AU2003210745B2 - Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process - Google Patents

Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process Download PDF

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Publication number
AU2003210745B2
AU2003210745B2 AU2003210745A AU2003210745A AU2003210745B2 AU 2003210745 B2 AU2003210745 B2 AU 2003210745B2 AU 2003210745 A AU2003210745 A AU 2003210745A AU 2003210745 A AU2003210745 A AU 2003210745A AU 2003210745 B2 AU2003210745 B2 AU 2003210745B2
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AU
Australia
Prior art keywords
catalyst
iron oxide
mole
compound
calculated
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Ceased
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AU2003210745A
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AU2003210745A1 (en
Inventor
Robert Dielman Culp
Eugene Harry Theobald
Sarah Louise Weaver
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Shell Internationale Research Maatschappij BV
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SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AU2003210745A 2002-01-30 2003-01-30 Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process Ceased AU2003210745B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US35358602P 2002-01-30 2002-01-30
US60/353,586 2002-01-30
PCT/US2003/002779 WO2003064032A1 (en) 2002-01-30 2003-01-30 Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process

Publications (2)

Publication Number Publication Date
AU2003210745A1 AU2003210745A1 (en) 2003-09-18
AU2003210745B2 true AU2003210745B2 (en) 2008-10-23

Family

ID=27663225

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2003210745A Ceased AU2003210745B2 (en) 2002-01-30 2003-01-30 Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process

Country Status (15)

Country Link
US (1) US7435703B2 (https=)
EP (1) EP1471999B1 (https=)
JP (1) JP4308665B2 (https=)
KR (1) KR100945966B1 (https=)
CN (2) CN1697691A (https=)
AR (1) AR038321A1 (https=)
AT (1) ATE356661T1 (https=)
AU (1) AU2003210745B2 (https=)
BR (1) BR0307214A (https=)
CA (1) CA2474607A1 (https=)
DE (1) DE60312484T2 (https=)
MX (1) MXPA04007296A (https=)
RU (1) RU2302290C2 (https=)
TW (1) TWI267401B (https=)
WO (1) WO2003064032A1 (https=)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
US12559369B2 (en) * 2021-01-04 2026-02-24 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via autothermal reforming

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TWI267401B (en) 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7282619B2 (en) 2003-10-14 2007-10-16 Shell Oil Company Method of operating a dehydrogenation reactor system
US7297402B2 (en) * 2004-04-15 2007-11-20 Shell Oil Company Shaped particle having an asymmetrical cross sectional geometry
US20060020152A1 (en) * 2004-07-22 2006-01-26 Theobald Eugene H Method for the low temperature selective oxidation of hydrogen contained in a hydrocarbon stream
CN101072632A (zh) * 2004-11-18 2007-11-14 国际壳牌研究有限公司 脱氢方法
RU2385313C2 (ru) * 2004-11-18 2010-03-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Улучшенный способ получения алкенилароматического соединения при низком отношении пар/углеводород
RU2379105C2 (ru) 2004-11-18 2010-01-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Высокоактивный и высокостабильный катализатор дегидрирования на основе оксида железа с низкой концентрацией титана, и его получение и применение
CN100391605C (zh) * 2005-01-26 2008-06-04 中国石油化工股份有限公司 用于制备烷烯基芳烃的脱氢催化剂
US20060224029A1 (en) * 2005-03-29 2006-10-05 Fina Technology, Inc. Method of extending catalyst life in vinyl aromatic hydrocarbon formation
WO2007009927A1 (de) * 2005-07-22 2007-01-25 Basf Aktiengesellschaft Katalysator zur dehydrierung oder hydrierung von kohlenwasserstoffen enthaltend sekundäres katalysatormaterial
JP2009508860A (ja) * 2005-09-16 2009-03-05 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 芳香族生成物を作製する方法
US20070189989A1 (en) * 2006-02-16 2007-08-16 Cantwell Maggie Y Cosmetic compositions and methods of making and using the compositions
EP2104563A1 (en) * 2007-01-18 2009-09-30 Shell Internationale Research Maatschappij B.V. A catalyst, its preparation and use
AR065023A1 (es) * 2007-01-30 2009-05-13 Shell Int Research Un catalizador de deshidrogenacion, su proceso de preparacion y su metodo de uso
BRPI0810223A2 (pt) * 2007-05-03 2014-10-29 Shell Int Research Catalisador de desidrogenação e, processos para preparar o mesmo, e para desidrogenar um hidrocarboneto desidrogenável.
EP2152412A2 (en) * 2007-05-03 2010-02-17 Shell Internationale Research Maatschappij B.V. A catalyst, its preparation and use
EP2175989A4 (en) * 2007-08-10 2012-02-01 Rentech Inc EXCESSED IRON CATALYST FOR HYDROGENATION OF CARBON MONOXIDE
US20100022816A1 (en) * 2008-07-22 2010-01-28 Fina Technology, Inc. Dehydrogenation of Methylbutenes to Isoprene
US8905259B2 (en) 2010-08-12 2014-12-09 Holtec International, Inc. Ventilated system for storing high level radioactive waste
RU2629195C2 (ru) * 2011-12-22 2017-08-25 Басф Се Катализатор для дегидрирования углеводородов
KR20240151410A (ko) 2023-04-11 2024-10-18 한국과학기술연구원 철산화물-금속이중층수산화물 복합체 및 그 제조방법

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US5190906A (en) * 1991-03-05 1993-03-02 Nissan Girdler Catalyst Co., Ltd. Alkyl aromatic hydrocarbon dehydrogenation catalyst and method for producing the catalyst
EP1027928A1 (de) * 1999-02-10 2000-08-16 Basf Aktiengesellschaft Katalysator zur Dehydrierung von Ethylbenzol zu Styrol

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12559369B2 (en) * 2021-01-04 2026-02-24 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via autothermal reforming

Also Published As

Publication number Publication date
JP2005515886A (ja) 2005-06-02
US7435703B2 (en) 2008-10-14
DE60312484D1 (de) 2007-04-26
BR0307214A (pt) 2004-12-07
WO2003064032A1 (en) 2003-08-07
EP1471999B1 (en) 2007-03-14
CN102343268A (zh) 2012-02-08
US20030144566A1 (en) 2003-07-31
RU2004126240A (ru) 2006-01-27
DE60312484T2 (de) 2007-12-13
ATE356661T1 (de) 2007-04-15
JP4308665B2 (ja) 2009-08-05
RU2302290C2 (ru) 2007-07-10
KR100945966B1 (ko) 2010-03-09
MXPA04007296A (es) 2004-10-29
CN1697691A (zh) 2005-11-16
EP1471999A1 (en) 2004-11-03
KR20040077807A (ko) 2004-09-06
AR038321A1 (es) 2005-01-12
TWI267401B (en) 2006-12-01
CA2474607A1 (en) 2003-08-07
TW200302131A (en) 2003-08-01

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MK14 Patent ceased section 143(a) (annual fees not paid) or expired