CO4410377A1 - Proceso de oxidacion parcial para la produccion de gas rico en hidrogeno - Google Patents

Proceso de oxidacion parcial para la produccion de gas rico en hidrogeno

Info

Publication number
CO4410377A1
CO4410377A1 CO94048434A CO94048434A CO4410377A1 CO 4410377 A1 CO4410377 A1 CO 4410377A1 CO 94048434 A CO94048434 A CO 94048434A CO 94048434 A CO94048434 A CO 94048434A CO 4410377 A1 CO4410377 A1 CO 4410377A1
Authority
CO
Colombia
Prior art keywords
gas
fuel
partial oxidation
saturated
hydrogen
Prior art date
Application number
CO94048434A
Other languages
English (en)
Inventor
Frederick Charles Jahnke
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of CO4410377A1 publication Critical patent/CO4410377A1/es

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0877Methods of cooling by direct injection of fluid
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0883Methods of cooling by indirect heat exchange
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
    • C01B2203/0894Generation of steam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
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    • C01INORGANIC CHEMISTRY
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1094Promotors or activators
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/146At least two purification steps in series
    • C01B2203/147Three or more purification steps in series

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

ESTA INVENCION SE RELACIONA CON LA PRODUCCI0N DE GAS RICO EN HIDROGENO MEDIANTE LA OXIDACION PAR- CIAL DE UN COMBUSTIBLE HIDROCARBONACEO GASEOSO SA- TURADO O DE UNA MEZCLA DE COMBUSTIBLE HIDROCARBO- NACEO GASEOSO SATURADO Y UN COMBUSTIBLE HIDROCAR- BONACEO LIQUIDO EN UN GENERADOR DE GAS. EL PROCESO, UN COMBUSTIBLE HIDROCARBONACEO GAS SA- TURADO PROCEDENTE DE UN POSTERIOR SATURADOR DE GAS COMBUSTIBLE SE PRECALIENTA MEDIANTE INTERCAMBIO TERMICO INDIRECTO CON UNA PORCION DE UNA CORRIENTE DE GAS DEL PROCESO DESPLAZADO Y PROCEDIENTE DE UNA ZONA DE CONVERSION CATALITICA POR DESPLAZAMIENTO DIRECTO AGUA-GAS Y SE HACE REACCIONAR EN DICHO GE- NERADOR DE GAS DE OXIDACION PARCIAL. LA CORRIENTE DE GAS DEL PROCESO PROCEDENTE DEL GE- NERADOR DE GAS DE OXIDACION PARCIAL NO CATALITICO SE ENFRIA Y SE LAVA CON AGUA Y SE PRECALIENTA ME- DIANTE INTERCAMBIO TERMICO INDIRECTO CON UNA SE- GUNDA PORCION DE LA CORRIENTE DE GAS DEL PROCESO PROCEDENTE DE LA ZONA DE CONVERSION POR DESPLAZA- MIENTO ANTES DE REACCIONAR CATALITICAMENTE EL CO Y EL H2O DE LA CORRIENTE DE GAS DE PROCESO EN LA ZO- NA DE CONVERSION POR DESPLAZAMIENTO PARA AUMENTAR SU CONTENIDO EN H2. LA CORRIENTE DE GAS DEL PROCESO DESPLAZADO SE EN- FRIA Y SE DESAGUA PARA PRODUCIR CONDENSADO DE DES- PLAZAMIENTO EL CUAL SE EMPLEA PARA SATURAR DICHA ALIMENTACION PRECALENTADA DE COMBUSTIBLE HIDROCAR- BONACEO GASEOSO AL GENERADOR DE GAS DE OXIDACION PARCIAL. FIGURA 1
CO94048434A 1993-12-01 1994-10-24 Proceso de oxidacion parcial para la produccion de gas rico en hidrogeno CO4410377A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/159,610 US5358696A (en) 1993-12-01 1993-12-01 Production of H2 -rich gas

Publications (1)

Publication Number Publication Date
CO4410377A1 true CO4410377A1 (es) 1997-01-09

Family

ID=22573256

Family Applications (1)

Application Number Title Priority Date Filing Date
CO94048434A CO4410377A1 (es) 1993-12-01 1994-10-24 Proceso de oxidacion parcial para la produccion de gas rico en hidrogeno

Country Status (16)

Country Link
US (2) US5358696A (es)
EP (1) EP0731773A4 (es)
JP (1) JPH09502694A (es)
CN (1) CN1136800A (es)
AU (1) AU680070B2 (es)
BR (1) BR9408247A (es)
CA (1) CA2177176A1 (es)
CO (1) CO4410377A1 (es)
FI (1) FI962218A (es)
HU (1) HUT75978A (es)
NO (1) NO962260L (es)
NZ (1) NZ276225A (es)
PL (1) PL314726A1 (es)
SK (1) SK70496A3 (es)
TW (1) TW311903B (es)
WO (1) WO1995015290A1 (es)

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Also Published As

Publication number Publication date
HUT75978A (en) 1997-05-28
CA2177176A1 (en) 1995-06-08
FI962218A0 (fi) 1996-05-27
AU680070B2 (en) 1997-07-17
WO1995015290A1 (en) 1995-06-08
CN1136800A (zh) 1996-11-27
FI962218A (fi) 1996-07-11
US5744067A (en) 1998-04-28
EP0731773A4 (en) 2000-02-23
NZ276225A (en) 1996-09-25
NO962260D0 (no) 1996-05-31
EP0731773A1 (en) 1996-09-18
PL314726A1 (en) 1996-09-16
NO962260L (no) 1996-07-04
TW311903B (es) 1997-08-01
BR9408247A (pt) 1997-05-27
SK70496A3 (en) 1997-04-09
AU1040695A (en) 1995-06-19
JPH09502694A (ja) 1997-03-18
US5358696A (en) 1994-10-25
HU9601481D0 (en) 1996-07-29

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