DE102004050506A1 - Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung - Google Patents
Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung Download PDFInfo
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- DE102004050506A1 DE102004050506A1 DE102004050506A DE102004050506A DE102004050506A1 DE 102004050506 A1 DE102004050506 A1 DE 102004050506A1 DE 102004050506 A DE102004050506 A DE 102004050506A DE 102004050506 A DE102004050506 A DE 102004050506A DE 102004050506 A1 DE102004050506 A1 DE 102004050506A1
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- 238000000034 method Methods 0.000 title claims abstract description 34
- 230000008569 process Effects 0.000 title claims abstract description 13
- 150000001336 alkenes Chemical class 0.000 title claims description 25
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 14
- 238000002360 preparation method Methods 0.000 title claims description 6
- 150000002978 peroxides Chemical class 0.000 title description 4
- 238000006243 chemical reaction Methods 0.000 claims abstract description 77
- 150000001875 compounds Chemical class 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims description 46
- 239000007789 gas Substances 0.000 claims description 29
- 238000006735 epoxidation reaction Methods 0.000 claims description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
- 229910052719 titanium Inorganic materials 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 10
- -1 tungstates Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 7
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 7
- 229910001887 tin oxide Inorganic materials 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- 210000003298 dental enamel Anatomy 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002808 molecular sieve Substances 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 125000006850 spacer group Chemical group 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 239000002243 precursor Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims 1
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- 229910052711 selenium Inorganic materials 0.000 claims 1
- 239000011669 selenium Substances 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 150000003658 tungsten compounds Chemical class 0.000 claims 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 26
- 239000012071 phase Substances 0.000 description 16
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 238000010574 gas phase reaction Methods 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical class C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000012223 aqueous fraction Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229950003776 protoporphyrin Drugs 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229940065287 selenium compound Drugs 0.000 description 1
- 150000003343 selenium compounds Chemical class 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/249—Plate-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00783—Laminate assemblies, i.e. the reactor comprising a stack of plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00835—Comprising catalytically active material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00873—Heat exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2453—Plates arranged in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2461—Heat exchange aspects
- B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2469—Feeding means
- B01J2219/247—Feeding means for the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2476—Construction materials
- B01J2219/2477—Construction materials of the catalysts
- B01J2219/2479—Catalysts coated on the surface of plates or inserts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (17)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004050506A DE102004050506A1 (de) | 2004-10-15 | 2004-10-15 | Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung |
| CNA2005800349897A CN101044129A (zh) | 2004-10-15 | 2005-09-16 | 氧化烯烃和过氧化物的制备方法、反应器和其用途 |
| MX2007004501A MX2007004501A (es) | 2004-10-15 | 2005-09-16 | Metodo para producir oxidos y peroxidos de olefina, reactor y el uso del mismo. |
| PCT/EP2005/009965 WO2006042598A1 (de) | 2004-10-15 | 2005-09-16 | Verfahren zur herstellung von olefinoxiden und peroxiden, reaktor und dessen verwendung |
| KR1020077008549A KR20070063004A (ko) | 2004-10-15 | 2005-09-16 | 올레핀 옥사이드 및 과산화물의 제조방법, 반응기 및 이의용도 |
| EA200700873A EA013086B1 (ru) | 2004-10-15 | 2005-09-16 | Способ получения оксидов олефинов и пероксидов, реактор и его применение |
| NZ554394A NZ554394A (en) | 2004-10-15 | 2005-09-16 | Method for producing olefin oxides and peroxides, reactor and the use thereof |
| HR20070150A HRP20070150A2 (hr) | 2004-10-15 | 2005-09-16 | Postupak za proizvodnju olefinskih oksida i peroksida, reaktor i njegova upotreba |
| AU2005297530A AU2005297530A1 (en) | 2004-10-15 | 2005-09-16 | Method for producing olefin oxides and peroxides, reactor and the use thereof |
| CA002584049A CA2584049A1 (en) | 2004-10-15 | 2005-09-16 | Method for producing olefin oxides and peroxides, reactor and the use thereof |
| JP2007536014A JP2008516900A (ja) | 2004-10-15 | 2005-09-16 | オレフィンオキシドおよび過酸化物の生成方法、反応器ならびにその使用 |
| US11/665,357 US20080306288A1 (en) | 2004-10-15 | 2005-09-16 | Method for Producing Olefin Oxides and Peroxides, Reactor and the Use Thereof |
| BRPI0516517-2A BRPI0516517A (pt) | 2004-10-15 | 2005-09-16 | método para produção de óxidos e peróxidos de olefina, reator e uso dos mesmos |
| EP05787485A EP1802596A1 (de) | 2004-10-15 | 2005-09-16 | Verfahren zur herstellung von olefinoxiden und peroxiden, reaktor und dessen verwendung |
| ZA200702469A ZA200702469B (en) | 2004-10-15 | 2007-03-26 | Method for producing olefin oxides and peroxides, reactor and the use thereof |
| EGNA2007000378 EG24502A (en) | 2004-10-15 | 2007-04-15 | Method for producing olefin oxides and peroxides, reactor and the use thereof |
| NO20072459A NO20072459L (no) | 2004-10-15 | 2007-05-14 | Fremgangsmate for produksjon av olefinoksider og peroksider, reaktor og anvendelse derav |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004050506A DE102004050506A1 (de) | 2004-10-15 | 2004-10-15 | Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung |
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| DE102004050506A1 true DE102004050506A1 (de) | 2006-04-20 |
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Family Applications (1)
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| DE102004050506A Withdrawn DE102004050506A1 (de) | 2004-10-15 | 2004-10-15 | Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung |
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| US (1) | US20080306288A1 (https=) |
| EP (1) | EP1802596A1 (https=) |
| JP (1) | JP2008516900A (https=) |
| KR (1) | KR20070063004A (https=) |
| CN (1) | CN101044129A (https=) |
| AU (1) | AU2005297530A1 (https=) |
| BR (1) | BRPI0516517A (https=) |
| CA (1) | CA2584049A1 (https=) |
| DE (1) | DE102004050506A1 (https=) |
| EA (1) | EA013086B1 (https=) |
| EG (1) | EG24502A (https=) |
| HR (1) | HRP20070150A2 (https=) |
| MX (1) | MX2007004501A (https=) |
| NO (1) | NO20072459L (https=) |
| NZ (1) | NZ554394A (https=) |
| WO (1) | WO2006042598A1 (https=) |
| ZA (1) | ZA200702469B (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006015268A1 (de) * | 2006-04-01 | 2007-10-25 | Cognis Ip Management Gmbh | Verfahren zur Herstellung von Alkylenoxiden |
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| GB2433705A (en) * | 2005-12-22 | 2007-07-04 | Shell Int Research | A method of installing an epoxidation catalyst |
| US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| JP5163921B2 (ja) * | 2006-03-01 | 2013-03-13 | 荒川化学工業株式会社 | エポキシ化合物の製造方法 |
| CN101279957B (zh) * | 2007-04-04 | 2012-07-04 | 中国石油化工股份有限公司 | 丙烯环氧化制备环氧丙烷的方法 |
| DE102009003466A1 (de) * | 2009-02-11 | 2010-08-19 | Karlsruher Institut für Technologie | Hexaalkylguanidiniumsalze |
| JP5757126B2 (ja) * | 2011-03-28 | 2015-07-29 | 日産化学工業株式会社 | フローリアクターを用いたシャープレス不斉エポキシ化反応 |
| US9481741B2 (en) | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| ES2769921T3 (es) * | 2015-11-26 | 2020-06-29 | Thyssenkrupp Ind Solutions Ag | Procedimiento para la epoxidación de una olefina |
| CN109999821B (zh) * | 2019-03-12 | 2021-11-16 | 内蒙古工业大学 | 一种表面处理的铝合金催化剂的制备及其应用 |
| CN112979587B (zh) * | 2019-12-12 | 2022-12-02 | 中国科学院大连化学物理研究所 | 一种微通道反应器合成环氧丙烷的方法 |
| EP3954743A1 (de) | 2020-08-12 | 2022-02-16 | Evonik Operations GmbH | Verwendung von siliziumdioxid zur verbesserung der leitfähigkeit von beschichtungen |
| CN113333029B (zh) * | 2021-06-29 | 2023-08-25 | 南京先进生物材料与过程装备研究院有限公司 | 金属改性bea与卟啉配位的复合催化剂及其在环己烯选择性环氧化反应中的应用 |
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| DE19748481A1 (de) * | 1997-11-03 | 1999-05-12 | Inst Mikrotechnik Mainz Gmbh | Statischer Mikrovermischer, und Mikroreaktor sowie dessen Verwendung |
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| DE19731627A1 (de) * | 1997-07-23 | 1999-01-28 | Degussa | Granulate, enthaltend Titansilikalit-l |
| DE19841993B4 (de) * | 1998-09-04 | 2005-02-17 | P21 - Power For The 21St Century Gmbh | Mikrostruktur-Reaktor |
| DE60021086T2 (de) * | 1999-08-17 | 2006-05-04 | Battelle Memorial Institute, Richland | Chemischer reaktor und verfahren zur katalytischen gasphasenreaktionen |
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| US6969505B2 (en) * | 2002-08-15 | 2005-11-29 | Velocys, Inc. | Process for conducting an equilibrium limited chemical reaction in a single stage process channel |
| DE10248599A1 (de) * | 2002-10-17 | 2004-04-29 | Degussa Ag | Verfahren zur Gewinnung einer gasförmigen Phase aus einem flüssigen Medium und Vorrichtung zu seiner Durchführung |
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-
2004
- 2004-10-15 DE DE102004050506A patent/DE102004050506A1/de not_active Withdrawn
-
2005
- 2005-09-16 MX MX2007004501A patent/MX2007004501A/es unknown
- 2005-09-16 KR KR1020077008549A patent/KR20070063004A/ko not_active Withdrawn
- 2005-09-16 WO PCT/EP2005/009965 patent/WO2006042598A1/de not_active Ceased
- 2005-09-16 AU AU2005297530A patent/AU2005297530A1/en not_active Abandoned
- 2005-09-16 HR HR20070150A patent/HRP20070150A2/xx not_active Application Discontinuation
- 2005-09-16 JP JP2007536014A patent/JP2008516900A/ja not_active Withdrawn
- 2005-09-16 BR BRPI0516517-2A patent/BRPI0516517A/pt not_active IP Right Cessation
- 2005-09-16 CA CA002584049A patent/CA2584049A1/en not_active Abandoned
- 2005-09-16 EP EP05787485A patent/EP1802596A1/de not_active Withdrawn
- 2005-09-16 EA EA200700873A patent/EA013086B1/ru not_active IP Right Cessation
- 2005-09-16 CN CNA2005800349897A patent/CN101044129A/zh active Pending
- 2005-09-16 NZ NZ554394A patent/NZ554394A/en not_active IP Right Cessation
- 2005-09-16 US US11/665,357 patent/US20080306288A1/en not_active Abandoned
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2007
- 2007-03-26 ZA ZA200702469A patent/ZA200702469B/xx unknown
- 2007-04-15 EG EGNA2007000378 patent/EG24502A/xx active
- 2007-05-14 NO NO20072459A patent/NO20072459L/no not_active Application Discontinuation
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006015268A1 (de) * | 2006-04-01 | 2007-10-25 | Cognis Ip Management Gmbh | Verfahren zur Herstellung von Alkylenoxiden |
| DE202006020415U1 (de) | 2006-04-01 | 2008-07-03 | Cognis Ip Management Gmbh | Verwendung von Mikroreaktionssystemen |
Also Published As
| Publication number | Publication date |
|---|---|
| EA200700873A1 (ru) | 2007-08-31 |
| AU2005297530A1 (en) | 2006-04-27 |
| EP1802596A1 (de) | 2007-07-04 |
| HRP20070150A2 (hr) | 2007-08-31 |
| BRPI0516517A (pt) | 2008-09-16 |
| MX2007004501A (es) | 2007-05-09 |
| JP2008516900A (ja) | 2008-05-22 |
| US20080306288A1 (en) | 2008-12-11 |
| EG24502A (en) | 2009-08-18 |
| NO20072459L (no) | 2007-06-29 |
| WO2006042598A1 (de) | 2006-04-27 |
| CN101044129A (zh) | 2007-09-26 |
| EA013086B1 (ru) | 2010-02-26 |
| ZA200702469B (en) | 2008-12-31 |
| CA2584049A1 (en) | 2006-04-27 |
| KR20070063004A (ko) | 2007-06-18 |
| NZ554394A (en) | 2009-10-30 |
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