DE1160830B - Verfahren zur Herstellung von Lithium- bzw. Erdalkalihydriden durch Umsetzung von aus Natrium- und/oder Kalium- und Lithium- bzw. Erdalkalihalogeniden bestehenden Gemischen mit Wasserstoff - Google Patents
Verfahren zur Herstellung von Lithium- bzw. Erdalkalihydriden durch Umsetzung von aus Natrium- und/oder Kalium- und Lithium- bzw. Erdalkalihalogeniden bestehenden Gemischen mit WasserstoffInfo
- Publication number
- DE1160830B DE1160830B DED34335A DED0034335A DE1160830B DE 1160830 B DE1160830 B DE 1160830B DE D34335 A DED34335 A DE D34335A DE D0034335 A DED0034335 A DE D0034335A DE 1160830 B DE1160830 B DE 1160830B
- Authority
- DE
- Germany
- Prior art keywords
- alkaline earth
- lithium
- sodium
- hydrogen
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 18
- 239000001257 hydrogen Substances 0.000 title claims description 18
- 239000011734 sodium Substances 0.000 title claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 13
- 239000000203 mixture Substances 0.000 title claims description 13
- 229910052708 sodium Inorganic materials 0.000 title claims description 12
- 229910052744 lithium Inorganic materials 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title claims description 8
- 229910052700 potassium Inorganic materials 0.000 title claims description 8
- 239000011591 potassium Substances 0.000 title claims description 8
- 229910000095 alkaline earth hydride Inorganic materials 0.000 title claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title description 9
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 title description 2
- 150000004820 halides Chemical class 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- -1 lithium halides Chemical class 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 150000004694 iodide salts Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 150000001649 bromium compounds Chemical class 0.000 claims 1
- 150000001805 chlorine compounds Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 17
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- 150000001340 alkali metals Chemical class 0.000 description 7
- 150000004678 hydrides Chemical class 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- 229910000103 lithium hydride Inorganic materials 0.000 description 5
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 150000003841 chloride salts Chemical class 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 150000003842 bromide salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000001912 cyanamides Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000004707 phenolate Chemical class 0.000 description 1
- NTTOTNSKUYCDAV-UHFFFAOYSA-N potassium hydride Chemical compound [KH] NTTOTNSKUYCDAV-UHFFFAOYSA-N 0.000 description 1
- 229910000105 potassium hydride Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- KRIJWFBRWPCESA-UHFFFAOYSA-L strontium iodide Chemical compound [Sr+2].[I-].[I-] KRIJWFBRWPCESA-UHFFFAOYSA-L 0.000 description 1
- 229910001643 strontium iodide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/04—Hydrides of alkali metals, alkaline earth metals, beryllium or magnesium; Addition complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL268836D NL268836A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1960-09-23 | ||
| DED34335A DE1160830B (de) | 1960-09-23 | 1960-09-23 | Verfahren zur Herstellung von Lithium- bzw. Erdalkalihydriden durch Umsetzung von aus Natrium- und/oder Kalium- und Lithium- bzw. Erdalkalihalogeniden bestehenden Gemischen mit Wasserstoff |
| CH975961A CH414574A (de) | 1960-09-23 | 1961-08-21 | Verfahren zur Herstellung der Hydride der Erdalkalimetalle oder des Lithiums |
| US137984A US3366453A (en) | 1960-09-23 | 1961-09-14 | Production of hydrides of alkaline earth metals and lithium |
| GB33504/61A GB949490A (en) | 1960-09-23 | 1961-09-19 | Process for the production of the hydrides of the alkaline earth metals and of lithium |
| BE608411A BE608411A (fr) | 1960-09-23 | 1961-09-21 | Procédé pour la préparation de hydrures des métaux alcalino-terreux et du lithium |
| FR874016A FR1327020A (fr) | 1960-09-23 | 1961-09-23 | Procédé de préparation d'hydrures de métaux alcalino-terreux et de lithium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED34335A DE1160830B (de) | 1960-09-23 | 1960-09-23 | Verfahren zur Herstellung von Lithium- bzw. Erdalkalihydriden durch Umsetzung von aus Natrium- und/oder Kalium- und Lithium- bzw. Erdalkalihalogeniden bestehenden Gemischen mit Wasserstoff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1160830B true DE1160830B (de) | 1964-01-09 |
Family
ID=7042139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED34335A Pending DE1160830B (de) | 1960-09-23 | 1960-09-23 | Verfahren zur Herstellung von Lithium- bzw. Erdalkalihydriden durch Umsetzung von aus Natrium- und/oder Kalium- und Lithium- bzw. Erdalkalihalogeniden bestehenden Gemischen mit Wasserstoff |
Country Status (6)
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3728434A (en) * | 1968-02-06 | 1973-04-17 | Ethyl Corp | Treatment of metal hydrides |
| DE3536797A1 (de) * | 1985-10-16 | 1987-04-16 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung von halogen-magnesium-alanat und dessen verwendung |
| US6593017B1 (en) * | 2002-01-30 | 2003-07-15 | Energy Conversion Devices, Inc. | High capacity calcium lithium based hydrogen storage material and method of making the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1796265A (en) * | 1926-08-23 | 1931-03-10 | Degussa | Process of manufacture of alkali-metal hydrides |
| US2408748A (en) * | 1944-09-30 | 1946-10-08 | Metal Hydrides Inc | Production of lithium hydride |
| US2702740A (en) * | 1953-10-02 | 1955-02-22 | Metal Hydrides Inc | Method for preparing calcium hydride |
| US2794732A (en) * | 1954-05-03 | 1957-06-04 | Metal Hydrides Inc | Method for preparing calcium |
| US2794733A (en) * | 1954-05-03 | 1957-06-04 | Metal Hydrides Inc | Method for preparing calcium |
| US2864671A (en) * | 1954-06-30 | 1958-12-16 | Standard Oil Co | Process of hydrogen recovery |
| US3130011A (en) * | 1958-09-17 | 1964-04-21 | British Titan Products | Production of silicon halides |
-
0
- NL NL268836D patent/NL268836A/xx unknown
-
1960
- 1960-09-23 DE DED34335A patent/DE1160830B/de active Pending
-
1961
- 1961-08-21 CH CH975961A patent/CH414574A/de unknown
- 1961-09-14 US US137984A patent/US3366453A/en not_active Expired - Lifetime
- 1961-09-19 GB GB33504/61A patent/GB949490A/en not_active Expired
- 1961-09-21 BE BE608411A patent/BE608411A/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US3366453A (en) | 1968-01-30 |
| GB949490A (en) | 1964-02-12 |
| CH414574A (de) | 1966-06-15 |
| NL268836A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| BE608411A (fr) | 1962-03-21 |
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