 1959-12-30 | 1963-12-17 | Union Carbide Corp | Amorphous aluminosilicate catalyst compositions for hydrocarbon conversion reactions |
US3136713A (en) * | 1960-06-30 | 1964-06-09 | Socony Mobil Oil Co Inc | Selective combustion |
US3140249A (en) * | 1960-07-12 | 1964-07-07 | Socony Mobil Oil Co Inc | Catalytic cracking of hydrocarbons with a crystalline zeolite catalyst composite |
US3097115A (en) * | 1960-08-01 | 1963-07-09 | Leesona Corp | Catalysts and electrodes for fuel cells |
US3193493A (en) * | 1960-10-17 | 1965-07-06 | Socony Mobil Oil Co Inc | Catalytic cracking process with a catalyst composition comprising an aluminosilicate containing beryllium |
NL273443A (en, 2012) * | 1961-03-08 | |||
US3298780A (en) * | 1961-03-21 | 1967-01-17 | Union Oil Co | Process for preparing a crystalline zeolite |
US3324188A (en) * | 1961-06-02 | 1967-06-06 | Norton Co | Catalytic isomerization of hydrocarbons |
US3219592A (en) * | 1961-08-08 | 1965-11-23 | Sun Oil Co | Silica-alumina cracking catalysts ionexchanged with cuprous copper, silver, or aurous gold |
US3254131A (en) * | 1961-08-11 | 1966-05-31 | Socony Mobil Oil Co Inc | Catalytic synthesis of condensation products from mercaptans |
US3201356A (en) * | 1961-09-27 | 1965-08-17 | Exxon Research Engineering Co | Molecular sieve catalyst activation process |
US3221073A (en) * | 1961-10-27 | 1965-11-30 | Monsanto Co | Purification of olefins |
US3178365A (en) * | 1961-12-15 | 1965-04-13 | Socony Mobil Oil Co Inc | Catalytic conversion of hydrocarbons with the use of a nitrogen compound as an activator |
US3236910A (en) * | 1961-12-18 | 1966-02-22 | Union Carbide Corp | Dehydrogenation process employing a chromium containing zeolite |
NL132193C (en, 2012) * | 1961-12-21 | |||
US3140252A (en) * | 1961-12-21 | 1964-07-07 | Socony Mobil Oil Co Inc | Hydrocarbon conversion with crystalline acid-metal aluminosilicates |
US3175967A (en) * | 1962-01-11 | 1965-03-30 | Socony Mobil Oil Co Inc | Catalytic conversion with activated catalyst |
GB1020132A (en) * | 1962-01-24 | 1966-02-16 | Exxon Research Engineering Co | Catalytic cracking process |
US3236903A (en) * | 1962-02-06 | 1966-02-22 | Union Carbide Corp | Hydrocarbon upgrading process |
NL288698A (en, 2012) * | 1962-02-07 | 1900-01-01 | ||
US3143491A (en) * | 1962-02-20 | 1964-08-04 | Socony Mobil Oil Co Inc | Catalytic conversion of hydrocarbons with a silica-alumina and crystalline zeolite catalyst composite |
US3404192A (en) * | 1962-03-07 | 1968-10-01 | Sinclair Research Inc | Process for selective hydrogenation of olefins with deactivated zeolite catalyst |
US3255103A (en) * | 1962-03-20 | 1966-06-07 | Socony Mobil Oil Co Inc | Catalytic conversion of hydrocarbons with catalyst activity adjustment |
US3146279A (en) * | 1962-04-04 | 1964-08-25 | Sinclair Research Inc | Selective isomerization process |
US3247099A (en) * | 1962-04-05 | 1966-04-19 | Socony Mobil Oil Co Inc | Catalytic reforming |
US3163594A (en) * | 1962-04-05 | 1964-12-29 | Exxon Research Engineering Co | Color improvement of hydrocarbon oil fractions |
US3278418A (en) * | 1962-04-30 | 1966-10-11 | Shell Oil Co | Hydrocarbon conversion catalyst for the hydrocracking of hydrocarbon oils, comprising rhenium and silver on a silica-alumina cracking base |
NL292103A (en, 2012) * | 1962-04-30 | |||
US3436357A (en) * | 1962-05-17 | 1969-04-01 | Mobil Oil Corp | Catalyst and conversion of organic compounds in the presence thereof |
US3238147A (en) * | 1962-05-24 | 1966-03-01 | Socony Mobil Oil Co | Crystalline aluminosilicate hydrocarbon conversion catalyst composite and method of preparation thereof |
US3352796A (en) * | 1962-09-11 | 1967-11-14 | Exxon Research Engineering Co | Catalyst for hydrocarbon conversions |
US3275571A (en) * | 1962-09-11 | 1966-09-27 | Exxon Research Engineering Co | Crystalline zeolite composition and method of preparation thereof |
NL301317A (en, 2012) * | 1962-12-05 | |||
NL300835A (en, 2012) * | 1962-12-06 | |||
US3287282A (en) * | 1962-12-07 | 1966-11-22 | Union Oil Co | Hydrogen zeolite y having improved hydrothermal stability |
US3370099A (en) * | 1962-12-12 | 1968-02-20 | Mobil Oil Corp | Isomerization process |
US3251897A (en) * | 1962-12-20 | 1966-05-17 | Socony Mobil Oil Co Inc | Alkylation of aromatic compounds in the presence of an alumino-silicate catalyst |
NL301845A (en, 2012) * | 1962-12-28 | |||
US3247278A (en) * | 1963-03-21 | 1966-04-19 | Socony Mobil Oil Co Inc | Catalytic reactions of sulfur with organic compounds |
US3228889A (en) * | 1963-04-23 | 1966-01-11 | Socony Mobil Oil Co Inc | Conversion catalyst comprising an aluminosilicate prepared from a hydrogen organoperoxymetalloaluminosilicate |
US3255101A (en) * | 1963-06-20 | 1966-06-07 | Exxon Research Engineering Co | Hydrocracking process with the use of a crystalline zeolite containing iron |
DE1297792B (de) * | 1963-06-28 | 1969-06-19 | Mobil Oil Corp | Verfahren zum katalytischen Kracken eines Kohlenwasserstoffoels |
GB1058855A (en) * | 1963-07-10 | 1967-02-15 | Exxon Research Engineering Co | Catalytic cracking of hydrocarbons |
US3251902A (en) * | 1963-07-15 | 1966-05-17 | Socony Mobil Oil Co Inc | Isoparaffin-olefin alkylation using crystalline zeolite catalyst |
US3369048A (en) * | 1963-08-08 | 1968-02-13 | Mobil Oil Corp | Aldehyde synthesis |
US3190939A (en) * | 1963-08-19 | 1965-06-22 | Shell Oil Co | Paraffin isomerization process using hydrogen mordenite catalyst |
DE1250039C2 (de) * | 1963-08-23 | 1973-02-22 | Verfahren zum hydrocracken von stickstoffhaltigen kohlenwasserstoffoelen | |
US3248319A (en) * | 1963-08-30 | 1966-04-26 | Socony Mobil Oil Co Inc | Method and means for converting hydrocarbon in the presence of hydrogen in the conversion and regeneration zones |
US3479149A (en) * | 1963-09-10 | 1969-11-18 | Mobil Oil Corp | Process for reducing carbon dioxide with hydrogen to carbon monoxide |
US3402217A (en) * | 1963-11-20 | 1968-09-17 | Monsanto Co | Process for preparing olefin hydrocarbons for detergent use |
US3325397A (en) * | 1963-12-06 | 1967-06-13 | Mobil Oil Corp | Catalytic hydrocarbon conversion with the use of a catalyst composite comprising a manganese promoted crystalline aluminosilicate |
DE1296726B (de) * | 1963-12-24 | 1969-06-04 | Mobil Oil Corp | Verfahren zum Reformieren von Schwerbenzin in Gegenwart eines Katalysators aus einem kristallinen Aluminiumsilikat |
US3140253A (en) * | 1964-05-01 | 1964-07-07 | Socony Mobil Oil Co Inc | Catalytic hydrocarbon conversion with a crystalline zeolite composite catalyst |
US3280212A (en) * | 1964-08-18 | 1966-10-18 | Mobil Oil Corp | Conversion of hydrocarbons |
NL6511293A (en, 2012) * | 1964-09-14 | 1966-03-15 | ||
US3301917A (en) * | 1964-09-22 | 1967-01-31 | Mobil Oil Corp | Upgrading of paraffinic hydrocarbons in the presence of a mixed aluminosilicate, platinum metal catalyst |
US3312615A (en) * | 1965-04-09 | 1967-04-04 | Mobil Oil Corp | Catalyst composition containing a crystalline alumino-silicate, a siliceous matrix and inerts for the conversion of hydrocarbons |
US4016246A (en) * | 1965-04-09 | 1977-04-05 | Laporte Industries Limited | Manufacture of synthetic zeolites |
US3210267A (en) * | 1965-04-20 | 1965-10-05 | Socony Mobil Oil Co Inc | Catalytic cracking of hydrocarbons with the use of a crystalline zeolite catalyst containing rare earths and a porous matrix |
US3385906A (en) * | 1965-05-25 | 1968-05-28 | Union Carbide Corp | Production of cumene |
US3271418A (en) * | 1965-06-22 | 1966-09-06 | Mobil Oil Corp | Catalytic conversion of hydrocarbons with a crystalline alumino-silicate in a silica-alumina matrix |
US3392180A (en) * | 1965-07-12 | 1968-07-09 | Mobil Oil Corp | Catalystic process for reactions of alkyl aluminum compounds |
US3397137A (en) * | 1965-07-16 | 1968-08-13 | Union Carbide Corp | Hydrocarbon reforming process and catalyst compositions therefor |
US3373110A (en) * | 1966-04-14 | 1968-03-12 | Mobil Oil Corp | Process for the preparation of platinum metal containing aluminosilicates |
US3669903A (en) * | 1966-06-16 | 1972-06-13 | Mobil Oil Corp | Catalytic cracking process |
US3533939A (en) * | 1966-10-12 | 1970-10-13 | Mobil Oil Corp | Reforming with a crystalline aluminosilicate free of hydrogenation activity |
US3413370A (en) * | 1967-06-30 | 1968-11-26 | Universal Oil Prod Co | Saturated hydrocarbon isomerization process |
US3511888A (en) * | 1968-02-08 | 1970-05-12 | Shell Oil Co | Paraffin conversion catalyst and process |
US3459680A (en) * | 1969-01-02 | 1969-08-05 | Mobil Oil Corp | Crystalline zeolite composite for catalytic hydrocarbon conversion |
US3627674A (en) * | 1969-11-06 | 1971-12-14 | Universal Oil Prod Co | Catalyst composition and hydrodesulfurization with an extruded composite containing alumina, group vi-b metal and zinc component |
US3760024A (en) * | 1971-06-16 | 1973-09-18 | Mobil Oil Corp | Preparation of aromatics |
US3832414A (en) * | 1972-12-11 | 1974-08-27 | Sun Research Development | Dehydrocyclization of hydrocarbons |
US3890218A (en) * | 1974-03-29 | 1975-06-17 | Mobil Oil Corp | Upgrading aliphatic naphthas to higher octane gasoline |
US3871993A (en) * | 1974-03-29 | 1975-03-18 | Mobil Oil Corp | Upgrading the octane value of naphtha employing a crystalline aluminosilicate zeolite which has a high silica to alumina ratio wherein alumina is incorporated in the interstices of the zeolite crystal |
US4034053A (en) * | 1975-12-08 | 1977-07-05 | Mobil Oil Corporation | Selective production of para-xylene |
US4146462A (en) | 1978-05-19 | 1979-03-27 | Rustamov Musa I O | Hydroisomerization of gasoline fraction |
US4284529A (en) * | 1979-12-14 | 1981-08-18 | Mobil Oil Corporation | Hydrocarbon conversion catalyst |
US4451578A (en) | 1982-04-26 | 1984-05-29 | United Technologies Corporation | Iron oxide catalyst for steam reforming |
US4929338A (en) * | 1983-04-21 | 1990-05-29 | W. R. Grace & Co. - Conn. | Catalytic cracking catalyst and process |
US4585897A (en) * | 1984-08-24 | 1986-04-29 | Standard Oil Company (Indiana) | Process for preparation of fuel additives from acetylene |
FR2601601A1 (fr) * | 1986-07-16 | 1988-01-22 | Total France | Catalyseur d'isomerisation d'hydrocarbures, procede de preparation et application dudit catalyseur. |
IT1248985B (it) * | 1990-06-22 | 1995-02-11 | Eniricerche Spa | Procedimento per oligomerizzare olefine leggere |
US9993810B2 (en) | 2012-07-23 | 2018-06-12 | W. R. Grace & Co.-Conn | Silica sol bound catalytic cracking catalyst stabilized with magnesium |
US10005072B2 (en) | 2012-07-23 | 2018-06-26 | W. R. Grace & Co.-Conn | High matrix surface area catalytic cracking catalyst stabilized with magnesium and silica |
CN106140078B (zh) * | 2016-06-30 | 2019-06-28 | 中国海洋石油集团有限公司 | 一种双金属芳烃吸附剂的制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE365366C (de) * | 1915-03-31 | 1922-12-13 | Permutit Akt Ges | Verfahren zur Ausfuehrung chemischer Reaktionen, die auf katalytischen Vorgaengen beruhen |
DE869200C (de) * | 1951-04-18 | 1953-03-05 | Basf Ag | Verfahren zur Druckhydrierung, Dehydrierung, Reformierung oder Spaltung von Kohlenwasserstoffen |
US2658875A (en) * | 1950-03-27 | 1953-11-10 | Shell Dev | Nickel catalyst and preparation thereof |
DE914972C (de) * | 1951-08-01 | 1954-07-12 | Basf Ag | Verfahren zur Druckhydrierung, Dehydrierung, Reformierung oder Spaltung von Kohlenwasserstoffen |
DE928168C (de) * | 1944-10-15 | 1955-05-26 | Ruhrchemie Ag | Verfahren zu Dehydrierung von hoehermolekularen Kohlenwasserstoffen |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2522426A (en) * | 1945-05-30 | 1950-09-12 | Standard Oil Dev Co | Method of extrcting hydrocarbons |
US2818455A (en) * | 1955-03-28 | 1957-12-31 | Texas Co | Desorption of straight chain hydrocarbons from selective adsorbents |
US2834429A (en) * | 1955-10-25 | 1958-05-13 | Texas Co | Treating process employing a fluidized mass of adsorbent |
-
0
- BE BE608029D patent/BE608029A/xx unknown
- CA CA645825A patent/CA645825A/en not_active Expired
- IT IT588545D patent/IT588545A1/it unknown
-
1957
- 1957-02-05 US US638232A patent/US2971903A/en not_active Expired - Lifetime
-
1958
- 1958-02-04 FR FR1198719D patent/FR1198719A/fr not_active Expired
- 1958-04-22 GB GB12739/58A patent/GB824543A/en not_active Expired
- 1958-04-29 DE DEE15807A patent/DE1232685B/de active Pending
-
1960
- 1960-11-09 FR FR843494A patent/FR1320007A/fr not_active Expired
-
1962
- 1962-08-24 US US21934962 patent/USRE26188E/en not_active Expired
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE365366C (de) * | 1915-03-31 | 1922-12-13 | Permutit Akt Ges | Verfahren zur Ausfuehrung chemischer Reaktionen, die auf katalytischen Vorgaengen beruhen |
DE928168C (de) * | 1944-10-15 | 1955-05-26 | Ruhrchemie Ag | Verfahren zu Dehydrierung von hoehermolekularen Kohlenwasserstoffen |
US2658875A (en) * | 1950-03-27 | 1953-11-10 | Shell Dev | Nickel catalyst and preparation thereof |
DE869200C (de) * | 1951-04-18 | 1953-03-05 | Basf Ag | Verfahren zur Druckhydrierung, Dehydrierung, Reformierung oder Spaltung von Kohlenwasserstoffen |
DE914972C (de) * | 1951-08-01 | 1954-07-12 | Basf Ag | Verfahren zur Druckhydrierung, Dehydrierung, Reformierung oder Spaltung von Kohlenwasserstoffen |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1297271B (de) * | 1963-05-13 | 1969-06-12 | Mobil Oil Corp | Verfahren zum katalytischen Kracken von Kohlenwasserstoffen |
Also Published As
Publication number | Publication date |
---|---|
US2971903A (en) | 1961-02-14 |
FR1198719A (fr) | 1959-12-09 |
GB824543A (en) | 1959-12-02 |
FR1320007A (fr) | 1963-03-08 |
USRE26188E (en) | 1967-04-11 |
BE608029A (en, 2012) | 1900-01-01 |
IT588545A1 (en, 2012) | 1900-01-01 |
CA645825A (en) | 1962-07-31 |
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