BR0307214A - Catalisador baseado em ferro, sua preparação e seu uso em um processo de desidrogenação - Google Patents

Catalisador baseado em ferro, sua preparação e seu uso em um processo de desidrogenação

Info

Publication number
BR0307214A
BR0307214A BR0307214-2A BR0307214A BR0307214A BR 0307214 A BR0307214 A BR 0307214A BR 0307214 A BR0307214 A BR 0307214A BR 0307214 A BR0307214 A BR 0307214A
Authority
BR
Brazil
Prior art keywords
catalyst
compound
preparation
iron
iron oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
BR0307214-2A
Other languages
English (en)
Inventor
Robert Dielman Culp
Eugene Harry Theobald
Sarah Louise Weaver
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INTERNATIONALE RESEARCH MAASCHAPPIJ BV
SHELL INTERNATIONALE RES MAASC
Original Assignee
SHELL INTERNATIONALE RESEARCH MAASCHAPPIJ B.V
SHELL INTERNATIONALE RES MAASC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INTERNATIONALE RESEARCH MAASCHAPPIJ B.V, SHELL INTERNATIONALE RES MAASC filed Critical SHELL INTERNATIONALE RESEARCH MAASCHAPPIJ B.V
Publication of BR0307214A publication Critical patent/BR0307214A/pt
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"CATALISADOR BASEADO EM FERRO, SUA PREPARAçãO E SEU USO EM UM PROCESSO DE DESIDROGENAçãO". Um catalisador que é baseado em um óxido de ferro e um composto de um lantanídeo, do qual pelo menos uma porção de óxido de ferro é feita por um processo que envolve decomposição por aquecimento de um haleto de ferro, o lantanídeo sendo em uma quantidade na faixa de 0,07 a 0,15 mol por mol de óxido de ferro presente no catalisador, calculada como Fe~ 2~0~ 3~; um processo para a preparação do catalisador; um processo para a desidrogenação de um composto alquilaromático cujo processo envolve contatar um mecanismo alimentador contendo o composto alquilaromático com o catalisador; e um método de usar um composto alquenilaromático para preparar polímeros ou copolímeros, em cujo método o composto alquenilaromático foi preparado pelo processo de desidrogenação.
BR0307214-2A 2002-01-30 2003-01-30 Catalisador baseado em ferro, sua preparação e seu uso em um processo de desidrogenação Pending BR0307214A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US35358602P 2002-01-30 2002-01-30
PCT/US2003/002779 WO2003064032A1 (en) 2002-01-30 2003-01-30 Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process

Publications (1)

Publication Number Publication Date
BR0307214A true BR0307214A (pt) 2004-12-07

Family

ID=27663225

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0307214-2A Pending BR0307214A (pt) 2002-01-30 2003-01-30 Catalisador baseado em ferro, sua preparação e seu uso em um processo de desidrogenação

Country Status (15)

Country Link
US (1) US7435703B2 (pt)
EP (1) EP1471999B1 (pt)
JP (1) JP4308665B2 (pt)
KR (1) KR100945966B1 (pt)
CN (2) CN102343268A (pt)
AR (1) AR038321A1 (pt)
AT (1) ATE356661T1 (pt)
AU (1) AU2003210745B2 (pt)
BR (1) BR0307214A (pt)
CA (1) CA2474607A1 (pt)
DE (1) DE60312484T2 (pt)
MX (1) MXPA04007296A (pt)
RU (1) RU2302290C2 (pt)
TW (1) TWI267401B (pt)
WO (1) WO2003064032A1 (pt)

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TWI267401B (en) 2002-01-30 2006-12-01 Shell Int Research A catalyst, its preparation and its use in a dehydrogenation process
US7282619B2 (en) 2003-10-14 2007-10-16 Shell Oil Company Method of operating a dehydrogenation reactor system
US7297402B2 (en) * 2004-04-15 2007-11-20 Shell Oil Company Shaped particle having an asymmetrical cross sectional geometry
US20060020152A1 (en) * 2004-07-22 2006-01-26 Theobald Eugene H Method for the low temperature selective oxidation of hydrogen contained in a hydrocarbon stream
TW200624170A (en) 2004-11-18 2006-07-16 Shell Int Research A high activity and high stability iron oxide based dehydrogenation catalyst having a low concentration of titanium and the manufacture and use thereof
AU2005307854A1 (en) * 2004-11-18 2006-05-26 Shell Internationale Research Maatschappij B.V. Dehydrogenation process
CN101115698B (zh) * 2004-11-18 2011-06-15 国际壳牌研究有限公司 在低的蒸汽与油之比的工艺条件下制备烯基芳族化合物的改进方法
CN100391605C (zh) * 2005-01-26 2008-06-04 中国石油化工股份有限公司 用于制备烷烯基芳烃的脱氢催化剂
US20060224029A1 (en) * 2005-03-29 2006-10-05 Fina Technology, Inc. Method of extending catalyst life in vinyl aromatic hydrocarbon formation
JP4934134B2 (ja) * 2005-07-22 2012-05-16 ビーエーエスエフ ソシエタス・ヨーロピア 二次触媒材料を含有する、炭化水素の脱水素または水素化触媒
AU2006292708A1 (en) * 2005-09-16 2007-03-29 Shell Internationale Research Maatschappij B.V. A method of making aromatic products
US20070189989A1 (en) * 2006-02-16 2007-08-16 Cantwell Maggie Y Cosmetic compositions and methods of making and using the compositions
JP5683109B2 (ja) * 2007-01-18 2015-03-11 バスフ・コーポレイション 触媒、これの調製および使用
AR065023A1 (es) * 2007-01-30 2009-05-13 Shell Int Research Un catalizador de deshidrogenacion, su proceso de preparacion y su metodo de uso
US8143188B2 (en) * 2007-05-03 2012-03-27 Basf Corporation Catalyst, its preparation and use
EP2152412A2 (en) * 2007-05-03 2010-02-17 Shell Internationale Research Maatschappij B.V. A catalyst, its preparation and use
AU2008286950B2 (en) * 2007-08-10 2013-11-07 Res Usa, Llc Precipitated iron catalyst for hydrogenation of carbon monoxide
US20100022816A1 (en) * 2008-07-22 2010-01-28 Fina Technology, Inc. Dehydrogenation of Methylbutenes to Isoprene
US8905259B2 (en) 2010-08-12 2014-12-09 Holtec International, Inc. Ventilated system for storing high level radioactive waste
CN107298634B (zh) * 2011-12-22 2021-06-01 巴斯夫欧洲公司 用于烃脱氢的催化剂

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Also Published As

Publication number Publication date
KR20040077807A (ko) 2004-09-06
DE60312484D1 (de) 2007-04-26
EP1471999B1 (en) 2007-03-14
CN1697691A (zh) 2005-11-16
RU2302290C2 (ru) 2007-07-10
TW200302131A (en) 2003-08-01
MXPA04007296A (es) 2004-10-29
DE60312484T2 (de) 2007-12-13
TWI267401B (en) 2006-12-01
EP1471999A1 (en) 2004-11-03
WO2003064032A1 (en) 2003-08-07
US7435703B2 (en) 2008-10-14
JP4308665B2 (ja) 2009-08-05
JP2005515886A (ja) 2005-06-02
CA2474607A1 (en) 2003-08-07
RU2004126240A (ru) 2006-01-27
AU2003210745B2 (en) 2008-10-23
CN102343268A (zh) 2012-02-08
KR100945966B1 (ko) 2010-03-09
US20030144566A1 (en) 2003-07-31
AR038321A1 (es) 2005-01-12
ATE356661T1 (de) 2007-04-15

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Legal Events

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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B09B Patent application refused [chapter 9.2 patent gazette]

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