DE1034452B - Sparbeizmittel zum Schutze von Metallen bei der Behandlung mit sauren Mitteln - Google Patents
Sparbeizmittel zum Schutze von Metallen bei der Behandlung mit sauren MittelnInfo
- Publication number
- DE1034452B DE1034452B DED16268A DED0016268A DE1034452B DE 1034452 B DE1034452 B DE 1034452B DE D16268 A DED16268 A DE D16268A DE D0016268 A DED0016268 A DE D0016268A DE 1034452 B DE1034452 B DE 1034452B
- Authority
- DE
- Germany
- Prior art keywords
- acid
- sodium
- acids
- treated
- saver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000002378 acidificating effect Effects 0.000 title claims description 6
- 229910052751 metal Inorganic materials 0.000 title description 9
- 239000002184 metal Substances 0.000 title description 9
- 238000005554 pickling Methods 0.000 title description 6
- 150000002739 metals Chemical class 0.000 title description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 9
- 150000003460 sulfonic acids Chemical class 0.000 claims description 8
- 125000002015 acyclic group Chemical group 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 description 24
- 229910052708 sodium Inorganic materials 0.000 description 24
- 239000011734 sodium Substances 0.000 description 24
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 23
- 150000007513 acids Chemical class 0.000 description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003223 protective agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 241000272534 Struthio camelus Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- -1 cyclic anhydrides Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- KMKHWFHJIBBSBB-UHFFFAOYSA-N phenylsulfanylmethanedithioic acid Chemical compound SC(=S)SC1=CC=CC=C1 KMKHWFHJIBBSBB-UHFFFAOYSA-N 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- UFDGCMYVJSFYQM-UHFFFAOYSA-N propyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SCCC UFDGCMYVJSFYQM-UHFFFAOYSA-N 0.000 description 1
- TWIOETHNYAHVFS-UHFFFAOYSA-N propylcarbamodithioic acid Chemical compound CCCNC(S)=S TWIOETHNYAHVFS-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000008053 sultones Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003564 thiocarbonyl compounds Chemical class 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
- 239000012989 trithiocarbonate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/065—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors sulfur-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE532113D BE532113A (en(2012)) | 1953-11-02 | ||
DED16268A DE1034452B (de) | 1953-11-02 | 1953-11-02 | Sparbeizmittel zum Schutze von Metallen bei der Behandlung mit sauren Mitteln |
US464888A US2988512A (en) | 1953-11-02 | 1954-10-26 | Inhibited acid bath and use |
FR1111043D FR1111043A (fr) | 1953-11-02 | 1954-10-29 | Procédé de protection des métaux au cours de leur traitement par des agents acides |
GB31438/54A GB768581A (en) | 1953-11-02 | 1954-11-01 | A process for the protection of metals on treatment with acid agents |
CH335580D CH335580A (de) | 1953-11-02 | 1954-11-01 | Verfahren zum Schützen von Metallen bei der Behandlung mit sauren Mitteln |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED16268A DE1034452B (de) | 1953-11-02 | 1953-11-02 | Sparbeizmittel zum Schutze von Metallen bei der Behandlung mit sauren Mitteln |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1034452B true DE1034452B (de) | 1958-07-17 |
Family
ID=7035314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DED16268A Pending DE1034452B (de) | 1953-11-02 | 1953-11-02 | Sparbeizmittel zum Schutze von Metallen bei der Behandlung mit sauren Mitteln |
Country Status (6)
Country | Link |
---|---|
US (1) | US2988512A (en(2012)) |
BE (1) | BE532113A (en(2012)) |
CH (1) | CH335580A (en(2012)) |
DE (1) | DE1034452B (en(2012)) |
FR (1) | FR1111043A (en(2012)) |
GB (1) | GB768581A (en(2012)) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1309274A (en) * | 1970-10-27 | 1973-03-07 | Ilford Ltd | Merocyanin dyes |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE825038C (de) * | 1948-10-02 | 1952-01-10 | Farbwerke Hoechst Vormals Meis | Sparbeitze |
DE864185C (de) * | 1950-11-25 | 1953-01-22 | Hoechst Ag | Sparbeize |
DE883544C (de) * | 1944-11-25 | 1953-07-20 | Bayer Ag | Metallsparbeize und Kesselsteinentfernungsmittel |
DE914698C (de) * | 1952-05-21 | 1954-07-08 | Dr Arthur Luettringhaus | Verfahren zum Schutze von Metallen gegen Korrosion |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2734869A (en) * | 1956-02-14 | Lubricating oil additive | ||
US856644A (en) * | 1905-08-28 | 1907-06-11 | Charles E Laverty | Pickling-bath. |
US1855035A (en) * | 1928-01-14 | 1932-04-19 | Rubber Service Lab Co | Means of preserving metallic surfaces |
US2544001A (en) * | 1948-02-09 | 1951-03-06 | Monsanto Chemicals | Cleaning of metallic surfaces |
US2614081A (en) * | 1948-03-26 | 1952-10-14 | Pennsylvania Salt Mfg Co | Pickling bath foaming agent |
US2547193A (en) * | 1949-04-13 | 1951-04-03 | Monsanto Chemicals | Pickling of metals |
US2642430A (en) * | 1949-04-27 | 1953-06-16 | Monsanto Chemicals | Hydroxy substituted aliphatic ether derivatives of nitrogen heterocyclics |
NL128245C (en(2012)) * | 1951-05-31 | |||
US2651630A (en) * | 1951-10-26 | 1953-09-08 | Monsanto Chemicals | Mercapto azine derivatives |
US2695310A (en) * | 1951-12-12 | 1954-11-23 | Lever Brothers Ltd | Preparation of guanidinium mercaptoalkanesulfonate |
US2699991A (en) * | 1951-12-22 | 1955-01-18 | California Research Corp | Surface-active compounds and fuel compositions containing them |
US2799651A (en) * | 1953-02-20 | 1957-07-16 | Standard Oil Co | Corrosion inhibitors and compositions containing the same |
-
0
- BE BE532113D patent/BE532113A/xx unknown
-
1953
- 1953-11-02 DE DED16268A patent/DE1034452B/de active Pending
-
1954
- 1954-10-26 US US464888A patent/US2988512A/en not_active Expired - Lifetime
- 1954-10-29 FR FR1111043D patent/FR1111043A/fr not_active Expired
- 1954-11-01 CH CH335580D patent/CH335580A/de unknown
- 1954-11-01 GB GB31438/54A patent/GB768581A/en not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE883544C (de) * | 1944-11-25 | 1953-07-20 | Bayer Ag | Metallsparbeize und Kesselsteinentfernungsmittel |
DE825038C (de) * | 1948-10-02 | 1952-01-10 | Farbwerke Hoechst Vormals Meis | Sparbeitze |
DE864185C (de) * | 1950-11-25 | 1953-01-22 | Hoechst Ag | Sparbeize |
DE914698C (de) * | 1952-05-21 | 1954-07-08 | Dr Arthur Luettringhaus | Verfahren zum Schutze von Metallen gegen Korrosion |
Also Published As
Publication number | Publication date |
---|---|
US2988512A (en) | 1961-06-13 |
BE532113A (en(2012)) | |
GB768581A (en) | 1957-02-20 |
CH335580A (de) | 1959-01-15 |
FR1111043A (fr) | 1956-02-21 |
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