DE112014007334B3 - Sauerstoffpräzipitation in stark dotierten Siliciumwafern, geschnitten aus nach dem Czochralski-Verfahren gezüchteten Ingots - Google Patents
Sauerstoffpräzipitation in stark dotierten Siliciumwafern, geschnitten aus nach dem Czochralski-Verfahren gezüchteten Ingots Download PDFInfo
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- DE112014007334B3 DE112014007334B3 DE112014007334.2T DE112014007334T DE112014007334B3 DE 112014007334 B3 DE112014007334 B3 DE 112014007334B3 DE 112014007334 T DE112014007334 T DE 112014007334T DE 112014007334 B3 DE112014007334 B3 DE 112014007334B3
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- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 84
- 239000001301 oxygen Substances 0.000 title claims abstract description 84
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 238000001556 precipitation Methods 0.000 title claims abstract description 35
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims description 76
- 229910052710 silicon Inorganic materials 0.000 title claims description 76
- 239000010703 silicon Substances 0.000 title claims description 76
- 235000012431 wafers Nutrition 0.000 title description 131
- 239000002244 precipitate Substances 0.000 claims abstract description 64
- 238000000034 method Methods 0.000 claims abstract description 56
- 239000002019 doping agent Substances 0.000 claims abstract description 49
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims abstract description 45
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 37
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 37
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 35
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 34
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052796 boron Inorganic materials 0.000 claims abstract description 29
- 238000010438 heat treatment Methods 0.000 claims abstract description 18
- 230000002093 peripheral effect Effects 0.000 claims abstract description 18
- 239000013078 crystal Substances 0.000 claims description 67
- 239000012212 insulator Substances 0.000 claims description 14
- 239000010410 layer Substances 0.000 description 39
- 238000000151 deposition Methods 0.000 description 22
- 230000008021 deposition Effects 0.000 description 21
- 239000012535 impurity Substances 0.000 description 19
- 229910052799 carbon Inorganic materials 0.000 description 15
- 230000007547 defect Effects 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 230000008569 process Effects 0.000 description 11
- 150000004767 nitrides Chemical class 0.000 description 10
- 239000000155 melt Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 6
- 229910052814 silicon oxide Inorganic materials 0.000 description 6
- 238000005204 segregation Methods 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- VJTAZCKMHINUKO-UHFFFAOYSA-M chloro(2-methoxyethyl)mercury Chemical compound [Cl-].COCC[Hg+] VJTAZCKMHINUKO-UHFFFAOYSA-M 0.000 description 4
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 4
- 239000012776 electronic material Substances 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
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- TXUWMXQFNYDOEZ-UHFFFAOYSA-N 5-(1H-indol-3-ylmethyl)-3-methyl-2-sulfanylidene-4-imidazolidinone Chemical compound O=C1N(C)C(=S)NC1CC1=CNC2=CC=CC=C12 TXUWMXQFNYDOEZ-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 101001128694 Homo sapiens Neuroendocrine convertase 1 Proteins 0.000 description 2
- 102100032132 Neuroendocrine convertase 1 Human genes 0.000 description 2
- 101000973669 Petunia hybrida Bidirectional sugar transporter NEC1 Proteins 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- -1 oxygen fiber-saturated silicon Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 241000252203 Clupea harengus Species 0.000 description 1
- 238000002231 Czochralski process Methods 0.000 description 1
- 101100346656 Drosophila melanogaster strat gene Proteins 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- PPWPWBNSKBDSPK-UHFFFAOYSA-N [B].[C] Chemical compound [B].[C] PPWPWBNSKBDSPK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
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- 235000013351 cheese Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
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- 238000002109 crystal growth method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
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- 238000005247 gettering Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000019514 herring Nutrition 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
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- 239000002210 silicon-based material Substances 0.000 description 1
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- 238000010998 test method Methods 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/322—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to modify their internal properties, e.g. to produce internal imperfections
- H01L21/3221—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to modify their internal properties, e.g. to produce internal imperfections of silicon bodies, e.g. for gettering
- H01L21/3225—Thermally inducing defects using oxygen present in the silicon body for intrinsic gettering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02002—Preparing wafers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02656—Special treatments
- H01L21/02664—Aftertreatments
- H01L21/02694—Controlling the interface between substrate and epitaxial layer, e.g. by ion implantation followed by annealing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/22—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
- H01L21/223—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/60—Impurity distributions or concentrations
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/914,925 US9634098B2 (en) | 2013-06-11 | 2013-06-11 | Oxygen precipitation in heavily doped silicon wafers sliced from ingots grown by the Czochralski method |
| US13/914,925 | 2013-06-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE112014007334B3 true DE112014007334B3 (de) | 2023-08-24 |
Family
ID=50983191
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE112014007334.2T Active DE112014007334B3 (de) | 2013-06-11 | 2014-05-23 | Sauerstoffpräzipitation in stark dotierten Siliciumwafern, geschnitten aus nach dem Czochralski-Verfahren gezüchteten Ingots |
| DE112014002781.2T Active DE112014002781B9 (de) | 2013-06-11 | 2014-05-23 | Verfahren zur Kontrolle der Sauerstoffpräzipitation in stark dotierten Siliciumwafern, geschnitten aus nach dem Czochralski-Verfahren gezüchteten Ingots, und Silicumwafer |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE112014002781.2T Active DE112014002781B9 (de) | 2013-06-11 | 2014-05-23 | Verfahren zur Kontrolle der Sauerstoffpräzipitation in stark dotierten Siliciumwafern, geschnitten aus nach dem Czochralski-Verfahren gezüchteten Ingots, und Silicumwafer |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9634098B2 (enExample) |
| JP (1) | JP6289621B2 (enExample) |
| KR (3) | KR102071304B1 (enExample) |
| DE (2) | DE112014007334B3 (enExample) |
| WO (1) | WO2014200686A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9945048B2 (en) * | 2012-06-15 | 2018-04-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor structure and method |
| US20150243494A1 (en) * | 2014-02-25 | 2015-08-27 | Texas Instruments Incorporated | Mechanically robust silicon substrate having group iiia-n epitaxial layer thereon |
| KR101680213B1 (ko) * | 2015-04-06 | 2016-11-28 | 주식회사 엘지실트론 | 실리콘 단결정 잉곳의 성장 방법 |
| KR101759876B1 (ko) * | 2015-07-01 | 2017-07-31 | 주식회사 엘지실트론 | 웨이퍼 및 웨이퍼 결함 분석 방법 |
| JP6610056B2 (ja) * | 2015-07-28 | 2019-11-27 | 株式会社Sumco | エピタキシャルシリコンウェーハの製造方法 |
| KR101674819B1 (ko) * | 2015-08-12 | 2016-11-09 | 주식회사 엘지실트론 | 단결정 성장 방법 |
| JP6447439B2 (ja) * | 2015-09-28 | 2019-01-09 | 信越半導体株式会社 | 貼り合わせsoiウェーハの製造方法 |
| WO2017058928A1 (en) | 2015-10-01 | 2017-04-06 | Sunedison Semiconductor Limited | Epitaxial growth of defect-free, wafer-scale single-layer graphene on thin films of cobalt |
| JP6579046B2 (ja) * | 2016-06-17 | 2019-09-25 | 株式会社Sumco | シリコン単結晶の製造方法 |
| EP3653761B1 (en) * | 2016-12-28 | 2024-02-28 | Sunedison Semiconductor Limited | Silicon wafers with intrinsic gettering and gate oxide integrity yield |
| JP7306536B1 (ja) | 2022-06-14 | 2023-07-11 | 信越半導体株式会社 | エピタキシャルウェーハの製造方法 |
| CN118507557A (zh) * | 2023-09-27 | 2024-08-16 | 隆基绿能科技股份有限公司 | 一种混合掺杂的硅片 |
Citations (3)
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|---|---|---|---|---|
| US20080038526A1 (en) | 2004-07-22 | 2008-02-14 | Shin-Etsu Handotai Co., Ltd. | Silicon Epitaxial Wafer And Manufacturing Method Thereof |
| US20090017291A1 (en) | 2004-08-31 | 2009-01-15 | Shinsuke Sadamitsu | Silicon epitaxial wafer and production method for same |
| US20130102129A1 (en) | 2011-06-03 | 2013-04-25 | Memc Singapore Pte. Ltd. (Uen200614794D) | Processes for suppressing minority carrier lifetime degradation in silicon wafers |
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| JP2726583B2 (ja) * | 1991-11-18 | 1998-03-11 | 三菱マテリアルシリコン株式会社 | 半導体基板 |
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| JP2010283295A (ja) * | 2009-06-08 | 2010-12-16 | Sumco Corp | 半導体デバイスの製造方法及びシリコンウェーハの処理装置 |
| JP2011253978A (ja) | 2010-06-03 | 2011-12-15 | Sumco Corp | エピタキシャル基板およびその製造方法 |
| JP5572569B2 (ja) * | 2011-02-24 | 2014-08-13 | 信越半導体株式会社 | シリコン基板の製造方法及びシリコン基板 |
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2013
- 2013-06-11 US US13/914,925 patent/US9634098B2/en active Active
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- 2014-05-23 DE DE112014007334.2T patent/DE112014007334B3/de active Active
- 2014-05-23 KR KR1020167000402A patent/KR102071304B1/ko active Active
- 2014-05-23 KR KR1020207011376A patent/KR102172905B1/ko active Active
- 2014-05-23 KR KR1020207002039A patent/KR102172904B1/ko active Active
- 2014-05-23 WO PCT/US2014/039363 patent/WO2014200686A1/en not_active Ceased
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080038526A1 (en) | 2004-07-22 | 2008-02-14 | Shin-Etsu Handotai Co., Ltd. | Silicon Epitaxial Wafer And Manufacturing Method Thereof |
| US20090017291A1 (en) | 2004-08-31 | 2009-01-15 | Shinsuke Sadamitsu | Silicon epitaxial wafer and production method for same |
| US20130102129A1 (en) | 2011-06-03 | 2013-04-25 | Memc Singapore Pte. Ltd. (Uen200614794D) | Processes for suppressing minority carrier lifetime degradation in silicon wafers |
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| LI, C. [et al.]: Effect of Rapid Thermal Process on Oxygen. In: Japanese Journal of Applied Physics, Vol. 42, 2003, S. 7290 - 7291. |
| SHIMIZU, Y. [et al.]: Impact of carbon coimplantation on boron behavior in silicon: Carbon-boron coclustering and suppression of boron diffusion. In: Appl. Phys. Lett., Vol. 98, 2011, Seiten 232101-1 – 232101-3. |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2016526783A (ja) | 2016-09-05 |
| DE112014002781T5 (de) | 2016-03-10 |
| KR20200044152A (ko) | 2020-04-28 |
| KR102172905B1 (ko) | 2020-11-03 |
| KR102071304B1 (ko) | 2020-01-31 |
| US9634098B2 (en) | 2017-04-25 |
| WO2014200686A1 (en) | 2014-12-18 |
| US20140361408A1 (en) | 2014-12-11 |
| DE112014002781B9 (de) | 2021-07-29 |
| KR20160019495A (ko) | 2016-02-19 |
| DE112014002781B4 (de) | 2020-06-18 |
| KR20200011563A (ko) | 2020-02-03 |
| KR102172904B1 (ko) | 2020-11-03 |
| JP6289621B2 (ja) | 2018-03-07 |
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