CN1653107A - 二组分混合体系 - Google Patents
二组分混合体系 Download PDFInfo
- Publication number
- CN1653107A CN1653107A CN 03811296 CN03811296A CN1653107A CN 1653107 A CN1653107 A CN 1653107A CN 03811296 CN03811296 CN 03811296 CN 03811296 A CN03811296 A CN 03811296A CN 1653107 A CN1653107 A CN 1653107A
- Authority
- CN
- China
- Prior art keywords
- aerosil
- silicic acid
- weight
- thixotropic
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002156 mixing Methods 0.000 title description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 83
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 78
- 235000012239 silicon dioxide Nutrition 0.000 claims description 30
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 28
- 238000000197 pyrolysis Methods 0.000 claims description 27
- 239000004848 polyfunctional curative Substances 0.000 claims description 23
- 239000011342 resin composition Substances 0.000 claims description 21
- 230000009974 thixotropic effect Effects 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- -1 dihydroxyphenyl Chemical group 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000013008 thixotropic agent Substances 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 229930185605 Bisphenol Natural products 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000000463 material Substances 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 9
- 238000001035 drying Methods 0.000 description 7
- 238000000518 rheometry Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000011164 primary particle Substances 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 2
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- OSQBFLZKVLCVGI-UHFFFAOYSA-N 1,2,3,4-tetrahydronaphthalene-1-carbonyl 1,2,3,4-tetrahydronaphthalene-1-carboxylate Chemical compound C1CCC2=CC=CC=C2C1C(=O)OC(=O)C1C2=CC=CC=C2CCC1 OSQBFLZKVLCVGI-UHFFFAOYSA-N 0.000 description 1
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical class CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 1
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical class CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
- 229910017008 AsF 6 Inorganic materials 0.000 description 1
- JTCRTKVUZWHPHD-UHFFFAOYSA-N C(Cl)C1CO1.OC(CC)(C1=CC=CC=C1)O Chemical compound C(Cl)C1CO1.OC(CC)(C1=CC=CC=C1)O JTCRTKVUZWHPHD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- XCJXQCUJXDUNDN-UHFFFAOYSA-N chlordene Chemical compound C12C=CCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl XCJXQCUJXDUNDN-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229920002601 oligoester Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
检测方法 | Aerosil130 Aerosil150 Aerosil200 Aerosil300 Aerosil380 AerosilCOK 84 氧化铝C | |||||||
对水的性能 | 亲水的 | |||||||
外观 | 松散的白色粉末 | |||||||
BET表面 | m2/g | 130±25 | 150±15 | 200±25 | 300±30 | 380±30 | 170±30 | 100±15 |
初次颗粒的平均粒度 | nm | 16 | 14 | 12 | 7 | 7 | -- | 13 |
捣实密度(大约值) | g/l | 50 | 50 | 50 | 50 | 50 | 50 | 50 |
经压实的物料(附注“V”) | g/l | 120 | 120 | 120 | 120 | 120 | 50 | |
VV物料(附注“VV”) | g/lg/l | 50/75 | 50/75120/150 | 50/75120/150 | ||||
干燥损失(105℃下2h)在离开供货地点时 | % | <1.5 | 0.5 | <1.5 | <1.5 | <2.0 | <1.5 | <5 |
加热损失(在1000℃下2h) | % | <1 | <1 | <1 | <2 | <2.5 | <1 | <3 |
pH值 | 3.7-4.7 | 3.7-4.7 | 3.7-4.7 | 3.7-4.7 | 3.7-4.7 | 3.6-4.3 | 4.5-5.5 | |
SiO2 | % | >99.8 | >99.8 | >99.8 | >99.8 | >99.8 | 82-86 | <0.1 |
Al2O3 | % | <0.05 | <0.05 | <0.05 | <0.05 | <0.05 | 14-18 | >99.6 |
Fe2O3 | % | <0.003 | <0.003 | <0.003 | <0.003 | <0.003 | <0.1 | <0.2 |
TiO2 | % | <0.03 | <0.03 | <0.03 | <0.03 | <0.03 | <0.03 | <0.1 |
HCl | % | <0.025 | <0.025 | <0.025 | <0.025 | <0.025 | <0.1 | <0.5 |
筛上物(根据Mocker,45nm)束大小(净) | %kg | <0.0510 | <0.0510 | <0.0510 | <0.0510 | <0.0510 | <0.110 | <0.0510 |
性能 | 单位 | AerosilUS204有效值 | AerosilUS 202 | 方法 |
BET表面 | m2/g | 120-160 | 70-110 | ACM 107-1 |
pH值(在4%的水性分散体) | 4.0-6.0 | 4.0-6.0 | ACM 102-1 | |
干燥损失(在105℃下2h) | % | <0.5 | <0.5 | ACM 101 |
碳含量 | % | 3.0-4.5 | 3.0-4.5 | WAAM 105-1 |
初次颗粒的平均粒度 | nm | 12 | 14 | nsm |
捣实密度 | g/l | 50 | 50 | ACM 104 |
二氧化硅 | % | >99.8 | >99.8 | ACM 118 |
Al2O3 | % | <0.05 | <0.05 | ACM 116 |
Fe2O3 | % | <0.01 | <0.01 | ACM 115 |
TiO2 | % | <0.03 | <0.03 | ACM 117 |
HCl-含量 | % | <0.025 | <0.025 | ACM 112 |
AerosilR 202 | ||
对水的性能 | 疏水性的 | |
外观 | 松散的白色粉末 | |
BET表面1) | m2/g | 100±20 |
初次颗粒的平均粒度 | nm | 14 |
捣实密度(大约值)2)通常的物料 | g/l | 50 |
压实了的物料(附注“VV”) | g/l | 60/90 |
干燥损失3)(105℃下2h)在离开供货地点时 | % | <0.5 |
加热损失4) 7)(1000℃下2h) | % | 4-611) |
pH值5) | 4-69) | |
SiO2 8) | % | >99.8 |
Al2O3 8) | % | <0.05 |
Fe2O3 8) | % | <0.01 |
TiO2 8) | % | <0.03 |
HCl8)10) | % | <0.025 |
筛上物6)(根据Mocker,45μm) | % | <0.05 |
束大小(净) | kg | 10 |
物理-化学参数 | ||
性能 | 单位 | 标准值 |
比表面(BET) | m2/g | 110±20 |
C含量 | % | 3.5-5.5 |
初次颗粒的平均粒度 | nm | 14 |
捣实密度(大约值)根据DIN ISO 787/XI,1983.8. | g/l | 约60 |
在105℃下2h的干燥损失 | % | ≤0.5 |
在1000℃下2h的加热损失,以经干燥的物质计(在105℃下2h) | % | 4.0-6.0 |
pH值4%的分散体 | 4.0-6.0 | |
SiO2含量(1)(1)以经加热的物质计 | % | ≥99.8 |
物理-化学参数 | ||
性能 | 单位 | 标准值 |
比表面(BET) | m2/g | 110±20 |
C含量 | % | 3.5-5.5 |
初次颗粒的平均粒度 | nm | 14 |
捣实密度(大约值)根据DIN ISO 787/XI,1983.8. | g/l | 约90 |
在105℃下2h的干燥损失 | % | ≤0.5 |
在1000℃下2h的加热损失,以经干燥的物质计(在105℃下2h) | % | 4.0-6.0 |
pH值4%的分散体 | 4.0-6.0 | |
SiO2含量(1)(1)以经加热的物质计 | % | ≥99.8 |
试样号 | 流变极限Pa | 粘度Pa s0.5/s | 粘度Pa s100/s | 粘度Pa s0.5/s |
1号试样:6%的AerosilR 202VV 60 | 428 | 855 | 18 | 812 |
2号试样:8%的Aerosil200 | 427 | 987 | 23 | 712 |
在42天后测量 | ||||
1号试样:6%的AerosilR 202VV 60 | 331 | 757 | 18 | 868 |
2号试样:8%的Aerosil200 | 152 | 24 | 16 | 25 |
在1.5小时后的测量:硬化剂组分 | ||||
3号试样:10%的AerosilR 202VV 60 | 177 | 351 | 10 | 250 |
4号试样:8%的Aerosil200 | 597 | 902 | 6.7 | 883 |
在42天后测量: | ||||
3号试样:10%的AerosilR 202VV 60 | 74 | 101 | 11.6 | 124 |
4号试样:8%的Aerosil200 | 770 | 1943 | 12.8 | 1886 |
Claims (4)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10222153.7 | 2002-05-17 | ||
US10222153.7 | 2002-05-17 | ||
DE10222153.7A DE10222153B4 (de) | 2002-05-17 | 2002-05-17 | 2-Komponenten-Mischsysteme |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1653107A true CN1653107A (zh) | 2005-08-10 |
CN100351283C CN100351283C (zh) | 2007-11-28 |
Family
ID=29413939
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038112965A Expired - Lifetime CN100351283C (zh) | 2002-05-17 | 2003-04-15 | 二组分混合体系 |
Country Status (4)
Country | Link |
---|---|
CN (1) | CN100351283C (zh) |
AU (1) | AU2003222813A1 (zh) |
DE (1) | DE10222153B4 (zh) |
WO (1) | WO2003097713A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10356042A1 (de) * | 2003-12-01 | 2005-07-07 | Degussa Ag | Kleb-und Dichtstoffsysteme |
DE102008000499A1 (de) | 2008-03-04 | 2009-09-10 | Evonik Degussa Gmbh | Kieselsäure sowie Epoxidharze |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES335564A1 (es) | 1966-01-13 | 1968-03-16 | Ciba Geigy | Procedimiento para preparar mezclas tixotropicas endureci- bles. |
US4692479A (en) * | 1985-07-19 | 1987-09-08 | Ashland Oil, Inc. | Self-setting urethane adhesive paste system |
US4775728A (en) * | 1987-02-24 | 1988-10-04 | Ashland Oil, Inc. | Sag resistant, high performance, two component epoxy structural adhesives |
EP0488949B1 (en) | 1990-11-29 | 1995-07-26 | Ciba-Geigy Ag | High performance epoxy adhesive |
CN1092091A (zh) * | 1993-03-06 | 1994-09-14 | 韩永海 | 阻燃绝缘涂料 |
DE4442353A1 (de) | 1994-11-29 | 1996-05-30 | Henkel Kgaa | Polyurethan-Zusammensetzungen mit stabiler Reaktivität |
DE19618537C1 (de) | 1996-05-08 | 1998-05-07 | Pci Augsburg Gmbh | Mehrkomponentenkit für eine Polyurethandicht- und -klebmasse und daraus hergestellte Dicht- und Klebmasse |
US6248204B1 (en) | 1999-05-14 | 2001-06-19 | Loctite Corporation | Two part, reinforced, room temperature curable thermosetting epoxy resin compositions with improved adhesive strength and fracture toughness |
BR0114496A (pt) | 2000-10-10 | 2003-12-30 | Henkel Kgaa | Sistema de dois componentes, métodos de cura de uma composição termoendurecìvel, de preparação de uma espuma de reforço de estrutura, de reforço de um substrato que tem uma superfìcie, e de reforço de uma peça de estrutura que tem uma cavidade, adesivo de reforço de estrutura, espuma para reforço de estrutura, e, componente útil na cura de um segundo componente que compreende resina de epóxi |
-
2002
- 2002-05-17 DE DE10222153.7A patent/DE10222153B4/de not_active Expired - Lifetime
-
2003
- 2003-04-15 AU AU2003222813A patent/AU2003222813A1/en not_active Abandoned
- 2003-04-15 CN CNB038112965A patent/CN100351283C/zh not_active Expired - Lifetime
- 2003-04-15 WO PCT/EP2003/003895 patent/WO2003097713A1/de not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
DE10222153A1 (de) | 2003-12-04 |
WO2003097713A1 (de) | 2003-11-27 |
CN100351283C (zh) | 2007-11-28 |
DE10222153B4 (de) | 2018-11-22 |
AU2003222813A1 (en) | 2003-12-02 |
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