CN1938379B - 冲击性改善的组合物及方法 - Google Patents
冲击性改善的组合物及方法 Download PDFInfo
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- CN1938379B CN1938379B CN2005800102343A CN200580010234A CN1938379B CN 1938379 B CN1938379 B CN 1938379B CN 2005800102343 A CN2005800102343 A CN 2005800102343A CN 200580010234 A CN200580010234 A CN 200580010234A CN 1938379 B CN1938379 B CN 1938379B
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- monomer
- weight
- methyl
- hydroxy phenyl
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- 239000000203 mixture Substances 0.000 title claims abstract description 88
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000000178 monomer Substances 0.000 claims abstract description 183
- 229920001971 elastomer Polymers 0.000 claims abstract description 127
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 76
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 71
- 239000004417 polycarbonate Substances 0.000 claims abstract description 71
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 60
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 56
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 31
- 150000002825 nitriles Chemical class 0.000 claims abstract description 26
- 239000011159 matrix material Substances 0.000 claims description 54
- 238000002360 preparation method Methods 0.000 claims description 46
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 45
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 44
- 125000003118 aryl group Chemical group 0.000 claims description 43
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 29
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- -1 alkyl (methyl) acrylate Chemical compound 0.000 claims description 26
- 125000001118 alkylidene group Chemical group 0.000 claims description 25
- 229920000638 styrene acrylonitrile Polymers 0.000 claims description 18
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 16
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 15
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- 125000005647 linker group Chemical group 0.000 claims description 10
- 239000011145 styrene acrylonitrile resin Substances 0.000 claims description 10
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 9
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 9
- 239000004793 Polystyrene Substances 0.000 claims description 9
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052794 bromium Inorganic materials 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- 229920001897 terpolymer Polymers 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000049 pigment Substances 0.000 claims description 8
- 239000001294 propane Substances 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000975 dye Substances 0.000 claims description 5
- 150000002431 hydrogen Chemical group 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 claims description 4
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- AHVOFPQVUVXHNL-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.CCCCOC(=O)C=C AHVOFPQVUVXHNL-UHFFFAOYSA-N 0.000 claims description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000005328 phosphinyl group Chemical group [PH2](=O)* 0.000 claims description 4
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 claims description 4
- VNNBZUFJRRODHO-UHFFFAOYSA-N prop-2-enenitrile;prop-1-en-2-ylbenzene Chemical compound C=CC#N.CC(=C)C1=CC=CC=C1 VNNBZUFJRRODHO-UHFFFAOYSA-N 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 150000003457 sulfones Chemical class 0.000 claims description 4
- 150000003462 sulfoxides Chemical class 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 4
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 3
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 150000001875 compounds Chemical group 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 230000006872 improvement Effects 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 2
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 claims description 2
- PBYQIPORGDZOGS-UHFFFAOYSA-N 2-ethyl-4-propylphenol Chemical compound CCCC1=CC=C(O)C(CC)=C1 PBYQIPORGDZOGS-UHFFFAOYSA-N 0.000 claims description 2
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 claims description 2
- SYDNSSSQVSOXTN-UHFFFAOYSA-N 2-nitro-p-cresol Chemical compound CC1=CC=C(O)C([N+]([O-])=O)=C1 SYDNSSSQVSOXTN-UHFFFAOYSA-N 0.000 claims description 2
- ZPBYCSQKDDZPGO-UHFFFAOYSA-N 2-phenyl-4-propylphenol Chemical compound CCCC1=CC=C(O)C(C=2C=CC=CC=2)=C1 ZPBYCSQKDDZPGO-UHFFFAOYSA-N 0.000 claims description 2
- ZNVLKMKGFWEUPV-UHFFFAOYSA-N 2-propan-2-yl-4-propylphenol Chemical compound CCCC1=CC=C(O)C(C(C)C)=C1 ZNVLKMKGFWEUPV-UHFFFAOYSA-N 0.000 claims description 2
- KAAUEKCDBCEPPL-UHFFFAOYSA-N 3-chloro-4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1Cl KAAUEKCDBCEPPL-UHFFFAOYSA-N 0.000 claims description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 2
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 claims description 2
- YNWRQXYZKFAPSH-UHFFFAOYSA-N 4-(4-hydroxy-3,5-dimethylphenyl)sulfinyl-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(S(=O)C=2C=C(C)C(O)=C(C)C=2)=C1 YNWRQXYZKFAPSH-UHFFFAOYSA-N 0.000 claims description 2
- SUCTVKDVODFXFX-UHFFFAOYSA-N 4-(4-hydroxy-3,5-dimethylphenyl)sulfonyl-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(S(=O)(=O)C=2C=C(C)C(O)=C(C)C=2)=C1 SUCTVKDVODFXFX-UHFFFAOYSA-N 0.000 claims description 2
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 claims description 2
- RQCACQIALULDSK-UHFFFAOYSA-N 4-(4-hydroxyphenyl)sulfinylphenol Chemical compound C1=CC(O)=CC=C1S(=O)C1=CC=C(O)C=C1 RQCACQIALULDSK-UHFFFAOYSA-N 0.000 claims description 2
- YCSVMCYCFDEOMM-UHFFFAOYSA-N 4-(cyclohexylmethyl)phenol Chemical compound C1=CC(O)=CC=C1CC1CCCCC1 YCSVMCYCFDEOMM-UHFFFAOYSA-N 0.000 claims description 2
- DFVAFJJABIQSBK-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-methylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 DFVAFJJABIQSBK-UHFFFAOYSA-N 0.000 claims description 2
- RPJFWRZEEKJTGN-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=CC(O)=CC=2)=C1 RPJFWRZEEKJTGN-UHFFFAOYSA-N 0.000 claims description 2
- CYYZDBDROVLTJU-UHFFFAOYSA-N 4-n-Butylphenol Chemical compound CCCCC1=CC=C(O)C=C1 CYYZDBDROVLTJU-UHFFFAOYSA-N 0.000 claims description 2
- KNDDEFBFJLKPFE-UHFFFAOYSA-N 4-n-Heptylphenol Chemical compound CCCCCCCC1=CC=C(O)C=C1 KNDDEFBFJLKPFE-UHFFFAOYSA-N 0.000 claims description 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
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- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 2
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 2
- ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 claims description 2
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 claims description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 2
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 claims description 2
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 claims description 2
- SRONXYPFSAKOGH-UHFFFAOYSA-N cyclopentadecane Chemical compound C1CCCCCCCCCCCCCC1 SRONXYPFSAKOGH-UHFFFAOYSA-N 0.000 claims description 2
- PWAPCRSSMCLZHG-UHFFFAOYSA-N cyclopentylidene Chemical group [C]1CCCC1 PWAPCRSSMCLZHG-UHFFFAOYSA-N 0.000 claims description 2
- LJXTYJXBORAIHX-UHFFFAOYSA-N diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1 LJXTYJXBORAIHX-UHFFFAOYSA-N 0.000 claims description 2
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000001905 inorganic group Chemical group 0.000 claims description 2
- 229910052740 iodine Inorganic materials 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims description 2
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 2
- ASHGTJPOSUFTGB-UHFFFAOYSA-N methyl resorcinol Natural products COC1=CC=CC(O)=C1 ASHGTJPOSUFTGB-UHFFFAOYSA-N 0.000 claims description 2
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 2
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- 125000000962 organic group Chemical group 0.000 claims description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims description 2
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- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- RFPMGSKVEAUNMZ-UHFFFAOYSA-N pentylidene Chemical group [CH2+]CCC[CH-] RFPMGSKVEAUNMZ-UHFFFAOYSA-N 0.000 claims description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
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- 150000003568 thioethers Chemical class 0.000 claims description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 2
- FBWWONJGKBCKRQ-UHFFFAOYSA-N 3-(2,3-dihydroxyphenyl)sulfonylbenzene-1,2-diol Chemical compound OC1=CC=CC(S(=O)(=O)C=2C(=C(O)C=CC=2)O)=C1O FBWWONJGKBCKRQ-UHFFFAOYSA-N 0.000 claims 1
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- 229910052799 carbon Inorganic materials 0.000 description 7
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/04—Aromatic polycarbonates
- C08G64/045—Aromatic polycarbonates containing aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/16—Homopolymers or copolymers of alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Steroid Compounds (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | 4 | 5 |
第一阶段单体 | |||||
苯乙烯 | 6.11 | 12.22 | 18.34 | 24.45 | 30.56 |
丙烯腈 | 3.06 | 6.11 | 9.17 | 12.22 | 15.28 |
第二阶段单体 | |||||
苯乙烯 | 18.33 | 14.67 | 11 | 7.33 | 3.67 |
丙烯腈 | 11.46 | 9.17 | 6.87 | 4.58 | 2.29 |
甲基丙烯酸甲酯 | 16.04 | 12.83 | 9.62 | 6.42 | 3.21 |
产物中凝胶重量% | 50.5 | 51 | 54 | 59 | 63 |
实施例 | 6 | 7 | 8 | 9 |
第一阶段单体 | ||||
苯乙烯份数 | 12.1 | 12.1 | 16.59 | 20.27 |
丙烯腈份数 | 4.54 | 4.54 | 7.53 | 9.98 |
MMA份数 | 13.61 | 13.61 | 6.12 | 0 |
第二阶段单体 | ||||
苯乙烯份数 | 9.9 | 16.58 | 13.58 | 9.9 |
丙烯腈份数 | 3.71 | 8.17 | 6.16 | 3.71 |
MMA份数 | 11.14 | 0 | 5.01 | 11.14 |
产物中凝胶重量% | 55 | 60.6 | 60.6 | 64.6 |
实施例 | 15 | 16 | 17 | 18 | 19 | 20 |
第一阶段单体 | ||||||
苯乙烯 | 20.44 | 20.44 | 20.44 | 21.96 | 21.96 | 21.96 |
丙烯腈 | 10.07 | 10.07 | 10.07 | 8.54 | 8.54 | 8.54 |
第二阶段单体 | ||||||
苯乙烯 | 9.80 | 9.80 | 7.35 | 9.80 | 9.80 | 7.35 |
丙烯腈 | 6.13 | 3.68 | 2.45 | 6.13 | 3.68 | 2.45 |
甲基丙烯酸甲酯 | 8.58 | 11.03 | 14.70 | 8.58 | 11.03 | 14.70 |
实施例 | C.Ex. | 21 | 22 | 23 | 24 | 25 |
M-ASA-接枝 | ASA | Ex.6 | Ex.7 | Ex.8 | Ex.9 | Ex.14 |
δE | 3.39 | 0.98 | 2.19 | 1.36 | 1.45 | 0.96 |
60°光泽度* | 79 | 89 | 86 | 91 | 90 | 93 |
VicatB,℃ | 108 | 106.5 | 107.4 | 107.3 | 108 | 107.5 |
弯曲板冲击强度,焦耳 | 14.7 | 17.6 | 18.7 | 20.9 | 11.9 | 21.9 |
伊佐德冲击强度,KJ/m2 | 11.8 | 8.7 | 10.2 | 11.7 | 11.8 | 11.0 |
MVR,cm3/10min. | 23.2 | 28 | 25.6 | 24 | 23.8 | 24.8 |
实施例 | C.Ex. | 26 | 27 | 28 | 29 |
M-ASA-接枝 | ASA | Ex.10 | Ex.11 | Ex.12 | Ex.13 |
δE | 3.39 | 1.29 | 0.80 | 1.38 | 1.22 |
60°光泽度* | 79 | 96 | 86 | 95 | 88 |
Vicat B,℃ | 108 | 107.2 | 107.4 | 107.7 | 107.8 |
弯曲板冲击强度,焦耳 | 14.7 | 8.4 | 47.9 | 18 | 23 |
伊佐德冲击强度,KJ/m2 | 11.8 | 11.5 | 12.2 | 10 | 11.8 |
MVR,cm3/10min. | 23.2 | 21.9 | 18.3 | 23.0 | 13.6 |
实施例 | C.Ex. | 30 | 31 | 32 |
热塑性树脂 | SAN75:25 | MMA-SAN | AMSAN | SAN66:33 |
δE | 3.39 | 1.30 | 1.34 | 1.95 |
60°光泽度* | 79 | 90 | 90 | 90 |
VicatB,℃ | 108 | 100.9 | 117.5 | 108.9 |
弯曲板冲击强度,焦耳 | 14.7 | 43.5 | 49.6 | 37.4 |
伊佐德冲击强度,KJ/m2 | 11.8 | 17.6 | 19.8 | 18.9 |
MVR,cm3/10min. | 23.2 | 10.6 | 6.9 | 14.6 |
Claims (42)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/771,520 | 2004-02-04 | ||
US10/771,520 US20050171297A1 (en) | 2004-02-04 | 2004-02-04 | Impact-modified compositions and method |
PCT/US2005/000983 WO2005080503A1 (en) | 2004-02-04 | 2005-01-13 | Impact-modified compositions and method |
Publications (2)
Publication Number | Publication Date |
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CN1938379A CN1938379A (zh) | 2007-03-28 |
CN1938379B true CN1938379B (zh) | 2012-05-16 |
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CN2005800102343A Expired - Fee Related CN1938379B (zh) | 2004-02-04 | 2005-01-13 | 冲击性改善的组合物及方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20050171297A1 (zh) |
EP (1) | EP1713862B1 (zh) |
JP (1) | JP4768635B2 (zh) |
KR (1) | KR101143239B1 (zh) |
CN (1) | CN1938379B (zh) |
AT (1) | ATE384766T1 (zh) |
AU (1) | AU2005214316A1 (zh) |
DE (1) | DE602005004509T2 (zh) |
ES (1) | ES2300981T3 (zh) |
WO (1) | WO2005080503A1 (zh) |
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US8969476B2 (en) * | 2002-06-21 | 2015-03-03 | Sabic Global Technologies B.V. | Impact-modified compositions |
US20050245645A1 (en) * | 2004-05-03 | 2005-11-03 | General Electric Company | Special visual effect thermoplastic compositions, articles made therefrom, and method |
US20060069208A1 (en) * | 2004-09-29 | 2006-03-30 | General Electric Company | Weatherable resinous composition with improved heat resistance |
US20060069207A1 (en) * | 2004-09-29 | 2006-03-30 | General Electric Company | Resinous composition with improved resistance to plate-out formation, and method |
US20100016507A1 (en) * | 2005-06-03 | 2010-01-21 | Techno Polymer Co., Ltd. | Thermoplastic resin, process for production of the same, and molded article manufactured from the same |
US8674007B2 (en) * | 2006-07-12 | 2014-03-18 | Sabic Innovative Plastics Ip B.V. | Flame retardant and scratch resistant thermoplastic polycarbonate compositions |
US8030400B2 (en) * | 2006-08-01 | 2011-10-04 | Sabic Innovative Plastics Ip B.V. | Thermoplastic polycarbonate compositions with improved chemical and scratch resistance |
US8871865B2 (en) * | 2006-08-01 | 2014-10-28 | Sabic Global Technologies B.V. | Flame retardant thermoplastic polycarbonate compositions |
US20080242779A1 (en) * | 2007-04-02 | 2008-10-02 | Satish Kumar Gaggar | Resinous compositions and articles made therefrom |
KR100856137B1 (ko) * | 2007-08-08 | 2008-09-02 | 제일모직주식회사 | 전기전도성 열가소성 수지 조성물 및 그 성형품 |
KR101269422B1 (ko) * | 2009-12-30 | 2013-06-04 | 제일모직주식회사 | 내마모성 및 전기전도성이 우수한 폴리카보네이트계 수지 조성물 및 그 제조방법 |
KR101654722B1 (ko) * | 2012-12-28 | 2016-09-13 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 포함한 성형품 |
WO2014104485A1 (ko) | 2012-12-28 | 2014-07-03 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 포함한 성형품 |
KR20150002267A (ko) | 2013-06-28 | 2015-01-07 | 제일모직주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
KR101665483B1 (ko) | 2013-08-01 | 2016-10-12 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 이용한 성형품 |
KR101681212B1 (ko) | 2013-09-03 | 2016-11-30 | 롯데첨단소재(주) | 열가소성 수지 조성물을 이용한 자동차용 성형품 |
CN103980675B (zh) * | 2014-04-30 | 2016-08-24 | 中国科学院化学研究所 | 一种3d打印芳香族聚酯材料及其制备方法 |
CN103980672B (zh) * | 2014-04-30 | 2016-07-06 | 中国科学院化学研究所 | 一种3d打印芳香族聚酯材料及其制备方法 |
CN108192312A (zh) * | 2018-01-12 | 2018-06-22 | 中山长虹电器有限公司 | 具有细腻的金属/珠光幻彩质感的高亮免喷涂聚碳酸酯复合材料及其制备方法 |
CN111073252B (zh) * | 2019-12-24 | 2022-04-05 | 上海长伟锦磁工程塑料有限公司 | 高耐候浅色无卤阻燃pc/asa合金材料及其制备方法 |
KR20210086227A (ko) * | 2019-12-31 | 2021-07-08 | 롯데케미칼 주식회사 | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
CN116426109B (zh) * | 2023-05-09 | 2024-03-26 | 上海品诚控股集团有限公司 | Pc薄膜、阻燃透明纤维复合材料及制备方法 |
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-
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- 2005-01-13 CN CN2005800102343A patent/CN1938379B/zh not_active Expired - Fee Related
- 2005-01-13 JP JP2006552122A patent/JP4768635B2/ja not_active Expired - Fee Related
- 2005-01-13 AT AT05705579T patent/ATE384766T1/de not_active IP Right Cessation
- 2005-01-13 DE DE602005004509T patent/DE602005004509T2/de active Active
- 2005-01-13 EP EP05705579A patent/EP1713862B1/en active Active
- 2005-01-13 AU AU2005214316A patent/AU2005214316A1/en not_active Abandoned
- 2005-01-13 WO PCT/US2005/000983 patent/WO2005080503A1/en active IP Right Grant
- 2005-01-13 ES ES05705579T patent/ES2300981T3/es active Active
- 2005-01-13 KR KR1020067015712A patent/KR101143239B1/ko not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
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JP4768635B2 (ja) | 2011-09-07 |
WO2005080503A8 (en) | 2006-08-31 |
JP2007520616A (ja) | 2007-07-26 |
EP1713862B1 (en) | 2008-01-23 |
ES2300981T3 (es) | 2008-06-16 |
EP1713862A1 (en) | 2006-10-25 |
DE602005004509D1 (de) | 2008-03-13 |
US20050171297A1 (en) | 2005-08-04 |
AU2005214316A1 (en) | 2005-09-01 |
KR20070009559A (ko) | 2007-01-18 |
KR101143239B1 (ko) | 2012-05-18 |
CN1938379A (zh) | 2007-03-28 |
WO2005080503A1 (en) | 2005-09-01 |
DE602005004509T2 (de) | 2009-01-22 |
ATE384766T1 (de) | 2008-02-15 |
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