DE1076485B - Verfahren zur Entfernung der Kieselsaeure aus silikatreichen, alkalischen Zellstoffablaugen, insbesondere im kontinuierlichen Betrieb - Google Patents
Verfahren zur Entfernung der Kieselsaeure aus silikatreichen, alkalischen Zellstoffablaugen, insbesondere im kontinuierlichen BetriebInfo
- Publication number
- DE1076485B DE1076485B DEI14333A DEI0014333A DE1076485B DE 1076485 B DE1076485 B DE 1076485B DE I14333 A DEI14333 A DE I14333A DE I0014333 A DEI0014333 A DE I0014333A DE 1076485 B DE1076485 B DE 1076485B
- Authority
- DE
- Germany
- Prior art keywords
- silica
- silicate
- sio
- magnesium compounds
- waste liquors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 65
- 239000000377 silicon dioxide Substances 0.000 title claims description 33
- 238000000034 method Methods 0.000 title claims description 24
- 239000002699 waste material Substances 0.000 title claims description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims description 6
- 239000001913 cellulose Substances 0.000 title description 2
- 229920002678 cellulose Polymers 0.000 title description 2
- 239000010802 sludge Substances 0.000 claims description 11
- 150000002681 magnesium compounds Chemical class 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 230000015271 coagulation Effects 0.000 claims 1
- 238000005345 coagulation Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 39
- 229910004298 SiO 2 Inorganic materials 0.000 description 21
- 239000011777 magnesium Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- 238000007792 addition Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 238000004062 sedimentation Methods 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 159000000003 magnesium salts Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000013049 sediment Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 235000014676 Phragmites communis Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- -1 Ca SO 4 Chemical class 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000273256 Phragmites communis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000009993 causticizing Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 210000002023 somite Anatomy 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/04—Regeneration of pulp liquors or effluent waste waters of alkali lye
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/0085—Introduction of auxiliary substances into the regenerating system in order to improve the performance of certain steps of the latter, the presence of these substances being confined to the regeneration cycle
Landscapes
- Silicon Compounds (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL232042D NL232042A (enrdf_load_stackoverflow) | 1958-01-29 | ||
| DEI14333A DE1076485B (de) | 1958-01-29 | 1958-01-29 | Verfahren zur Entfernung der Kieselsaeure aus silikatreichen, alkalischen Zellstoffablaugen, insbesondere im kontinuierlichen Betrieb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI14333A DE1076485B (de) | 1958-01-29 | 1958-01-29 | Verfahren zur Entfernung der Kieselsaeure aus silikatreichen, alkalischen Zellstoffablaugen, insbesondere im kontinuierlichen Betrieb |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1076485B true DE1076485B (de) | 1960-02-25 |
Family
ID=7185630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI14333A Pending DE1076485B (de) | 1958-01-29 | 1958-01-29 | Verfahren zur Entfernung der Kieselsaeure aus silikatreichen, alkalischen Zellstoffablaugen, insbesondere im kontinuierlichen Betrieb |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1076485B (enrdf_load_stackoverflow) |
| NL (1) | NL232042A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0165945A4 (en) * | 1983-12-23 | 1986-07-17 | North Broken Hill Ltd | METHOD FOR IMPROVING THE PURITY OF ALKALINE METAL HYDROXYDES. |
| EP4153811A4 (en) * | 2020-05-22 | 2024-06-19 | Suzano S.A. | METHOD OF TREATING A POWER PROCESS RECOVERY PARTICLE TO REDUCE THE METAL LEVEL IN THE POWER PROCESS |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB381697A (en) * | 1931-09-19 | 1932-10-13 | Erik Ludvig Rinman | Method of relieving alkaline waste liquors from the soda or sulphate pulp manufacture, of silica |
| FR1029169A (fr) * | 1950-12-06 | 1953-06-01 | Perfectionnements à la régénération des liqueurs résiduaires de papeteries | |
| FR1064230A (fr) * | 1951-10-09 | 1954-05-12 | Columbia Southern Chem Corp | Perfectionnements aux procédés pour la préparation de silice pagmentaire finementdivisée |
-
0
- NL NL232042D patent/NL232042A/xx unknown
-
1958
- 1958-01-29 DE DEI14333A patent/DE1076485B/de active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB381697A (en) * | 1931-09-19 | 1932-10-13 | Erik Ludvig Rinman | Method of relieving alkaline waste liquors from the soda or sulphate pulp manufacture, of silica |
| GB393962A (en) * | 1931-09-19 | 1933-06-12 | Erik Ludvig Rinman | Method of relieving waste liquors from the soda or sulphate pulp manufacture of silica |
| FR1029169A (fr) * | 1950-12-06 | 1953-06-01 | Perfectionnements à la régénération des liqueurs résiduaires de papeteries | |
| FR1064230A (fr) * | 1951-10-09 | 1954-05-12 | Columbia Southern Chem Corp | Perfectionnements aux procédés pour la préparation de silice pagmentaire finementdivisée |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0165945A4 (en) * | 1983-12-23 | 1986-07-17 | North Broken Hill Ltd | METHOD FOR IMPROVING THE PURITY OF ALKALINE METAL HYDROXYDES. |
| EP4153811A4 (en) * | 2020-05-22 | 2024-06-19 | Suzano S.A. | METHOD OF TREATING A POWER PROCESS RECOVERY PARTICLE TO REDUCE THE METAL LEVEL IN THE POWER PROCESS |
Also Published As
| Publication number | Publication date |
|---|---|
| NL232042A (enrdf_load_stackoverflow) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2518431C3 (de) | Verfarhen zur Entfernung der schädlichen organischen Verbindungen aus der bei der Tonerdegewinnung nach dem Bayer-Verfarhen anfallenden Aluminatlauge | |
| DE1592126A1 (de) | Verfahren zur Herstellung von Hydrotalkit | |
| DE948212C (de) | Verfahren zur Gewinnung von Lignin und Ligninverbindungen bei der Aufarbeitung von Schwarzlauge | |
| DE2918520C2 (enrdf_load_stackoverflow) | ||
| DE2647259B2 (de) | Verfahren zum Entfernen von Verunreinigungen aus einer nach dem Bayer-Verfahren gewonnenen alkalischen Natriumaluminatlösung | |
| DE3040773A1 (de) | Verfahren zur verminderung der konzentration der orgnischen stoffe im kreislauf der tonerdeherstellung nach dem bayer-verfahren | |
| DE1076485B (de) | Verfahren zur Entfernung der Kieselsaeure aus silikatreichen, alkalischen Zellstoffablaugen, insbesondere im kontinuierlichen Betrieb | |
| DE1592159B2 (de) | Verfahren zum klaeren von technischen natriumaluminatloesungen aus dem alkalischen aufschluss von bauxiten | |
| DE1911141C3 (de) | Verfahren zur Extraktion des Berylliumgehalts aus Erzen | |
| DE599986C (de) | Verfahren zur Reinigung von Beizereiablaugen | |
| DE957650C (de) | Verfahren zur Behandlung von Zuckersäften | |
| DE3620221C2 (enrdf_load_stackoverflow) | ||
| DE2360112C3 (de) | Gewinnung von Tonerde und Kaliumsulfat aus Alunit | |
| DE972230C (de) | Verfahren zur Saftreinigung in der Zuckerindustrie mittels Kalkzusatz und Saturation | |
| DE2152283B2 (de) | Verfahren zur gewinnung von kieselsaeure, silikaten und/oder entsprechenden organischen komplexen aus bei der zellstoffherstellung anfallender schwarzlauge und verwendung der so erhaltenen produkte als pigment | |
| AT232930B (de) | Verfahren zur Aufarbeitung von Alkalisulfat enthaltenden Lösungen, vornehmlich Abwässern der viskoseverarbeitenden Industrie | |
| AT141143B (de) | Verfahren zur Abscheidung der Nichtzuckerstoffe aus Zuckerfabriks- und Raffineriesäften durch Ausflockung. | |
| DE1592159C3 (de) | Verfahren zum Klären von technischen Natriumaluminatlösungen aus dem alkalischen Aufschluß von Bauxiten | |
| AT86032B (de) | Verfahren zur Herstellung von basenaustauschenden Stoffen, sogenannten Metallatsilikaten. | |
| AT147010B (de) | Verfahren zur Gewinnung von Aluminiumverbindungen aus schwer aufschließbaren Tonerdemineralien (Tonen, Kaolinen und ähnlichen). | |
| DE95447C (enrdf_load_stackoverflow) | ||
| DE866452C (de) | Verfahren zur Gewinnung von faserstoffhaltigem Material fuer die Papierfabrikation aus Torf | |
| DE1215118B (de) | Verfahren zur Herstellung von gut filtrierbarem, reinem Magnesiumhydroxyd hohen Feststoffgehaltes | |
| AT333933B (de) | Verfahren zur aufarbeitung und verbesserung der filtrierbarkeit von in neutralisierten, zinkoxidhydrat enthaltenden abgangsbadern aus der herstellung von kunstfasern aus viskose vorliegenden feststoffen | |
| DE1517476A1 (de) | Verfahren zum Neutralisieren von saeurehaltigem Wasser |