DE105567C - - Google Patents

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Publication number

DE105567C

DE105567C DENDAT105567D DE105567DA DE105567C DE 105567 C DE105567 C DE 105567C DE NDAT105567 D DENDAT105567 D DE NDAT105567D DE 105567D A DE105567D A DE 105567DA DE 105567 C DE105567 C DE 105567C

Authority

DE

Germany

Prior art keywords

acid

hexaoxyanthraquinone

solution

disulfonic acid

sulfuric acid

Prior art date

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• 239000013067 intermediate product Substances 0.000 claims description 18
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
• KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 8
• 239000004327 boric acid Substances 0.000 claims description 8
• 239000000155 melt Substances 0.000 claims description 8
• NMNSBFYYVHREEE-UHFFFAOYSA-N 1,2-dinitroanthracene-9,10-dione Chemical class C1=CC=C2C(=O)C3=C([N+]([O-])=O)C([N+](=O)[O-])=CC=C3C(=O)C2=C1 NMNSBFYYVHREEE-UHFFFAOYSA-N 0.000 claims description 6
• HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 claims description 6
• 150000008064 anhydrides Chemical class 0.000 claims description 5
• 238000010438 heat treatment Methods 0.000 claims description 4
• 238000000034 method Methods 0.000 claims description 4
• 239000003638 chemical reducing agent Substances 0.000 claims description 3
• 230000008569 process Effects 0.000 claims description 3
• 230000009466 transformation Effects 0.000 claims description 3
• 238000002955 isolation Methods 0.000 claims description 2
• 239000012266 salt solution Substances 0.000 claims description 2
• 238000000844 transformation Methods 0.000 claims 1
• 239000002253 acid Substances 0.000 description 29
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 19
• 239000000243 solution Substances 0.000 description 15
• 238000006243 chemical reaction Methods 0.000 description 6
• 239000000126 substance Substances 0.000 description 4
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
• LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
• 230000009467 reduction Effects 0.000 description 3
• 239000011593 sulfur Substances 0.000 description 3
• 229910052717 sulfur Inorganic materials 0.000 description 3
• 230000007704 transition Effects 0.000 description 3
• XVMVHWDCRFNPQR-UHFFFAOYSA-N 1,5-dinitroanthracene-9,10-dione Chemical compound O=C1C=2C([N+](=O)[O-])=CC=CC=2C(=O)C2=C1C=CC=C2[N+]([O-])=O XVMVHWDCRFNPQR-UHFFFAOYSA-N 0.000 description 2
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
• WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
• 150000007513 acids Chemical class 0.000 description 2
• 239000000975 dye Substances 0.000 description 2
• 238000009413 insulation Methods 0.000 description 2
• NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
• 239000000047 product Substances 0.000 description 2
• 238000005185 salting out Methods 0.000 description 2
• ORFSSYGWXNGVFB-UHFFFAOYSA-N sodium 4-amino-6-[[4-[4-[(8-amino-1-hydroxy-5,7-disulfonaphthalen-2-yl)diazenyl]-3-methoxyphenyl]-2-methoxyphenyl]diazenyl]-5-hydroxynaphthalene-1,3-disulfonic acid Chemical compound COC1=C(C=CC(=C1)C2=CC(=C(C=C2)N=NC3=C(C4=C(C=C3)C(=CC(=C4N)S(=O)(=O)O)S(=O)(=O)O)O)OC)N=NC5=C(C6=C(C=C5)C(=CC(=C6N)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] ORFSSYGWXNGVFB-UHFFFAOYSA-N 0.000 description 2
• 235000002639 sodium chloride Nutrition 0.000 description 2
• 239000011780 sodium chloride Substances 0.000 description 2
• 239000007787 solid Substances 0.000 description 2
• 238000003756 stirring Methods 0.000 description 2
• -1 sulfuric acid ethers Chemical class 0.000 description 2
• 210000002268 wool Anatomy 0.000 description 2
• RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
• DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
• 235000005811 Viola adunca Nutrition 0.000 description 1
• 240000009038 Viola odorata Species 0.000 description 1
• 235000013487 Viola odorata Nutrition 0.000 description 1
• 235000002254 Viola papilionacea Nutrition 0.000 description 1
• 244000172533 Viola sororia Species 0.000 description 1
• NMLQNVRHVSWEGS-UHFFFAOYSA-N [Cl].[K] Chemical compound [Cl].[K] NMLQNVRHVSWEGS-UHFFFAOYSA-N 0.000 description 1
• 230000009471 action Effects 0.000 description 1
• HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
• 229910021529 ammonia Inorganic materials 0.000 description 1
• 239000007864 aqueous solution Substances 0.000 description 1
• 238000001311 chemical methods and process Methods 0.000 description 1
• 150000001875 compounds Chemical class 0.000 description 1
• 239000012141 concentrate Substances 0.000 description 1
• 238000012790 confirmation Methods 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 238000004043 dyeing Methods 0.000 description 1
• JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
• 230000000116 mitigating effect Effects 0.000 description 1
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
• 230000001590 oxidative effect Effects 0.000 description 1
• AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
• 235000011164 potassium chloride Nutrition 0.000 description 1
• 239000001103 potassium chloride Substances 0.000 description 1
• 239000002244 precipitate Substances 0.000 description 1
• 230000000391 smoking effect Effects 0.000 description 1
• 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
• IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
• 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
• 150000003460 sulfonic acids Chemical class 0.000 description 1
• AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 1