GB855214A - Organo-tin compounds containing sulphur and their application - Google Patents
Organo-tin compounds containing sulphur and their applicationInfo
- Publication number
- GB855214A GB855214A GB25334/58A GB2533458A GB855214A GB 855214 A GB855214 A GB 855214A GB 25334/58 A GB25334/58 A GB 25334/58A GB 2533458 A GB2533458 A GB 2533458A GB 855214 A GB855214 A GB 855214A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- acid
- thiocarboxylic
- tin
- unsaturated carboxylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 239000005864 Sulphur Substances 0.000 title 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 abstract 7
- 239000000203 mixture Substances 0.000 abstract 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 4
- 150000007513 acids Chemical class 0.000 abstract 3
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- IQBLWPLYPNOTJC-FPLPWBNLSA-N (z)-4-(2-ethylhexoxy)-4-oxobut-2-enoic acid Chemical compound CCCCC(CC)COC(=O)\C=C/C(O)=O IQBLWPLYPNOTJC-FPLPWBNLSA-N 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 2
- 239000011976 maleic acid Substances 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004608 Heat Stabiliser Substances 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- UIJGNTRUPZPVNG-UHFFFAOYSA-N benzenecarbothioic s-acid Chemical class SC(=O)C1=CC=CC=C1 UIJGNTRUPZPVNG-UHFFFAOYSA-N 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 abstract 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- -1 hydrocarbon tin oxide Chemical class 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 abstract 1
- 235000011150 stannous chloride Nutrition 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 229910001887 tin oxide Inorganic materials 0.000 abstract 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Polyvinyl chloride compositions, vinyl chloridevinylidene chloride and vinyl chloride-vinyl acetate copolymer compositions are stabilized against heat deterioration by addition of a dialkyl, diaralkyl, diaryl or dialkaryl tin salt of a thiocarboxylic acid or of a mixture of thiocarboxylic acid and an a , b -unsaturated carboxylic acid, The specified acids are thioacetic, thiobenzoic, and mono-esters of maleic acid e.g. mono-octyl maleate. Plasticizers (dioctyl phthalate) and lubricants (stearic acid, 'Ferrolube') may also be present.ALSO:The invention comprises dialkyl, diaralkyl, diaryl or dialkaryl tin salts of thiocarboxylic acids and dialkyl, diaralkyl, diaryl or dialkaryl tin mixed salts of thiocarboxylic acids and a , b -unsaturated carboxylic acids. Preferably the hydrocarbon groups attached to the tin atom have from two to eight carbon atoms. The thiocarboxylic acids are the thiono-and thiolocarboxylic acids, thioacetic and thiobenzoic acids being specified. Mono-esters of maleic acid, especially mono-octyl maleate, are the preferred a , b -unsaturated carboxylic acid. The salts of the invention may be prepared by reacting a hydrocarbon tin oxide with a thiocarboxylic acid with or without a a , b -unsaturated carboxylic acid at a temperature between 100 DEG and 120 DEG C., or by reacting a dihydrocarbon tin dichloride with the sodium potassium or ammonium salts of the thiocarboxylic acid and if desired of the a , b -unsaturated carboxylic acid. In the case of the mixed acids, the weight of unsaturated acid can vary between the limits 10-90%. The prepared salts may be used as heat stabilisers in polyvinyl chloride compositions, vinyl chloride-vinylidene chloride compositions and vinyl chloride-vinyl acetate compositions.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE581414D BE581414A (en) | 1958-08-07 | ||
| GB25334/58A GB855214A (en) | 1958-08-07 | 1958-08-07 | Organo-tin compounds containing sulphur and their application |
| DEP23295A DE1176654B (en) | 1958-08-07 | 1959-08-01 | Process for the production of organotin compounds |
| FR802033A FR1232032A (en) | 1958-08-07 | 1959-08-04 | Manufacturing process of organic tin compounds containing sulfur and their applications |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB25334/58A GB855214A (en) | 1958-08-07 | 1958-08-07 | Organo-tin compounds containing sulphur and their application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB855214A true GB855214A (en) | 1960-11-30 |
Family
ID=10225998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB25334/58A Expired GB855214A (en) | 1958-08-07 | 1958-08-07 | Organo-tin compounds containing sulphur and their application |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE581414A (en) |
| DE (1) | DE1176654B (en) |
| FR (1) | FR1232032A (en) |
| GB (1) | GB855214A (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL88419C (en) * | 1953-01-22 | 1900-01-01 | ||
| AT191908B (en) * | 1954-07-17 | 1957-09-25 | Basf Ag | Process for the production of new organic tin compounds |
-
0
- BE BE581414D patent/BE581414A/xx unknown
-
1958
- 1958-08-07 GB GB25334/58A patent/GB855214A/en not_active Expired
-
1959
- 1959-08-01 DE DEP23295A patent/DE1176654B/en active Pending
- 1959-08-04 FR FR802033A patent/FR1232032A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1232032A (en) | 1960-10-05 |
| DE1176654B (en) | 1964-08-27 |
| BE581414A (en) | 1900-01-01 |
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