RU2302290C2 - Катализатор на основе оксида железа, его получение и применение в процессе дегидрирования - Google Patents

Катализатор на основе оксида железа, его получение и применение в процессе дегидрирования Download PDF

Info

Publication number
RU2302290C2
RU2302290C2 RU2004126240/04A RU2004126240A RU2302290C2 RU 2302290 C2 RU2302290 C2 RU 2302290C2 RU 2004126240/04 A RU2004126240/04 A RU 2004126240/04A RU 2004126240 A RU2004126240 A RU 2004126240A RU 2302290 C2 RU2302290 C2 RU 2302290C2
Authority
RU
Russia
Prior art keywords
iron oxide
catalyst
mol
compound
amount
Prior art date
Application number
RU2004126240/04A
Other languages
English (en)
Russian (ru)
Other versions
RU2004126240A (ru
Inventor
Роберт Дилман КАЛП (US)
Роберт Дилман КАЛП
Юджин Харри ТЕОБАЛД (US)
Юджин Харри ТЕОБАЛД
Сара Луиз ВИВЕР (US)
Сара Луиз ВИВЕР
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of RU2004126240A publication Critical patent/RU2004126240A/ru
Application granted granted Critical
Publication of RU2302290C2 publication Critical patent/RU2302290C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
RU2004126240/04A 2002-01-30 2003-01-30 Катализатор на основе оксида железа, его получение и применение в процессе дегидрирования RU2302290C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35358602P 2002-01-30 2002-01-30
US60/353,586 2002-01-30

Publications (2)

Publication Number Publication Date
RU2004126240A RU2004126240A (ru) 2006-01-27
RU2302290C2 true RU2302290C2 (ru) 2007-07-10

Family

ID=27663225

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2004126240/04A RU2302290C2 (ru) 2002-01-30 2003-01-30 Катализатор на основе оксида железа, его получение и применение в процессе дегидрирования

Country Status (15)

Country Link
US (1) US7435703B2 (https=)
EP (1) EP1471999B1 (https=)
JP (1) JP4308665B2 (https=)
KR (1) KR100945966B1 (https=)
CN (2) CN1697691A (https=)
AR (1) AR038321A1 (https=)
AT (1) ATE356661T1 (https=)
AU (1) AU2003210745B2 (https=)
BR (1) BR0307214A (https=)
CA (1) CA2474607A1 (https=)
DE (1) DE60312484T2 (https=)
MX (1) MXPA04007296A (https=)
RU (1) RU2302290C2 (https=)
TW (1) TWI267401B (https=)
WO (1) WO2003064032A1 (https=)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI267401B (en) 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7282619B2 (en) 2003-10-14 2007-10-16 Shell Oil Company Method of operating a dehydrogenation reactor system
US7297402B2 (en) * 2004-04-15 2007-11-20 Shell Oil Company Shaped particle having an asymmetrical cross sectional geometry
US20060020152A1 (en) * 2004-07-22 2006-01-26 Theobald Eugene H Method for the low temperature selective oxidation of hydrogen contained in a hydrocarbon stream
CN101072632A (zh) * 2004-11-18 2007-11-14 国际壳牌研究有限公司 脱氢方法
RU2385313C2 (ru) * 2004-11-18 2010-03-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Улучшенный способ получения алкенилароматического соединения при низком отношении пар/углеводород
RU2379105C2 (ru) 2004-11-18 2010-01-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Высокоактивный и высокостабильный катализатор дегидрирования на основе оксида железа с низкой концентрацией титана, и его получение и применение
CN100391605C (zh) * 2005-01-26 2008-06-04 中国石油化工股份有限公司 用于制备烷烯基芳烃的脱氢催化剂
US20060224029A1 (en) * 2005-03-29 2006-10-05 Fina Technology, Inc. Method of extending catalyst life in vinyl aromatic hydrocarbon formation
WO2007009927A1 (de) * 2005-07-22 2007-01-25 Basf Aktiengesellschaft Katalysator zur dehydrierung oder hydrierung von kohlenwasserstoffen enthaltend sekundäres katalysatormaterial
JP2009508860A (ja) * 2005-09-16 2009-03-05 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 芳香族生成物を作製する方法
US20070189989A1 (en) * 2006-02-16 2007-08-16 Cantwell Maggie Y Cosmetic compositions and methods of making and using the compositions
EP2104563A1 (en) * 2007-01-18 2009-09-30 Shell Internationale Research Maatschappij B.V. A catalyst, its preparation and use
AR065023A1 (es) * 2007-01-30 2009-05-13 Shell Int Research Un catalizador de deshidrogenacion, su proceso de preparacion y su metodo de uso
BRPI0810223A2 (pt) * 2007-05-03 2014-10-29 Shell Int Research Catalisador de desidrogenação e, processos para preparar o mesmo, e para desidrogenar um hidrocarboneto desidrogenável.
EP2152412A2 (en) * 2007-05-03 2010-02-17 Shell Internationale Research Maatschappij B.V. A catalyst, its preparation and use
EP2175989A4 (en) * 2007-08-10 2012-02-01 Rentech Inc EXCESSED IRON CATALYST FOR HYDROGENATION OF CARBON MONOXIDE
US20100022816A1 (en) * 2008-07-22 2010-01-28 Fina Technology, Inc. Dehydrogenation of Methylbutenes to Isoprene
US8905259B2 (en) 2010-08-12 2014-12-09 Holtec International, Inc. Ventilated system for storing high level radioactive waste
RU2629195C2 (ru) * 2011-12-22 2017-08-25 Басф Се Катализатор для дегидрирования углеводородов
US11820658B2 (en) * 2021-01-04 2023-11-21 Saudi Arabian Oil Company Black powder catalyst for hydrogen production via autothermal reforming
KR20240151410A (ko) 2023-04-11 2024-10-18 한국과학기술연구원 철산화물-금속이중층수산화물 복합체 및 그 제조방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5190906A (en) * 1991-03-05 1993-03-02 Nissan Girdler Catalyst Co., Ltd. Alkyl aromatic hydrocarbon dehydrogenation catalyst and method for producing the catalyst
SU1515471A1 (ru) * 1987-10-19 1996-04-27 Г.Р. Котельников Способ приготовления катализатора для дегидрирования алкилароматических и олефиновых углеводородов
RU2139846C1 (ru) * 1993-07-07 1999-10-20 Рейзион Енджиниэз энд Кэнстрактэз, Инк. Способ дегидрирования алкилароматического углеводорода в алкенилароматический углеводород, способ регенерации и стабилизации активности железоокисного катализатора и установка дегидрирования алкилароматических углеводородов
EP1027928A1 (de) * 1999-02-10 2000-08-16 Basf Aktiengesellschaft Katalysator zur Dehydrierung von Ethylbenzol zu Styrol

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1368748A (en) * 1920-01-05 1921-02-15 Nat Ferrite Company Process of manufacturing iron compounds and product
FR2592375B1 (fr) * 1985-12-27 1988-04-08 Shell Int Research Procede de deshydrogenation sans oxydation
US4822936A (en) * 1987-08-25 1989-04-18 The Dow Chemical Company Selective hydrogenation of phenylacetylene in the presence of styrene
US5023225A (en) * 1989-07-21 1991-06-11 United Catalysts Inc. Dehydrogenation catalyst and process for its preparation
US5156816A (en) * 1990-10-04 1992-10-20 Fina Technology, Inc. System for purifying styrene monomer feedstock using ethylbenzene dehydrogenation waste gas
US5171914A (en) * 1991-08-30 1992-12-15 Shell Oil Company Dehydrogenation catalyst and process
BR9107322A (pt) * 1991-10-10 1996-01-02 Dow Chemical Co Processo para a hidrogenação seletiva de composto s de acetileno aromático
JPH07178340A (ja) * 1993-11-11 1995-07-18 Idemitsu Petrochem Co Ltd アルキル芳香族炭化水素の脱水素反応用触媒及びこれを用いたビニル芳香族炭化水素の製造方法
US5401485A (en) * 1994-03-15 1995-03-28 Shell Oil Company Reduction of residual chloride in iron oxides
JPH10510524A (ja) * 1994-12-14 1998-10-13 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 大粒子の脱水素化触媒および方法
EP0797481B1 (en) * 1994-12-14 2000-08-30 Shell Internationale Researchmaatschappij B.V. Restructured iron oxide
US5597547A (en) * 1995-04-13 1997-01-28 Shell Oil Company Reduction of residual chloride in iron oxides
IT1283207B1 (it) * 1996-03-08 1998-04-16 Montecatini Tecnologie Srl Catalizzatori per la deidrogenazione di etilbenzene a stirene
EP0850881B1 (de) * 1996-12-27 2002-08-21 Ruthner, Michael Johann, Dipl.Ing. Dr.mont. Verfahren und Vorrichtung zur Herstellung von Eisenoxiden aus salzsauren eisenchloridhaltigen Lösungen
IT1293531B1 (it) 1997-08-01 1999-03-01 Sud Chemie Mt S R L Ex Monteca Catalizzatori per la deidrogenazione dell'etilbenzene a stirene
DE19814080A1 (de) * 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung
US6242379B1 (en) * 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
EP1379470B9 (de) 2001-04-10 2012-05-02 Basf Se Eisenoxide mit höherem veredelungsgrad
TWI267401B (en) 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1515471A1 (ru) * 1987-10-19 1996-04-27 Г.Р. Котельников Способ приготовления катализатора для дегидрирования алкилароматических и олефиновых углеводородов
US5190906A (en) * 1991-03-05 1993-03-02 Nissan Girdler Catalyst Co., Ltd. Alkyl aromatic hydrocarbon dehydrogenation catalyst and method for producing the catalyst
RU2139846C1 (ru) * 1993-07-07 1999-10-20 Рейзион Енджиниэз энд Кэнстрактэз, Инк. Способ дегидрирования алкилароматического углеводорода в алкенилароматический углеводород, способ регенерации и стабилизации активности железоокисного катализатора и установка дегидрирования алкилароматических углеводородов
EP1027928A1 (de) * 1999-02-10 2000-08-16 Basf Aktiengesellschaft Katalysator zur Dehydrierung von Ethylbenzol zu Styrol

Also Published As

Publication number Publication date
JP2005515886A (ja) 2005-06-02
US7435703B2 (en) 2008-10-14
DE60312484D1 (de) 2007-04-26
BR0307214A (pt) 2004-12-07
WO2003064032A1 (en) 2003-08-07
EP1471999B1 (en) 2007-03-14
CN102343268A (zh) 2012-02-08
US20030144566A1 (en) 2003-07-31
RU2004126240A (ru) 2006-01-27
DE60312484T2 (de) 2007-12-13
AU2003210745B2 (en) 2008-10-23
ATE356661T1 (de) 2007-04-15
JP4308665B2 (ja) 2009-08-05
KR100945966B1 (ko) 2010-03-09
MXPA04007296A (es) 2004-10-29
CN1697691A (zh) 2005-11-16
EP1471999A1 (en) 2004-11-03
KR20040077807A (ko) 2004-09-06
AR038321A1 (es) 2005-01-12
TWI267401B (en) 2006-12-01
CA2474607A1 (en) 2003-08-07
TW200302131A (en) 2003-08-01

Similar Documents

Publication Publication Date Title
RU2302290C2 (ru) Катализатор на основе оксида железа, его получение и применение в процессе дегидрирования
US20080207858A1 (en) Catalyst, its preparation and use
AU2003210745A1 (en) Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process
US7713498B2 (en) Manufacturing plant for the dehydrogenation of an unsaturated hydrocarbon
WO2008137583A2 (en) A catalyst, its preparation and use
US20080200632A1 (en) Catalyst, its preparation and use
EP2158036A2 (en) A catalyst, its preparation and use

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20120131