CN1697691A - 铁氧化物基催化剂、其制备方法及其在脱氢方法中的应用 - Google Patents
铁氧化物基催化剂、其制备方法及其在脱氢方法中的应用 Download PDFInfo
- Publication number
- CN1697691A CN1697691A CNA038030365A CN03803036A CN1697691A CN 1697691 A CN1697691 A CN 1697691A CN A038030365 A CNA038030365 A CN A038030365A CN 03803036 A CN03803036 A CN 03803036A CN 1697691 A CN1697691 A CN 1697691A
- Authority
- CN
- China
- Prior art keywords
- catalyst
- mol
- iron oxide
- iron
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35358602P | 2002-01-30 | 2002-01-30 | |
| US60/353,586 | 2002-01-30 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102140120A Division CN102343268A (zh) | 2002-01-30 | 2003-01-30 | 铁氧化物基催化剂、其制备方法及其在脱氢方法中的应用 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1697691A true CN1697691A (zh) | 2005-11-16 |
Family
ID=27663225
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA038030365A Pending CN1697691A (zh) | 2002-01-30 | 2003-01-30 | 铁氧化物基催化剂、其制备方法及其在脱氢方法中的应用 |
| CN2011102140120A Pending CN102343268A (zh) | 2002-01-30 | 2003-01-30 | 铁氧化物基催化剂、其制备方法及其在脱氢方法中的应用 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102140120A Pending CN102343268A (zh) | 2002-01-30 | 2003-01-30 | 铁氧化物基催化剂、其制备方法及其在脱氢方法中的应用 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7435703B2 (https=) |
| EP (1) | EP1471999B1 (https=) |
| JP (1) | JP4308665B2 (https=) |
| KR (1) | KR100945966B1 (https=) |
| CN (2) | CN1697691A (https=) |
| AR (1) | AR038321A1 (https=) |
| AT (1) | ATE356661T1 (https=) |
| AU (1) | AU2003210745B2 (https=) |
| BR (1) | BR0307214A (https=) |
| CA (1) | CA2474607A1 (https=) |
| DE (1) | DE60312484T2 (https=) |
| MX (1) | MXPA04007296A (https=) |
| RU (1) | RU2302290C2 (https=) |
| TW (1) | TWI267401B (https=) |
| WO (1) | WO2003064032A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101626834B (zh) * | 2007-01-18 | 2012-09-26 | 国际壳牌研究有限公司 | 催化剂及其制备和用途 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI267401B (en) | 2002-01-30 | 2006-12-01 | Shell Int Research | A catalyst, its preparation and its use in a dehydrogenation process |
| US7282619B2 (en) | 2003-10-14 | 2007-10-16 | Shell Oil Company | Method of operating a dehydrogenation reactor system |
| US7297402B2 (en) * | 2004-04-15 | 2007-11-20 | Shell Oil Company | Shaped particle having an asymmetrical cross sectional geometry |
| US20060020152A1 (en) * | 2004-07-22 | 2006-01-26 | Theobald Eugene H | Method for the low temperature selective oxidation of hydrogen contained in a hydrocarbon stream |
| CN101072632A (zh) * | 2004-11-18 | 2007-11-14 | 国际壳牌研究有限公司 | 脱氢方法 |
| RU2385313C2 (ru) * | 2004-11-18 | 2010-03-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Улучшенный способ получения алкенилароматического соединения при низком отношении пар/углеводород |
| RU2379105C2 (ru) | 2004-11-18 | 2010-01-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Высокоактивный и высокостабильный катализатор дегидрирования на основе оксида железа с низкой концентрацией титана, и его получение и применение |
| CN100391605C (zh) * | 2005-01-26 | 2008-06-04 | 中国石油化工股份有限公司 | 用于制备烷烯基芳烃的脱氢催化剂 |
| US20060224029A1 (en) * | 2005-03-29 | 2006-10-05 | Fina Technology, Inc. | Method of extending catalyst life in vinyl aromatic hydrocarbon formation |
| WO2007009927A1 (de) * | 2005-07-22 | 2007-01-25 | Basf Aktiengesellschaft | Katalysator zur dehydrierung oder hydrierung von kohlenwasserstoffen enthaltend sekundäres katalysatormaterial |
| JP2009508860A (ja) * | 2005-09-16 | 2009-03-05 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 芳香族生成物を作製する方法 |
| US20070189989A1 (en) * | 2006-02-16 | 2007-08-16 | Cantwell Maggie Y | Cosmetic compositions and methods of making and using the compositions |
| AR065023A1 (es) * | 2007-01-30 | 2009-05-13 | Shell Int Research | Un catalizador de deshidrogenacion, su proceso de preparacion y su metodo de uso |
| BRPI0810223A2 (pt) * | 2007-05-03 | 2014-10-29 | Shell Int Research | Catalisador de desidrogenação e, processos para preparar o mesmo, e para desidrogenar um hidrocarboneto desidrogenável. |
| EP2152412A2 (en) * | 2007-05-03 | 2010-02-17 | Shell Internationale Research Maatschappij B.V. | A catalyst, its preparation and use |
| EP2175989A4 (en) * | 2007-08-10 | 2012-02-01 | Rentech Inc | EXCESSED IRON CATALYST FOR HYDROGENATION OF CARBON MONOXIDE |
| US20100022816A1 (en) * | 2008-07-22 | 2010-01-28 | Fina Technology, Inc. | Dehydrogenation of Methylbutenes to Isoprene |
| US8905259B2 (en) | 2010-08-12 | 2014-12-09 | Holtec International, Inc. | Ventilated system for storing high level radioactive waste |
| RU2629195C2 (ru) * | 2011-12-22 | 2017-08-25 | Басф Се | Катализатор для дегидрирования углеводородов |
| US11820658B2 (en) * | 2021-01-04 | 2023-11-21 | Saudi Arabian Oil Company | Black powder catalyst for hydrogen production via autothermal reforming |
| KR20240151410A (ko) | 2023-04-11 | 2024-10-18 | 한국과학기술연구원 | 철산화물-금속이중층수산화물 복합체 및 그 제조방법 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1368748A (en) * | 1920-01-05 | 1921-02-15 | Nat Ferrite Company | Process of manufacturing iron compounds and product |
| FR2592375B1 (fr) * | 1985-12-27 | 1988-04-08 | Shell Int Research | Procede de deshydrogenation sans oxydation |
| US4822936A (en) * | 1987-08-25 | 1989-04-18 | The Dow Chemical Company | Selective hydrogenation of phenylacetylene in the presence of styrene |
| SU1515471A1 (ru) * | 1987-10-19 | 1996-04-27 | Г.Р. Котельников | Способ приготовления катализатора для дегидрирования алкилароматических и олефиновых углеводородов |
| US5023225A (en) * | 1989-07-21 | 1991-06-11 | United Catalysts Inc. | Dehydrogenation catalyst and process for its preparation |
| US5156816A (en) * | 1990-10-04 | 1992-10-20 | Fina Technology, Inc. | System for purifying styrene monomer feedstock using ethylbenzene dehydrogenation waste gas |
| JPH04277030A (ja) * | 1991-03-05 | 1992-10-02 | Nissan Gaadoraa Shokubai Kk | エチルベンゼン脱水素触媒 |
| US5171914A (en) * | 1991-08-30 | 1992-12-15 | Shell Oil Company | Dehydrogenation catalyst and process |
| BR9107322A (pt) * | 1991-10-10 | 1996-01-02 | Dow Chemical Co | Processo para a hidrogenação seletiva de composto s de acetileno aromático |
| US5461179A (en) * | 1993-07-07 | 1995-10-24 | Raytheon Engineers & Constructors, Inc. | Regeneration and stabilization of dehydrogenation catalysts |
| JPH07178340A (ja) * | 1993-11-11 | 1995-07-18 | Idemitsu Petrochem Co Ltd | アルキル芳香族炭化水素の脱水素反応用触媒及びこれを用いたビニル芳香族炭化水素の製造方法 |
| US5401485A (en) * | 1994-03-15 | 1995-03-28 | Shell Oil Company | Reduction of residual chloride in iron oxides |
| JPH10510524A (ja) * | 1994-12-14 | 1998-10-13 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 大粒子の脱水素化触媒および方法 |
| EP0797481B1 (en) * | 1994-12-14 | 2000-08-30 | Shell Internationale Researchmaatschappij B.V. | Restructured iron oxide |
| US5597547A (en) * | 1995-04-13 | 1997-01-28 | Shell Oil Company | Reduction of residual chloride in iron oxides |
| IT1283207B1 (it) * | 1996-03-08 | 1998-04-16 | Montecatini Tecnologie Srl | Catalizzatori per la deidrogenazione di etilbenzene a stirene |
| EP0850881B1 (de) * | 1996-12-27 | 2002-08-21 | Ruthner, Michael Johann, Dipl.Ing. Dr.mont. | Verfahren und Vorrichtung zur Herstellung von Eisenoxiden aus salzsauren eisenchloridhaltigen Lösungen |
| IT1293531B1 (it) | 1997-08-01 | 1999-03-01 | Sud Chemie Mt S R L Ex Monteca | Catalizzatori per la deidrogenazione dell'etilbenzene a stirene |
| DE19814080A1 (de) * | 1998-03-30 | 1999-10-07 | Basf Ag | Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung |
| US6242379B1 (en) * | 1998-04-01 | 2001-06-05 | United Catalysts Inc. | Dehydrogenation catalysts |
| DE50012271D1 (de) | 1999-02-10 | 2006-04-27 | Basf Ag | Katalysator zur Dehydrierung von Ethylbenzol zu Styrol |
| EP1379470B9 (de) | 2001-04-10 | 2012-05-02 | Basf Se | Eisenoxide mit höherem veredelungsgrad |
| TWI267401B (en) | 2002-01-30 | 2006-12-01 | Shell Int Research | A catalyst, its preparation and its use in a dehydrogenation process |
-
2003
- 2003-01-23 TW TW092101474A patent/TWI267401B/zh not_active IP Right Cessation
- 2003-01-28 AR ARP030100238A patent/AR038321A1/es active IP Right Grant
- 2003-01-28 US US10/352,819 patent/US7435703B2/en not_active Expired - Lifetime
- 2003-01-30 AU AU2003210745A patent/AU2003210745B2/en not_active Ceased
- 2003-01-30 CA CA002474607A patent/CA2474607A1/en not_active Abandoned
- 2003-01-30 AT AT03735084T patent/ATE356661T1/de not_active IP Right Cessation
- 2003-01-30 BR BR0307214-2A patent/BR0307214A/pt not_active Application Discontinuation
- 2003-01-30 JP JP2003563713A patent/JP4308665B2/ja not_active Expired - Lifetime
- 2003-01-30 WO PCT/US2003/002779 patent/WO2003064032A1/en not_active Ceased
- 2003-01-30 DE DE60312484T patent/DE60312484T2/de not_active Expired - Lifetime
- 2003-01-30 EP EP03735084A patent/EP1471999B1/en not_active Expired - Lifetime
- 2003-01-30 CN CNA038030365A patent/CN1697691A/zh active Pending
- 2003-01-30 MX MXPA04007296A patent/MXPA04007296A/es not_active Application Discontinuation
- 2003-01-30 CN CN2011102140120A patent/CN102343268A/zh active Pending
- 2003-01-30 KR KR1020047011570A patent/KR100945966B1/ko not_active Expired - Fee Related
- 2003-01-30 RU RU2004126240/04A patent/RU2302290C2/ru not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101626834B (zh) * | 2007-01-18 | 2012-09-26 | 国际壳牌研究有限公司 | 催化剂及其制备和用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005515886A (ja) | 2005-06-02 |
| US7435703B2 (en) | 2008-10-14 |
| DE60312484D1 (de) | 2007-04-26 |
| BR0307214A (pt) | 2004-12-07 |
| WO2003064032A1 (en) | 2003-08-07 |
| EP1471999B1 (en) | 2007-03-14 |
| CN102343268A (zh) | 2012-02-08 |
| US20030144566A1 (en) | 2003-07-31 |
| RU2004126240A (ru) | 2006-01-27 |
| DE60312484T2 (de) | 2007-12-13 |
| AU2003210745B2 (en) | 2008-10-23 |
| ATE356661T1 (de) | 2007-04-15 |
| JP4308665B2 (ja) | 2009-08-05 |
| RU2302290C2 (ru) | 2007-07-10 |
| KR100945966B1 (ko) | 2010-03-09 |
| MXPA04007296A (es) | 2004-10-29 |
| EP1471999A1 (en) | 2004-11-03 |
| KR20040077807A (ko) | 2004-09-06 |
| AR038321A1 (es) | 2005-01-12 |
| TWI267401B (en) | 2006-12-01 |
| CA2474607A1 (en) | 2003-08-07 |
| TW200302131A (en) | 2003-08-01 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20051116 |