CS271328B2 - Method of 1,4-cis-polybutadiene or butadiene's copolymers preparation - Google Patents

Method of 1,4-cis-polybutadiene or butadiene's copolymers preparation Download PDF

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Publication number
CS271328B2
CS271328B2 CS863479A CS347986A CS271328B2 CS 271328 B2 CS271328 B2 CS 271328B2 CS 863479 A CS863479 A CS 863479A CS 347986 A CS347986 A CS 347986A CS 271328 B2 CS271328 B2 CS 271328B2
Authority
CS
Czechoslovakia
Prior art keywords
butadiene
neodymium
reactor
polymerization
polymer
Prior art date
Application number
CS863479A
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Czech (cs)
English (en)
Other versions
CS347986A2 (en
Inventor
Antonio Carbonaro
Silvano Gordini
Salvatore Cucinella
Original Assignee
Enichem Elastomers
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Enichem Elastomers filed Critical Enichem Elastomers
Publication of CS347986A2 publication Critical patent/CS347986A2/cs
Publication of CS271328B2 publication Critical patent/CS271328B2/cs

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06Butadiene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
CS863479A 1985-05-15 1986-05-14 Method of 1,4-cis-polybutadiene or butadiene's copolymers preparation CS271328B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT20717/85A IT1191614B (it) 1985-05-15 1985-05-15 Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene

Publications (2)

Publication Number Publication Date
CS347986A2 CS347986A2 (en) 1989-12-13
CS271328B2 true CS271328B2 (en) 1990-09-12

Family

ID=11171018

Family Applications (1)

Application Number Title Priority Date Filing Date
CS863479A CS271328B2 (en) 1985-05-15 1986-05-14 Method of 1,4-cis-polybutadiene or butadiene's copolymers preparation

Country Status (21)

Country Link
US (1) US4736001A (es)
EP (1) EP0201979B1 (es)
JP (1) JPH0676460B2 (es)
KR (1) KR890004068B1 (es)
CN (1) CN1008097B (es)
AU (1) AU591119B2 (es)
BR (1) BR8602294A (es)
CA (1) CA1279439C (es)
CS (1) CS271328B2 (es)
DD (1) DD245201A5 (es)
DE (1) DE3662525D1 (es)
EG (1) EG18289A (es)
ES (1) ES8706730A1 (es)
IE (1) IE59072B1 (es)
IN (1) IN167276B (es)
IT (1) IT1191614B (es)
PL (1) PL146475B1 (es)
PT (1) PT82584B (es)
TR (1) TR22613A (es)
YU (1) YU79186A (es)
ZA (1) ZA863288B (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1191612B (it) * 1985-05-15 1988-03-23 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene
US4965327A (en) * 1989-10-23 1990-10-23 The Goodyear Tire & Rubber Company Synthesis of polydiene rubber by high solids solution polymerization
US5158725A (en) * 1991-04-29 1992-10-27 The Goodyear Tire & Rubber Company Continuous mixing of elastomeric compounds
US5405815A (en) * 1993-06-17 1995-04-11 The Goodyear Tire & Rubber Company Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber
US5475067A (en) * 1993-09-16 1995-12-12 Exxon Chemical Patents Inc. Process for polyolefin production using short residence time reactors
DE19512116A1 (de) * 1995-04-04 1996-10-10 Bayer Ag Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden
US6441107B1 (en) * 1998-12-18 2002-08-27 Union Carbide Chemicals & Plastics Technology Corporation Molecular weight control of gas phase polymerized polybutadiene when using a rare earth catalyst
KR100352764B1 (ko) * 2000-03-16 2002-09-16 금호석유화학 주식회사 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매
EP1370593B1 (en) * 2001-02-28 2006-07-26 Bridgestone Corporation Continuous process for the production of conjugated diene polymers having narrow molecular weight distribution and products therefrom
KR100553249B1 (ko) * 2003-05-15 2006-02-20 금호석유화학 주식회사 고 1,4-시스 폴리부타디엔-폴리우레탄 공중합체 및 그 제조방법
ES2588177T3 (es) * 2004-03-02 2016-10-31 Bridgestone Corporation Proceso de polimerización en masa
US7879958B2 (en) * 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
US7825201B2 (en) * 2007-12-31 2010-11-02 Bridgestone Corporation Process for producing polydienes
US7902309B2 (en) 2009-02-23 2011-03-08 Bridgestone Corporation Process and catalyst system for polydiene production
US8623975B2 (en) 2009-06-24 2014-01-07 Bridgestone Corporation Process for producing polydienes
WO2012040026A1 (en) 2010-09-23 2012-03-29 Bridgestone Corporation Process for producing polydienes
CN102558400B (zh) * 2010-12-09 2014-07-02 中国石油化工股份有限公司 钕系均相稀土催化剂、其制备方法及其应用
CN102532356B (zh) * 2010-12-10 2014-05-14 北京化工大学 一种稀土催化剂及共轭二烯烃在芳烃介质中的可控聚合方法
US9000107B2 (en) 2011-01-31 2015-04-07 Bridgestone Corporation Process for producing polydienes
BR112014011773B1 (pt) 2011-11-17 2020-10-13 Bridgestone Corporation processo para a produção de polidienos
RU2523799C1 (ru) 2011-12-20 2014-07-27 Чайна Петролеум Энд Кемикал Корпорейшн Добавка и способ для обрыва полимеризации и/или снижения вязкости раствора полимера
SG11201404817VA (en) 2012-02-27 2014-09-26 Bridgestone Corp Processes for the preparation of high-cis polydienes
EP2825574B1 (en) 2012-03-14 2016-02-24 Bridgestone Corporation Process for producing polydienes
CN112048111B (zh) 2013-12-03 2022-12-02 株式会社普利司通 用于制备顺式-1,4-聚丁二烯和间同立构1,2-聚丁二烯的共混物的方法
CN105330763B (zh) * 2014-07-10 2020-04-07 中国石油化工股份有限公司 稀土催化剂用组合物和稀土催化剂及其制备方法和应用和烯烃聚合方法
EP3204430B1 (en) 2014-10-10 2019-06-26 Bridgestone Corporation Polymerization catalyst composition and method of employing same
US10202474B2 (en) 2015-09-11 2019-02-12 Bridgestone Corporation Process for producing polydienes
US10730985B2 (en) 2016-12-19 2020-08-04 Bridgestone Corporation Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer
US11807704B2 (en) 2017-12-15 2023-11-07 Bridgestone Corporation Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer
EP3732210A4 (en) 2017-12-30 2021-08-11 Bridgestone Corporation COMPOSITION INCLUDING MULTIPLE POLYMERS WITH TERMINAL FUNCTIONALIZATION
US11584808B2 (en) 2019-12-30 2023-02-21 Bridgestone Corporation Polymerization catalyst composition and method of employing same
FR3108910B1 (fr) * 2020-04-07 2023-06-02 Michelin & Cie Composition de caoutchouc comprenant du polyethylene a basse temperature de fusion

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1420566A1 (de) * 1956-12-31 1968-12-12 Mannesmann Ag Verfahren zur Polymerisation von AEthylen
US3397195A (en) * 1964-12-18 1968-08-13 Hercules Inc Preparation of alpha-olefin polymers in finely divided form
US3803053A (en) * 1968-05-08 1974-04-09 Atlantic Richfield Co Lanthanide oligomerization catalyst
DE2830080A1 (de) * 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
CA1223396A (en) * 1981-06-29 1987-06-23 Tooru Shibata Process for producing conjugated diene polymer
IT1151542B (it) * 1982-04-15 1986-12-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1164238B (it) * 1983-05-25 1987-04-08 Anic Spa Procedimento per la polimerizzazione del butadiene
IT1191612B (it) * 1985-05-15 1988-03-23 Enichem Elastomers Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene

Also Published As

Publication number Publication date
ZA863288B (en) 1986-12-30
IT1191614B (it) 1988-03-23
ES555333A0 (es) 1987-07-01
IE59072B1 (en) 1994-01-12
TR22613A (tr) 1988-01-08
IE861276L (en) 1986-11-15
IT8520717A0 (it) 1985-05-15
US4736001A (en) 1988-04-05
EP0201979B1 (en) 1989-03-22
EP0201979A1 (en) 1986-11-20
PT82584B (pt) 1988-11-30
AU591119B2 (en) 1989-11-30
IN167276B (es) 1990-09-29
DD245201A5 (de) 1987-04-29
JPH0676460B2 (ja) 1994-09-28
PL146475B1 (en) 1989-02-28
DE3662525D1 (en) 1989-04-27
CN86103350A (zh) 1986-11-12
KR860009048A (ko) 1986-12-19
CS347986A2 (en) 1989-12-13
PT82584A (en) 1986-06-01
ES8706730A1 (es) 1987-07-01
KR890004068B1 (ko) 1989-10-18
AU5710286A (en) 1986-11-20
JPS61268706A (ja) 1986-11-28
BR8602294A (pt) 1987-01-21
CA1279439C (en) 1991-01-22
YU79186A (en) 1987-10-31
CN1008097B (zh) 1990-05-23
EG18289A (en) 1992-11-30

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IF00 In force as of 2000-06-30 in czech republic
MK4A Patent expired

Effective date: 20010514