DE1215367B - Verfahren zur Polymerisation von Styrol oder kernmethylierten Styrolen - Google Patents
Verfahren zur Polymerisation von Styrol oder kernmethylierten StyrolenInfo
- Publication number
- DE1215367B DE1215367B DED35462A DED0035462A DE1215367B DE 1215367 B DE1215367 B DE 1215367B DE D35462 A DED35462 A DE D35462A DE D0035462 A DED0035462 A DE D0035462A DE 1215367 B DE1215367 B DE 1215367B
- Authority
- DE
- Germany
- Prior art keywords
- butadiene
- styrene
- cis
- polymerization
- styrenes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 32
- 238000000034 method Methods 0.000 title claims description 9
- 150000003440 styrenes Chemical class 0.000 title claims description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000012442 inert solvent Substances 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 description 7
- 229920002857 polybutadiene Polymers 0.000 description 7
- 239000004793 Polystyrene Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- OMNYXCUDBQKCMU-UHFFFAOYSA-N 2,4-dichloro-1-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C(Cl)=C1 OMNYXCUDBQKCMU-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229920003194 trans-1,4-polybutadiene polymer Polymers 0.000 description 1
- -1 vinyl aromatic compounds Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6955/60A GB948303A (en) | 1960-02-27 | 1960-02-27 | Improved styrene polymer compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1215367B true DE1215367B (de) | 1966-04-28 |
Family
ID=9823897
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED35462A Pending DE1215367B (de) | 1960-02-27 | 1961-02-22 | Verfahren zur Polymerisation von Styrol oder kernmethylierten Styrolen |
| DE19611570483 Pending DE1570483A1 (de) | 1960-02-27 | 1961-02-22 | Verfahren zur Herstellung von Styrolmischpolymerisaten hoher Zaehigkeit |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19611570483 Pending DE1570483A1 (de) | 1960-02-27 | 1961-02-22 | Verfahren zur Herstellung von Styrolmischpolymerisaten hoher Zaehigkeit |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3929936A (en, 2012) |
| BE (1) | BE687745A (en, 2012) |
| DE (2) | DE1215367B (en, 2012) |
| FR (1) | FR1280529A (en, 2012) |
| GB (1) | GB948303A (en, 2012) |
| IT (1) | IT648973A (en, 2012) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE613240A (en, 2012) * | 1961-01-30 | |||
| US3976725A (en) * | 1971-09-24 | 1976-08-24 | General Electric Company | High impact strength thermoplastic compositions |
| US4096205A (en) * | 1975-08-29 | 1978-06-20 | Standard Oil Company (Indiana) | Method to produce improved rubber-modified styrene polymer |
| US4312802A (en) * | 1977-08-31 | 1982-01-26 | United States Steel Corporation | Polymer compositions and articles therefrom |
| US4294937A (en) * | 1979-06-18 | 1981-10-13 | Shell Oil Company | Impact polymers |
| US4267283A (en) * | 1980-06-16 | 1981-05-12 | Shell Oil Company | Styrenic impact polymers |
| US4379884A (en) * | 1981-12-30 | 1983-04-12 | Phillips Petroleum Company | Copolymer blend of improved impact resistance |
| US5247020A (en) * | 1990-01-30 | 1993-09-21 | Idemitsu Kosan Co., Ltd. | Process for producing a styrene polymer composition |
| US6653404B2 (en) * | 2000-05-01 | 2003-11-25 | Jsr Corporation | Rubber compositions |
| US10597553B2 (en) * | 2011-03-25 | 2020-03-24 | Allnex Netherlands B.V. | Waterborne coating composition |
| CN112430369B (zh) * | 2020-12-05 | 2022-12-02 | 勇气模具塑胶(苏州)有限公司 | 一种冰箱抽屉材料及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1056373B (de) * | 1954-06-18 | 1959-04-30 | Monsanto Chemicals | Verfahren zur Herstellung neuartiger Kunststoffe aus Polystyrol und natuerlichem oder kuenstlichem Kautschuk |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3264374A (en) * | 1963-01-02 | 1966-08-02 | Monsanto Co | Graft copolymer formed by polymerizing butadiene in styrene with an alkylli catalyst, deactivating the catalyst and adding an organic peroxide |
-
0
- IT IT648973D patent/IT648973A/it unknown
-
1960
- 1960-02-27 GB GB6955/60A patent/GB948303A/en not_active Expired
-
1961
- 1961-02-22 DE DED35462A patent/DE1215367B/de active Pending
- 1961-02-22 DE DE19611570483 patent/DE1570483A1/de active Pending
- 1961-02-24 FR FR853742A patent/FR1280529A/fr not_active Expired
-
1966
- 1966-10-03 BE BE687745D patent/BE687745A/xx unknown
-
1973
- 1973-04-16 US US351712A patent/US3929936A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1056373B (de) * | 1954-06-18 | 1959-04-30 | Monsanto Chemicals | Verfahren zur Herstellung neuartiger Kunststoffe aus Polystyrol und natuerlichem oder kuenstlichem Kautschuk |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1570483A1 (de) | 1972-03-23 |
| FR1280529A (fr) | 1961-12-29 |
| BE687745A (en, 2012) | 1967-03-16 |
| US3929936A (en) | 1975-12-30 |
| GB948303A (en) | 1964-01-29 |
| IT648973A (en, 2012) |
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