DE102014205945B4 - Aktives Kathodenmaterial für sekundäre Lithium-Zellen und Batterien - Google Patents
Aktives Kathodenmaterial für sekundäre Lithium-Zellen und Batterien Download PDFInfo
- Publication number
- DE102014205945B4 DE102014205945B4 DE102014205945.3A DE102014205945A DE102014205945B4 DE 102014205945 B4 DE102014205945 B4 DE 102014205945B4 DE 102014205945 A DE102014205945 A DE 102014205945A DE 102014205945 B4 DE102014205945 B4 DE 102014205945B4
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- Germany
- Prior art keywords
- cathode material
- lithium
- metal oxide
- coating
- lithium metal
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0421—Methods of deposition of the material involving vapour deposition
- H01M4/0423—Physical vapour deposition
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0421—Methods of deposition of the material involving vapour deposition
- H01M4/0428—Chemical vapour deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014205945.3A DE102014205945B4 (de) | 2014-03-31 | 2014-03-31 | Aktives Kathodenmaterial für sekundäre Lithium-Zellen und Batterien |
| JP2016559610A JP2017510042A (ja) | 2014-03-31 | 2015-03-24 | 二次リチウムセルおよび電池のための活性カソード材料 |
| KR1020167024568A KR20160140612A (ko) | 2014-03-31 | 2015-03-24 | 리튬 이차전지 및 배터리용 캐소드 활성물질 |
| PCT/EP2015/056244 WO2015150167A1 (de) | 2014-03-31 | 2015-03-24 | Aktives kathodenmaterial für sekundäre lithium-zellen und batterien |
| CN201580017385.5A CN106165156A (zh) | 2014-03-31 | 2015-03-24 | 用于二次锂电池和电池组的活性阴极材料 |
| US15/279,531 US20170018760A1 (en) | 2014-03-31 | 2016-09-29 | Active Cathode Material for Secondary Lithium Cells and Batteries |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014205945.3A DE102014205945B4 (de) | 2014-03-31 | 2014-03-31 | Aktives Kathodenmaterial für sekundäre Lithium-Zellen und Batterien |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE102014205945A1 DE102014205945A1 (de) | 2015-10-01 |
| DE102014205945B4 true DE102014205945B4 (de) | 2025-06-12 |
Family
ID=52774213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102014205945.3A Active DE102014205945B4 (de) | 2014-03-31 | 2014-03-31 | Aktives Kathodenmaterial für sekundäre Lithium-Zellen und Batterien |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20170018760A1 (enExample) |
| JP (1) | JP2017510042A (enExample) |
| KR (1) | KR20160140612A (enExample) |
| CN (1) | CN106165156A (enExample) |
| DE (1) | DE102014205945B4 (enExample) |
| WO (1) | WO2015150167A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7025681B2 (ja) * | 2016-03-08 | 2022-02-25 | 住友金属鉱山株式会社 | 非水系電解質二次電池 |
| FI20165852L (fi) * | 2016-11-14 | 2018-05-15 | Picodeon Ltd Oy | MENETELMÄ Li-IONIAKKUJEN SEPARAATTORIKALVOJEN JA ELEKTRODIEN PINNOITTAMISEKSI JA PINNOITETTU SEPARAATTORI- TAI ELEKTRODIKALVO |
| JP6943023B2 (ja) * | 2017-05-30 | 2021-09-29 | 凸版印刷株式会社 | 積層体グリーンシート、全固体二次電池およびその製造方法 |
| US10511054B2 (en) | 2017-11-07 | 2019-12-17 | Toyota Motor Engineering & Manufacturing North America, Inc. | Compounds with mixed anions as solid Li-ion conductors |
| CN108172789B (zh) * | 2017-12-25 | 2020-11-24 | 中国工程物理研究院电子工程研究所 | 一种氟化锂-一氧化镍纳米复合物及其制备方法 |
| DE102018202180A1 (de) * | 2018-02-13 | 2019-10-17 | Volkswagen Aktiengesellschaft | Kathodenaktivmaterial für eine elektrochemische Vorrichtung und Verfahren zur Beschichtung eines Kathodenaktivmaterials |
| DE102018121275B4 (de) | 2018-08-31 | 2025-03-06 | Volkswagen Aktiengesellschaft | Verfahren und System zur Abscheidung eines Festelektrolyten auf Elektrodenaktivmaterial |
| DE102018219586A1 (de) | 2018-11-15 | 2020-05-20 | Volkswagen Aktiengesellschaft | Beschichtung von Anoden- und Kathodenaktivmaterialien mit hochvoltstabilen Festelektrolyten und einem Elektronenleiter im Mehrschichtsystem und Lithium-Ionen-Batteriezelle |
| DE102018219589A1 (de) | 2018-11-15 | 2020-05-20 | Volkswagen Aktiengesellschaft | Slurryherstellung auf Wasserbasis mit Kathodenaktivmaterial, das mit einem Festelektrolyten beschichtet ist, Herstellung einer Elektrode daraus und Herstellung einer Lithium-Ionen-Batteriezelle |
| DE102018221319A1 (de) | 2018-12-10 | 2020-06-10 | Volkswagen Aktiengesellschaft | Slurryherstellung auf Wasserbasis mit Kathodenaktivmaterial, das mit einem Festelektrolyten beschichtet ist, Herstellung einer Elektrode daraus und Herstellung einer Lithium-Ionen-Batteriezelle |
| DE102018221828A1 (de) | 2018-12-14 | 2020-06-18 | Volkswagen Aktiengesellschaft | Beschichtung von Anoden- und Kathodenaktivmaterialien mit hochvoltstabilen Festelektrolyten und einem Elektronenleiter im Mehrschichtsystem und Lithium-Ionen-Batteriezelle |
| DE102019119793A1 (de) * | 2019-07-22 | 2021-01-28 | Bayerische Motoren Werke Aktiengesellschaft | Kathoden-Aktivmaterial mit Lithiumperoxid, Kathode für eine Lithiumionen-Batterie, Lithiumionen-Batterie und Verwendung von beschichtetem Lithiumperoxid in einer Lithiumionen-Batterie |
| KR102809158B1 (ko) | 2020-01-14 | 2025-05-16 | 주식회사 엘지에너지솔루션 | 이차전지용 양극 활물질의 제조방법 |
| DE102020119841A1 (de) | 2020-07-28 | 2022-02-03 | Bayerische Motoren Werke Aktiengesellschaft | Lithiumionen-Batterie und Verfahren zur Herstellung einer solchen Lithiumionen-Batterie |
| DE102020119842A1 (de) | 2020-07-28 | 2022-02-03 | Bayerische Motoren Werke Aktiengesellschaft | Kathodenaktivmaterial und Lithiumionen-Batterie mit dem Kathodenaktivmaterial |
| DE102020119843A1 (de) | 2020-07-28 | 2022-02-03 | Bayerische Motoren Werke Aktiengesellschaft | Kathodenaktivmaterial und Lithiumionen-Batterie mit dem Kathodenaktivmaterial |
| DE102020119844A1 (de) | 2020-07-28 | 2022-02-03 | Bayerische Motoren Werke Aktiengesellschaft | Lithiumionen-Batterie und Verfahren zur Herstellung einer solchen Lithiumionen-Batterie |
| DE102020132661A1 (de) | 2020-12-08 | 2022-06-09 | Bayerische Motoren Werke Aktiengesellschaft | Kathodenaktivmaterial und Lithiumionen-Batterie mit dem Kathodenaktivmaterial |
| CN116988018B (zh) * | 2023-08-04 | 2025-01-21 | 中国科学技术大学 | 一种磁各向异性及表面粗糙度可调控的铥铁石榴石薄膜及其制备方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100190058A1 (en) | 2009-01-29 | 2010-07-29 | Uchicago Argonne, Llc | Surface protected lithium-metal-oxide electrodes |
| US20100233548A1 (en) | 2007-06-07 | 2010-09-16 | Koninklijke Philips Electronics N.V. | Solid-state battery and method for manufacturing of such a solid-state battery |
| US20110045355A1 (en) | 2009-08-18 | 2011-02-24 | Seiko Epson Corporation | Electrode for lithium battery and lithium battery |
| CN102738451A (zh) | 2012-07-13 | 2012-10-17 | 河南师范大学 | 一种改性锂离子电池正极材料及其制备方法 |
| DE102012203139A1 (de) | 2012-02-29 | 2013-08-29 | Robert Bosch Gmbh | Feststoffzelle |
| DE102012205931A1 (de) | 2012-04-12 | 2013-10-17 | Robert Bosch Gmbh | Elektrochemischer Energiespeicher und Verfahren zum Herstellen desselben |
| DE102012224377A1 (de) | 2012-12-27 | 2014-07-03 | Robert Bosch Gmbh | Verfahren zum Herstellen eines galvanischen Elements und galvanisches Element |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0017400B1 (en) | 1979-04-05 | 1984-05-30 | United Kingdom Atomic Energy Authority | Electrochemical cell and method of making ion conductors for said cell |
| DE102004010892B3 (de) | 2004-03-06 | 2005-11-24 | Christian-Albrechts-Universität Zu Kiel | Chemisch stabiler fester Lithiumionenleiter |
| DE102007030604A1 (de) | 2007-07-02 | 2009-01-08 | Weppner, Werner, Prof. Dr. | Ionenleiter mit Granatstruktur |
| JP5381640B2 (ja) * | 2009-11-24 | 2014-01-08 | 株式会社豊田中央研究所 | リチウム二次電池 |
| CN102244231A (zh) * | 2010-05-14 | 2011-11-16 | 中国科学院物理研究所 | 对正极活性材料和/或正极进行表面包覆的方法以及正极和电池的制备方法 |
| CN102064318B (zh) * | 2010-11-30 | 2013-05-01 | 四会市达博文实业有限公司 | 射频等离子体增强化学气相沉积实现磷酸铁锂碳包覆的方法 |
| KR101312275B1 (ko) * | 2011-03-30 | 2013-09-25 | 삼성에스디아이 주식회사 | 복합체, 이를 포함한 리튬 이차 전지용 전극 활물질, 그 제조방법, 이를 이용한 리튬 이차 전지용 전극 및 이를 채용한 리튬 이차 전지 |
| JP5252064B2 (ja) * | 2011-12-07 | 2013-07-31 | 株式会社豊田自動織機 | リチウムシリケート系化合物及びその製造方法 |
| JP5740297B2 (ja) * | 2011-12-22 | 2015-06-24 | 株式会社日立製作所 | リチウムイオン二次電池用正極、リチウムイオン二次電池、これを搭載した乗り物および電力貯蔵システム |
| JP5851584B2 (ja) * | 2012-03-13 | 2016-02-03 | 株式会社東芝 | 固体電解質二次電池用リチウムイオン伝導性酸化物、固体電解質二次電池および電池パック |
| JP2013214355A (ja) * | 2012-03-30 | 2013-10-17 | Equos Research Co Ltd | リチウムイオン電池用正極 |
| CN103633329B (zh) * | 2012-08-28 | 2015-12-02 | 华为技术有限公司 | 一种全固态锂离子电池复合型正极材料及其制备方法和全固态锂离子电池 |
| JP2013048112A (ja) * | 2012-11-22 | 2013-03-07 | Toyota Motor Corp | 正極活物質 |
-
2014
- 2014-03-31 DE DE102014205945.3A patent/DE102014205945B4/de active Active
-
2015
- 2015-03-24 JP JP2016559610A patent/JP2017510042A/ja active Pending
- 2015-03-24 WO PCT/EP2015/056244 patent/WO2015150167A1/de not_active Ceased
- 2015-03-24 KR KR1020167024568A patent/KR20160140612A/ko not_active Ceased
- 2015-03-24 CN CN201580017385.5A patent/CN106165156A/zh active Pending
-
2016
- 2016-09-29 US US15/279,531 patent/US20170018760A1/en not_active Abandoned
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100233548A1 (en) | 2007-06-07 | 2010-09-16 | Koninklijke Philips Electronics N.V. | Solid-state battery and method for manufacturing of such a solid-state battery |
| US20100190058A1 (en) | 2009-01-29 | 2010-07-29 | Uchicago Argonne, Llc | Surface protected lithium-metal-oxide electrodes |
| US20110045355A1 (en) | 2009-08-18 | 2011-02-24 | Seiko Epson Corporation | Electrode for lithium battery and lithium battery |
| DE102012203139A1 (de) | 2012-02-29 | 2013-08-29 | Robert Bosch Gmbh | Feststoffzelle |
| DE102012205931A1 (de) | 2012-04-12 | 2013-10-17 | Robert Bosch Gmbh | Elektrochemischer Energiespeicher und Verfahren zum Herstellen desselben |
| CN102738451A (zh) | 2012-07-13 | 2012-10-17 | 河南师范大学 | 一种改性锂离子电池正极材料及其制备方法 |
| DE102012224377A1 (de) | 2012-12-27 | 2014-07-03 | Robert Bosch Gmbh | Verfahren zum Herstellen eines galvanischen Elements und galvanisches Element |
Non-Patent Citations (1)
| Title |
|---|
| CHEN J M ET AL: "Electrochemical studies on LiCoO2 surface coated with Y3Al5O12 for lithium-ion cells", JOURNAL OF POWER SOURCES, ELSEVIER SA, CH, vol. 189, no. 1, 1 April 2009 (2009-04-01), Seiten 279 - 287, XP025982697, ISSN: 0378-7753, DOI: 10.1016/J.JPOWSOUR.2008.09.049. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106165156A (zh) | 2016-11-23 |
| KR20160140612A (ko) | 2016-12-07 |
| WO2015150167A1 (de) | 2015-10-08 |
| JP2017510042A (ja) | 2017-04-06 |
| DE102014205945A1 (de) | 2015-10-01 |
| US20170018760A1 (en) | 2017-01-19 |
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