DE1176654B - Verfahren zur Herstellung von Organo-zinnverbindungen - Google Patents
Verfahren zur Herstellung von Organo-zinnverbindungenInfo
- Publication number
- DE1176654B DE1176654B DEP23295A DEP0023295A DE1176654B DE 1176654 B DE1176654 B DE 1176654B DE P23295 A DEP23295 A DE P23295A DE P0023295 A DEP0023295 A DE P0023295A DE 1176654 B DE1176654 B DE 1176654B
- Authority
- DE
- Germany
- Prior art keywords
- acid
- salts
- production
- benzene
- organotin compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- UIJGNTRUPZPVNG-UHFFFAOYSA-N benzenecarbothioic s-acid Chemical compound SC(=O)C1=CC=CC=C1 UIJGNTRUPZPVNG-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 150000003606 tin compounds Chemical class 0.000 description 4
- IQBLWPLYPNOTJC-FPLPWBNLSA-N (z)-4-(2-ethylhexoxy)-4-oxobut-2-enoic acid Chemical compound CCCCC(CC)COC(=O)\C=C/C(O)=O IQBLWPLYPNOTJC-FPLPWBNLSA-N 0.000 description 3
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- -1 thiol compound Chemical class 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical class CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 2
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000005840 aryl radicals Chemical group 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- DRNWASHEONIABT-UHFFFAOYSA-N dibenzyl(oxo)tin Chemical compound C=1C=CC=CC=1C[Sn](=O)CC1=CC=CC=C1 DRNWASHEONIABT-UHFFFAOYSA-N 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical class CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- FOPKRSSYSAUFNZ-UHFFFAOYSA-N dipropyltin Chemical class CCC[Sn]CCC FOPKRSSYSAUFNZ-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB25334/58A GB855214A (en) | 1958-08-07 | 1958-08-07 | Organo-tin compounds containing sulphur and their application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1176654B true DE1176654B (de) | 1964-08-27 |
Family
ID=10225998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEP23295A Pending DE1176654B (de) | 1958-08-07 | 1959-08-01 | Verfahren zur Herstellung von Organo-zinnverbindungen |
Country Status (4)
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB751499A (en) * | 1953-01-22 | 1956-06-27 | Metal & Thermit Corp | Hydrocarbon tin mixed salts of monocarboxylic aliphatic and maleic acids |
| AT191908B (de) * | 1954-07-17 | 1957-09-25 | Basf Ag | Verfahren zur Herstellung neuer organischer Zinnverbindungen |
-
0
- BE BE581414D patent/BE581414A/xx unknown
-
1958
- 1958-08-07 GB GB25334/58A patent/GB855214A/en not_active Expired
-
1959
- 1959-08-01 DE DEP23295A patent/DE1176654B/de active Pending
- 1959-08-04 FR FR802033A patent/FR1232032A/fr not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB751499A (en) * | 1953-01-22 | 1956-06-27 | Metal & Thermit Corp | Hydrocarbon tin mixed salts of monocarboxylic aliphatic and maleic acids |
| AT191908B (de) * | 1954-07-17 | 1957-09-25 | Basf Ag | Verfahren zur Herstellung neuer organischer Zinnverbindungen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1232032A (fr) | 1960-10-05 |
| GB855214A (en) | 1960-11-30 |
| BE581414A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1900-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2540210B2 (de) | Verfahren zur Herstellung von Organozinntrihalogeniden und sich davon ableitende Organozinn-Stabilisatoren | |
| DE2607178B2 (de) | Verfahren zur Herstellung von Organozinndihalogeniden oder Gemischen aus Organozinndihalogeniden und Organozinntrihalogeniden | |
| DE1232146B (de) | Verfahren zur Herstellung von Metallsalzen der IV. und V. Hauptgruppe des Periodischen Systems von hoehermolekularen Carbonsaeuren | |
| DE1030824B (de) | Verfahren zur Herstellung von Epoxyester-Gemischen | |
| DE1279017B (de) | Verfahren zur Herstellung von Diorganostibinmercaptiden | |
| DE1227914B (de) | Verfahren zur Herstellung von 3-(1, 2-Dithia-cyclopentyl)-5-pentansaeure | |
| DE1643522B1 (de) | Verfahren zur Herstellung von 2-Arylimino-1,3-dithiacyclopentanen | |
| DE1176654B (de) | Verfahren zur Herstellung von Organo-zinnverbindungen | |
| DE946447C (de) | Verfahren zur Herstellung von Organozinnverbindungen | |
| DE681850C (de) | Verfahren zur Herstellung quaternaerer Stickstoffverbindungen | |
| DE941193C (de) | Verfahren zur Herstellung von neuen, bisquaternaeren Phosphoniumverbindungen | |
| DE1275067B (de) | Verfahren zur Herstellung von kristallinem Bis-[3-(1', 1', 3', 3'-tetramethylbutyl)-6-hydroxyphenyl]-monosulfid | |
| DE2055494A1 (de) | Verfahren zur Herstellung von Thiobisphenolen | |
| DE1276635B (de) | Verfahren zur Herstellung von Kaliumsorbat | |
| DE1768003C3 (de) | Verfahren zur Herstellung von neuartigen Chlorsulfenylphenylisocyaniddichloriden | |
| DE2605650A1 (de) | Verfahren zur herstellung von para-isobutyl-phenylessigsaeurederivaten | |
| AT214453B (de) | Verfahren zur Herstellung neuer organischer Zinnverbindungen | |
| DE1445659C (de) | Pyndylphosphorverbindungen und Verfahren zu ihrer Herstellung | |
| DE2360248C3 (de) | Verfahren zur Herstellung von Estern von Thiolcarbaminsäuren | |
| DE1168408B (de) | Verfahren zur Herstellung von ª‰-Methylmercaptopropionaldehyd | |
| DE2215710A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| AT242688B (de) | Verfahren zur Herstellung neuer Dinitro-alkylphenylbutyrate | |
| DE1668573C2 (de) | Verfahren zur Herstellung von Dialkylzinndihalogeniden Ausscheidung aus 1468494 | |
| DE1806707C3 (de) | Verfahren zur Herstellung von sekundären Phosphinoxyden | |
| DE559630C (de) | Verfahren zur Darstellung von neutralen, oelloeslichen Wismutsalzen fuer therapeutische Zwecke |