CN1861311A - 无铅抗氧化含稀土SnZn合金焊料及其制备方法 - Google Patents
无铅抗氧化含稀土SnZn合金焊料及其制备方法 Download PDFInfo
- Publication number
- CN1861311A CN1861311A CN 200610078038 CN200610078038A CN1861311A CN 1861311 A CN1861311 A CN 1861311A CN 200610078038 CN200610078038 CN 200610078038 CN 200610078038 A CN200610078038 A CN 200610078038A CN 1861311 A CN1861311 A CN 1861311A
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- alloy
- snzn
- earth
- lead
- solder
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 63
- 239000000956 alloy Substances 0.000 title claims abstract description 63
- 229910005728 SnZn Inorganic materials 0.000 title claims abstract description 57
- 230000003064 anti-oxidating effect Effects 0.000 title claims abstract description 18
- 238000003466 welding Methods 0.000 title description 36
- 238000000034 method Methods 0.000 title description 14
- 230000004907 flux Effects 0.000 title description 2
- 229910000679 solder Inorganic materials 0.000 claims abstract description 58
- 229910052802 copper Inorganic materials 0.000 claims abstract description 22
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 12
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 9
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 9
- 229910052738 indium Inorganic materials 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 229910052691 Erbium Inorganic materials 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 239000010949 copper Substances 0.000 claims description 36
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 30
- 230000004927 fusion Effects 0.000 claims description 24
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 14
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 14
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- 150000002910 rare earth metals Chemical class 0.000 claims description 12
- 239000011833 salt mixture Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 10
- 235000011164 potassium chloride Nutrition 0.000 claims description 7
- 239000001103 potassium chloride Substances 0.000 claims description 7
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 5
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 238000005476 soldering Methods 0.000 abstract description 24
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 description 25
- 239000011701 zinc Substances 0.000 description 25
- 230000003647 oxidation Effects 0.000 description 23
- 239000000843 powder Substances 0.000 description 18
- 238000005219 brazing Methods 0.000 description 12
- 229910007116 SnPb Inorganic materials 0.000 description 9
- 238000002844 melting Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000010008 shearing Methods 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 3
- 229910020994 Sn-Zn Inorganic materials 0.000 description 3
- 229910009069 Sn—Zn Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229910001152 Bi alloy Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910001074 Lay pewter Inorganic materials 0.000 description 1
- 206010027439 Metal poisoning Diseases 0.000 description 1
- 229910007637 SnAg Inorganic materials 0.000 description 1
- -1 SnAgCu Inorganic materials 0.000 description 1
- 229910008433 SnCU Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- JWVAUCBYEDDGAD-UHFFFAOYSA-N bismuth tin Chemical compound [Sn].[Bi] JWVAUCBYEDDGAD-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000006023 eutectic alloy Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 208000008127 lead poisoning Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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Abstract
Description
合金焊料 | 液相线温度(℃) | 固相线温度(℃) | 减切强度MPa | 扩展率(%) |
实施例1 | 187.5 | 190.2 | 65.3 | 80.1 |
实施例2 | 188.6 | 191.3 | 60.5 | 81.5 |
实施例3 | 189.2 | 192.5 | 59.8 | 79.8 |
实施例4 | 186.5 | 189.5 | 63.5 | 80.5 |
实施例5 | 187.9 | 190.5 | 58.6 | 80.6 |
对比例 | 197 | 201 | 45.5 | 62 |
Claims (4)
Priority Applications (1)
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CNB2006100780386A CN100462183C (zh) | 2006-04-30 | 2006-04-30 | 无铅抗氧化含稀土SnZn合金焊料及其制备方法 |
Applications Claiming Priority (1)
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CNB2006100780386A CN100462183C (zh) | 2006-04-30 | 2006-04-30 | 无铅抗氧化含稀土SnZn合金焊料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1861311A true CN1861311A (zh) | 2006-11-15 |
CN100462183C CN100462183C (zh) | 2009-02-18 |
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CNB2006100780386A Expired - Fee Related CN100462183C (zh) | 2006-04-30 | 2006-04-30 | 无铅抗氧化含稀土SnZn合金焊料及其制备方法 |
Country Status (1)
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CN (1) | CN100462183C (zh) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101380700B (zh) * | 2007-09-05 | 2011-04-20 | 北京康普锡威科技有限公司 | 一种锡铋铜系无铅焊料及其制备方法 |
CN101549441B (zh) * | 2008-04-01 | 2011-06-29 | 东莞市中实焊锡有限公司 | 一种无铅焊料 |
CN101618485B (zh) * | 2009-08-03 | 2011-10-19 | 浙江强力焊锡材料有限公司 | 无铅钎料 |
CN102489892A (zh) * | 2010-12-31 | 2012-06-13 | 广东中实金属有限公司 | 一种含Cr的SnZn基无铅钎料 |
CN102489893A (zh) * | 2010-12-31 | 2012-06-13 | 广东中实金属有限公司 | 一种SnZn基无铅钎料合金 |
CN102500949A (zh) * | 2011-11-03 | 2012-06-20 | 吉林大学 | 一种钎焊铜和钢的中温锌基钎料及其制备方法 |
CN101585120B (zh) * | 2009-06-29 | 2012-08-22 | 铜陵森泰金属材料有限公司 | 一种锡锌基无铅钎料合金 |
CN102642099A (zh) * | 2012-05-05 | 2012-08-22 | 大连理工大学 | 一种用于铝铜软钎焊的Sn-Zn基无铅钎料合金及其制备方法 |
CN103801852A (zh) * | 2012-11-12 | 2014-05-21 | 恒硕科技股份有限公司 | 高强度无银无铅焊锡 |
CN106425154A (zh) * | 2016-11-29 | 2017-02-22 | 东莞市广信知识产权服务有限公司 | 无铅钎料 |
CN106493483A (zh) * | 2016-11-30 | 2017-03-15 | 安徽华众焊业有限公司 | 低温无铅锡膏 |
CN108300896A (zh) * | 2017-12-21 | 2018-07-20 | 柳州智臻智能机械有限公司 | 一种含有稀土元素的焊料合金及其制备方法 |
JPWO2021010199A1 (zh) * | 2019-07-12 | 2021-01-21 | ||
CN114799612A (zh) * | 2022-05-27 | 2022-07-29 | 常州时创能源股份有限公司 | 一种光伏用钎焊焊料、其制备方法及应用 |
TWI782572B (zh) * | 2020-06-16 | 2022-11-01 | 日商亞特比目有限公司 | SnZn銲料及其製造方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR19980068127A (ko) * | 1997-02-15 | 1998-10-15 | 김광호 | 납땜용 무연 합금 |
CN1175956C (zh) * | 2002-05-10 | 2004-11-17 | 大连理工大学 | 锡锌基含稀土元素的无铅钎料合金 |
CN1152768C (zh) * | 2002-07-02 | 2004-06-09 | 北京工业大学 | 高蠕变抗力含稀土锡基无铅钎料及其制备方法 |
JP2005193294A (ja) * | 2004-01-09 | 2005-07-21 | Sony Corp | 無鉛はんだ |
CN100364712C (zh) * | 2004-12-17 | 2008-01-30 | 北京工业大学 | 含稀土Er的SnZn基无铅钎料 |
CN1730696A (zh) * | 2005-08-05 | 2006-02-08 | 大连理工大学 | 锡锌铜镍无铅钎料合金 |
-
2006
- 2006-04-30 CN CNB2006100780386A patent/CN100462183C/zh not_active Expired - Fee Related
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101380700B (zh) * | 2007-09-05 | 2011-04-20 | 北京康普锡威科技有限公司 | 一种锡铋铜系无铅焊料及其制备方法 |
CN101549441B (zh) * | 2008-04-01 | 2011-06-29 | 东莞市中实焊锡有限公司 | 一种无铅焊料 |
CN101585120B (zh) * | 2009-06-29 | 2012-08-22 | 铜陵森泰金属材料有限公司 | 一种锡锌基无铅钎料合金 |
CN101618485B (zh) * | 2009-08-03 | 2011-10-19 | 浙江强力焊锡材料有限公司 | 无铅钎料 |
CN102489892A (zh) * | 2010-12-31 | 2012-06-13 | 广东中实金属有限公司 | 一种含Cr的SnZn基无铅钎料 |
CN102489893A (zh) * | 2010-12-31 | 2012-06-13 | 广东中实金属有限公司 | 一种SnZn基无铅钎料合金 |
CN102500949A (zh) * | 2011-11-03 | 2012-06-20 | 吉林大学 | 一种钎焊铜和钢的中温锌基钎料及其制备方法 |
CN102642099A (zh) * | 2012-05-05 | 2012-08-22 | 大连理工大学 | 一种用于铝铜软钎焊的Sn-Zn基无铅钎料合金及其制备方法 |
CN103801852A (zh) * | 2012-11-12 | 2014-05-21 | 恒硕科技股份有限公司 | 高强度无银无铅焊锡 |
CN106425154A (zh) * | 2016-11-29 | 2017-02-22 | 东莞市广信知识产权服务有限公司 | 无铅钎料 |
CN106493483A (zh) * | 2016-11-30 | 2017-03-15 | 安徽华众焊业有限公司 | 低温无铅锡膏 |
CN108300896A (zh) * | 2017-12-21 | 2018-07-20 | 柳州智臻智能机械有限公司 | 一种含有稀土元素的焊料合金及其制备方法 |
JPWO2021010199A1 (zh) * | 2019-07-12 | 2021-01-21 | ||
TWI817020B (zh) * | 2019-07-12 | 2023-10-01 | 日商亞特比目有限公司 | SnZn焊料及其製造方法 |
TWI782572B (zh) * | 2020-06-16 | 2022-11-01 | 日商亞特比目有限公司 | SnZn銲料及其製造方法 |
CN114799612A (zh) * | 2022-05-27 | 2022-07-29 | 常州时创能源股份有限公司 | 一种光伏用钎焊焊料、其制备方法及应用 |
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