DE1094239B - Verfahren zum gleichzeitigen Entfernen von Kationen und schwer loesliche Silberverbindungen bildenden Anionen aus Fluessigkeiten - Google Patents
Verfahren zum gleichzeitigen Entfernen von Kationen und schwer loesliche Silberverbindungen bildenden Anionen aus FluessigkeitenInfo
- Publication number
- DE1094239B DE1094239B DEF24874A DEF0024874A DE1094239B DE 1094239 B DE1094239 B DE 1094239B DE F24874 A DEF24874 A DE F24874A DE F0024874 A DEF0024874 A DE F0024874A DE 1094239 B DE1094239 B DE 1094239B
- Authority
- DE
- Germany
- Prior art keywords
- liquids
- anions
- cations
- exchange
- sparingly soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims description 5
- 150000001450 anions Chemical class 0.000 title claims description 4
- 150000001768 cations Chemical class 0.000 title claims description 4
- 229940100890 silver compound Drugs 0.000 title claims description 4
- 150000003379 silver compounds Chemical class 0.000 title claims description 4
- 238000000034 method Methods 0.000 title description 2
- 239000010457 zeolite Substances 0.000 claims description 20
- 239000013535 sea water Substances 0.000 claims description 8
- JEWHCPOELGJVCB-UHFFFAOYSA-N aluminum;calcium;oxido-[oxido(oxo)silyl]oxy-oxosilane;potassium;sodium;tridecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.[Na].[Al].[K].[Ca].[O-][Si](=O)O[Si]([O-])=O JEWHCPOELGJVCB-UHFFFAOYSA-N 0.000 claims description 4
- 229910001743 phillipsite Inorganic materials 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 14
- 229910021536 Zeolite Inorganic materials 0.000 description 13
- 239000011734 sodium Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 12
- 238000010612 desalination reaction Methods 0.000 description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000002808 molecular sieve Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000017 hydrogel Substances 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 229910052908 analcime Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000000967 suction filtration Methods 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 238000004438 BET method Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B5/00—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/02—Processes using inorganic exchangers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE574857D BE574857A (en, 2012) | 1958-01-23 | ||
| DEF24874A DE1094239B (de) | 1958-01-23 | 1958-01-23 | Verfahren zum gleichzeitigen Entfernen von Kationen und schwer loesliche Silberverbindungen bildenden Anionen aus Fluessigkeiten |
| CH6712158A CH378855A (de) | 1958-01-23 | 1958-12-09 | Verwendung der Ag-Austauschprodukte von kristallinen Zeolithen als Entsalzer |
| GB169759A GB898458A (en) | 1958-01-23 | 1959-01-16 | A process for removing cations and anions from an aqueous solution |
| FR1214531D FR1214531A (fr) | 1958-01-23 | 1959-01-20 | Application comme agents de dessalage des produits d'échange d'argent de zéolites cristallines du type |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF24874A DE1094239B (de) | 1958-01-23 | 1958-01-23 | Verfahren zum gleichzeitigen Entfernen von Kationen und schwer loesliche Silberverbindungen bildenden Anionen aus Fluessigkeiten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1094239B true DE1094239B (de) | 1960-12-08 |
Family
ID=7091398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF24874A Pending DE1094239B (de) | 1958-01-23 | 1958-01-23 | Verfahren zum gleichzeitigen Entfernen von Kationen und schwer loesliche Silberverbindungen bildenden Anionen aus Fluessigkeiten |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE574857A (en, 2012) |
| CH (1) | CH378855A (en, 2012) |
| DE (1) | DE1094239B (en, 2012) |
| FR (1) | FR1214531A (en, 2012) |
| GB (1) | GB898458A (en, 2012) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1117776A (fr) * | 1953-12-24 | 1956-05-28 | Union Carbide & Carbon Corp | Procédé de fabrication de matières adsorbantes synthétiques |
| GB781726A (en) * | 1954-06-21 | 1957-08-21 | Atomic Energy Authority Uk | Improvements in or relating to process for removal of cations from aqueous solution |
-
0
- BE BE574857D patent/BE574857A/xx unknown
-
1958
- 1958-01-23 DE DEF24874A patent/DE1094239B/de active Pending
- 1958-12-09 CH CH6712158A patent/CH378855A/de unknown
-
1959
- 1959-01-16 GB GB169759A patent/GB898458A/en not_active Expired
- 1959-01-20 FR FR1214531D patent/FR1214531A/fr not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1117776A (fr) * | 1953-12-24 | 1956-05-28 | Union Carbide & Carbon Corp | Procédé de fabrication de matières adsorbantes synthétiques |
| GB781726A (en) * | 1954-06-21 | 1957-08-21 | Atomic Energy Authority Uk | Improvements in or relating to process for removal of cations from aqueous solution |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1214531A (fr) | 1960-04-08 |
| BE574857A (en, 2012) | |
| GB898458A (en) | 1962-06-06 |
| CH378855A (de) | 1964-06-30 |
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