CN1649909A - 制造硫化乙烯丙烯酸类和聚丙烯酸酯弹性体的方法 - Google Patents
制造硫化乙烯丙烯酸类和聚丙烯酸酯弹性体的方法 Download PDFInfo
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- CN1649909A CN1649909A CNA038096919A CN03809691A CN1649909A CN 1649909 A CN1649909 A CN 1649909A CN A038096919 A CNA038096919 A CN A038096919A CN 03809691 A CN03809691 A CN 03809691A CN 1649909 A CN1649909 A CN 1649909A
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- AFYCEAFSNDLKSX-UHFFFAOYSA-N coumarin 460 Chemical compound CC1=CC(=O)OC2=CC(N(CC)CC)=CC=C21 AFYCEAFSNDLKSX-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
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- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
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- 239000004519 grease Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
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- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920001603 poly (alkyl acrylates) Polymers 0.000 description 1
- ZGJADVGJIVEEGF-UHFFFAOYSA-M potassium;phenoxide Chemical compound [K+].[O-]C1=CC=CC=C1 ZGJADVGJIVEEGF-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- LMHHRCOWPQNFTF-UHFFFAOYSA-N s-propan-2-yl azepane-1-carbothioate Chemical compound CC(C)SC(=O)N1CCCCCC1 LMHHRCOWPQNFTF-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
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- 150000003568 thioethers Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
实验号 | 1 | 2 | 3 | 4 |
Vamac | 100 | 100 | 100 | 100 |
炭黑,N550 | 60 | 60 | 60 | 60 |
TP-759 | 10 | 10 | 10 | 10 |
硬脂酸 | 1.5 | 1.5 | 1.5 | 1.5 |
Vanfre VAM | 1 | 1 | 1 | 1 |
Armeen 18D | 0.5 | 0.5 | 0.5 | 0.5 |
Naugard 445 | 2 | 2 | 2 | 2 |
Diak#1 | 1.5 | 1.5 | ||
70 HMDA/30 H2O | 1.55 | 1.55 | ||
DOTG | 4 | 4 | 0 | 0 |
总PPH | 180.5 | 180.55 | 176.5 | 176.55 |
配混物的流变 | ||||
门尼粘度 | ||||
ML(1+4)@100℃ | 36 | 36 | 43 | 43 |
门尼焦烧-121℃ | ||||
最小粘度-MU | 13.2 | 13.1 | 15.5 | 15.4 |
t10--公制分钟 | 12.8 | 13.1 | 14.9 | 15.4 |
t18--公制分钟 | 18.8 | 19.7 | ||
在177,1°弧的MDR总结 | ||||
ML,lbf-in | 0.56 | 0.56 | 0.68 | 0.67 |
MH,lbf-in | 22.1 | 23.1 | 14 | 13.6 |
TS2,公制分钟 | 0.85 | 0.84 | 1.35 | 1.36 |
t50,m分钟 | 2.4 | 2.5 | 4.1 | 4.1 |
t90,m分钟 | 10.1 | 10.9 | 16.7 | 16.8 |
硫化之后的物理性能 | ||||
在175℃下加压硫化中5min | ||||
在175℃下后硫化的4小时 | ||||
硬度Shore A | 65 | 64 | 67 | 66 |
在100%伸长率下的模量psi | 775 | 860 | 725 | 722 |
拉伸强度,psi | 2322 | 2442 | 2343 | 2342 |
%伸长率 | 314 | 293 | 289 | 293 |
压缩变形168hrs/150℃ | 23.5 | 22.3 | 44.9 | 48.2 |
在175℃下在空气中老化1周 | ||||
硬度Shore A | 69 | 75 | 70 | 66 |
在100%伸长率下的模量psi | 893 | 975 | 694 | 636 |
拉伸强度,psi | 2371 | 2223 | 1882 | 1841 |
%伸长率 | 280 | 270 | 288 | 290 |
硬度的变化,点 | 4 | 11 | 3 | 0 |
在100%模量中的变化% | 15.2% | 13.4% | -4.3% | -11.9% |
在拉伸强度中的变化% | 2.1% | -9.0% | -19.7% | -21.4% |
伸长率中的变化% | -10.8% | -7.8% | -0.3% | -1.0% |
在150℃下在空气中老化6周 | ||||
硬度Shore A | 69 | 73 | 69 | 68 |
在100%伸长率下的模量psi | 884 | 936 | 802 | 740 |
拉伸强度,psi | 2168 | 2091 | 1937 | 1884 |
%伸长率 | 277 | 298 | 304 | 316 |
硬度的变化,点 | 4 | 9 | 2 | 2 |
在100%模量中的变化% | 14.1% | 8.8% | 10.6% | 2.5% |
在拉伸强度中的变化% | -6.6% | -14.4% | -17.3% | -19.6% |
伸长率中的变化% | -11.8% | 1.7% | 5.2% | 7.8% |
实验号 | 1 | 2 | 3 | 4 | 5 | 6 |
Vamac | 100 | 100 | 100 | 100 | 100 | 100 |
炭黑,N550 | 60 | 56.85 | 58.45 | 56.85 | 58.45 | 60 |
TP-759 | 10 | 10 | 10 | 10 | 10 | 10 |
硬脂酸 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
Vanfre VAM | 1 | 1 | 1 | 1 | 1 | 1 |
Armeen 18D | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
Naugard 445 | 2 | 2 | 2 | 2 | 2 | 2 |
Diak #1 | 1.5 | |||||
33HMDA/H2O,67二氧化硅(A) | 4.7 | |||||
50HMDA/H2O,50二氧化硅(B) | 3.1 | |||||
33HMDA/H2O,67炭黑(C) | 4.7 | |||||
50HMDA/H2O,50炭黑(D) | 3.1 | |||||
27.9HMDA/H2O,72.1DOTG(E) | 5.55 | |||||
DOTG | 4 | 4 | 4 | 4 | 4 | 0 |
总PPH | 180.5 | 180.55 | 180.55 | 180.55 | 180.55 | 180.55 |
配混物的流变 | ||||||
粘度,ML(1+4)@100℃ | 35.2 | 35.2 | 34.5 | 33.4 | 34.8 | 31.5 |
门尼焦烧-121℃ | ||||||
最小粘度-MU | 11.8 | 12.2 | 11.6 | 11.4 | 11.3 | 10.7 |
t3-公制分钟 | 7.7 | 7.7 | 7.8 | 7.9 | 7.9 | 7.7 |
t10-公制分钟 | 12.8 | 13.1 | 13.3 | 13.4 | 13.3 | 13.1 |
t18-公制分钟 | 18.8 | 20.3 | 20.3 | 19.8 | 20.2 | 18.8 |
在177,1°弧的MDR总结 | ||||||
ML,lbf-in | 0.52 | 0.54 | 0.52 | 0.51 | 0.54 | 0.51 |
MH,lbf-in | 22.1 | 23.1 | 23.5 | 21.3 | 24.2 | 20.5 |
tS1,公制分钟 | 0.65 | 0.64 | 0.65 | 0.65 | 0.66 | 0.64 |
tS2,公制分钟 | 0.85 | 0.84 | 0.86 | 0.86 | 0.86 | 0.84 |
t10,m分钟 | 0.88 | 0.88 | 0.91 | 0.91 | 0.93 | 0.84 |
t50,m分钟 | 2.4 | 2.5 | 2.6 | 2.6 | 2.7 | 2.3 |
t90,m分钟 | 9.3 | 11.5 | 11.2 | 10.7 | 11 | 10.2 |
斜率,(0.9*MH-ML+2)/(t90-tS2) | 2.53 | 2.09 | 2.19 | 2.10 | 2.29 | 2.13 |
斜率,(0.5*MH-ML+2)/(t50-tS2) | 13.8 | 13.4 | 13.0 | 11.9 | 12.6 | 13.7 |
硫化之后的物理性能 | ||||||
在175℃下加压硫化中的5min | ||||||
在175℃下后硫化的4小时 | ||||||
硬度,Shore A | 67 | 66 | 67 | 69 | 68 | 67 |
在100%伸长率下的模量,psi | 826 | 813 | 869 | 877 | 893 | 748 |
拉伸强度,psi | 2293 | 2323 | 2421 | 2397 | 2439 | 2385 |
%伸长率 | 294 | 286 | 281 | 276 | 279 | 319 |
模头C撕裂,pli | 204 | 207 | 210 | 203 | 186 | 195 |
压缩变形168hrs/150 | 20.3 | 21.1 | 19.1 | 17.4 | 20.9 | 20.4 |
Claims (4)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37677802P | 2002-04-29 | 2002-04-29 | |
US60/376,778 | 2002-04-29 | ||
US10/417,806 | 2003-04-17 | ||
US10/417,806 US7001957B2 (en) | 2002-04-29 | 2003-04-17 | Method of manufacturing cured ethylene acrylic and polyacrylate elastomers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1649909A true CN1649909A (zh) | 2005-08-03 |
CN100475861C CN100475861C (zh) | 2009-04-08 |
Family
ID=29254691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038096919A Expired - Lifetime CN100475861C (zh) | 2002-04-29 | 2003-04-29 | 制造硫化乙烯丙烯酸类和聚丙烯酸酯弹性体的方法 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7001957B2 (zh) |
EP (1) | EP1499670B1 (zh) |
JP (1) | JP4592420B2 (zh) |
KR (1) | KR101004167B1 (zh) |
CN (1) | CN100475861C (zh) |
AU (1) | AU2003301862A1 (zh) |
CA (1) | CA2482565A1 (zh) |
DE (1) | DE60300987T2 (zh) |
MX (1) | MXPA04010676A (zh) |
WO (1) | WO2004041920A2 (zh) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7521503B2 (en) * | 2003-07-24 | 2009-04-21 | E. I. Du Pont De Nemours And Company | Ethylene/alkyl acrylate copolymers, compounds and vulcanizates thereof |
US7598321B2 (en) * | 2005-08-10 | 2009-10-06 | E. I. Du Pont De Nemours And Company | Ethylene acid copolymer |
JP2007269855A (ja) * | 2006-03-30 | 2007-10-18 | Arai Pump Mfg Co Ltd | 非固着性ゴム組成物およびシール部材 |
KR101051654B1 (ko) | 2008-11-28 | 2011-07-26 | 평화오일씰공업주식회사 | 엔진 오일 필터의 개스킷용 고무 조성물 |
EP2292687B1 (en) | 2009-09-03 | 2012-07-25 | Rhein Chemie Rheinau GmbH | Improved vulcanisable guanidine-free mixtures containing ethylene acrylate (AEM), polyacrylate (ACM) and/or hydrogenated acrylnitrile (HNBR)-based rubbers compounds, vulcanisates, prepared by cross-linking this vulcanisable mixtures and their use |
KR20120111741A (ko) * | 2010-01-08 | 2012-10-10 | 페더럴-모걸 코오포레이숀 | 오븐 후경화 없는 에틸렌-아크릴 접합된 피스톤 |
EP2620277A1 (de) | 2012-01-26 | 2013-07-31 | LANXESS Deutschland GmbH | Mehrschichtsysteme |
WO2020017009A1 (ja) * | 2018-07-19 | 2020-01-23 | 横浜ゴム株式会社 | ホース用ゴム組成物 |
WO2020017010A1 (ja) * | 2018-07-19 | 2020-01-23 | 横浜ゴム株式会社 | ホース用ゴム組成物 |
EP3887155A1 (en) * | 2018-11-29 | 2021-10-06 | 3M Innovative Properties Company | Composite film, method of making the same, and article including the same |
WO2021037801A1 (de) | 2019-08-30 | 2021-03-04 | Lanxess Deutschland Gmbh | Mischungen enthaltend einen aminisch vernetzbaren kautschuk und polyethylenimin |
EP3786227A1 (de) | 2019-08-30 | 2021-03-03 | LANXESS Deutschland GmbH | Mischungen enthaltend einen aminisch vernetzbaren kautschuk und polyethylenimin |
EP3896127A1 (de) | 2020-04-16 | 2021-10-20 | LANXESS Deutschland GmbH | Mischungen enthaltend einen aminisch vernetzbaren kautschuk und polyethylenimin |
US20230046550A1 (en) | 2019-12-04 | 2023-02-16 | Exxonmobil Research And Engineering Company | Adhesive compositions |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
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DE2431556C3 (de) * | 1973-08-09 | 1988-02-11 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Copolymerisat mit regelloser Verteilung der einpolymerisierten Monomereinheiten |
US3883472A (en) * | 1973-08-09 | 1975-05-13 | Du Pont | Fast curing heat stable elastomeric compositions |
US3904588A (en) * | 1973-08-09 | 1975-09-09 | Du Pont | Random ethylene/alkyl acrylate 1,4-butene-dioic acid terpolymers |
US4026851A (en) * | 1975-08-13 | 1977-05-31 | E. I. Du Pont De Nemours And Company | Acrylate polymers cured with diamines in the presence of an acid catalyst |
US4141857A (en) * | 1976-04-30 | 1979-02-27 | Uop Inc. | Support matrices for immobilized enzymes |
JPS5624436A (en) * | 1979-08-03 | 1981-03-09 | Asahi Chem Ind Co Ltd | Polyoxymethylene composition |
US4292372A (en) * | 1980-06-02 | 1981-09-29 | E. I. Du Pont De Nemours And Company | Polyvinylbutyral sheeting |
US4399263A (en) * | 1981-12-24 | 1983-08-16 | E. I. Du Pont De Nemours & Co. | Modification of ethylene/acrylate/carboxylic polymer |
DE3151753A1 (de) * | 1981-12-29 | 1983-07-07 | Basf Ag, 6700 Ludwigshafen | Hochkonzentrierte, nichtstaubende, feste und leicht verteilbare pigmentpraeparation und deren verwendung |
US4412043A (en) | 1982-05-03 | 1983-10-25 | E. I. Du Pont De Nemours And Company | Vulcanizable ethylene copolymers |
US5427861A (en) * | 1991-08-12 | 1995-06-27 | Monsanto Company | Laminated glazing panel having improved resistance to light exposure |
JP2000044757A (ja) | 1998-07-29 | 2000-02-15 | Nippon Zeon Co Ltd | シール用加硫性ゴム組成物及びシール |
JP4505913B2 (ja) * | 1999-12-24 | 2010-07-21 | ユニマテック株式会社 | アクリル系エラストマー組成物およびその架橋性組成物 |
US6528586B2 (en) | 2000-05-16 | 2003-03-04 | Gordon Mark Cohen | Compositions of elastomeric ethylene/(meth)acrylic (acid) ester copolymer and polylactone or polyether |
-
2003
- 2003-04-17 US US10/417,806 patent/US7001957B2/en not_active Expired - Lifetime
- 2003-04-29 AU AU2003301862A patent/AU2003301862A1/en not_active Abandoned
- 2003-04-29 MX MXPA04010676A patent/MXPA04010676A/es not_active Application Discontinuation
- 2003-04-29 DE DE60300987T patent/DE60300987T2/de not_active Expired - Lifetime
- 2003-04-29 WO PCT/US2003/013211 patent/WO2004041920A2/en active IP Right Grant
- 2003-04-29 KR KR1020047017369A patent/KR101004167B1/ko active IP Right Grant
- 2003-04-29 EP EP03810734A patent/EP1499670B1/en not_active Expired - Lifetime
- 2003-04-29 CN CNB038096919A patent/CN100475861C/zh not_active Expired - Lifetime
- 2003-04-29 CA CA002482565A patent/CA2482565A1/en not_active Abandoned
- 2003-04-29 JP JP2004549875A patent/JP4592420B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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AU2003301862A1 (en) | 2004-06-07 |
AU2003301862A8 (en) | 2004-06-07 |
JP4592420B2 (ja) | 2010-12-01 |
KR101004167B1 (ko) | 2010-12-24 |
DE60300987D1 (de) | 2005-08-11 |
US7001957B2 (en) | 2006-02-21 |
EP1499670B1 (en) | 2005-07-06 |
KR20040106411A (ko) | 2004-12-17 |
DE60300987T2 (de) | 2006-05-24 |
CN100475861C (zh) | 2009-04-08 |
WO2004041920A2 (en) | 2004-05-21 |
CA2482565A1 (en) | 2004-05-21 |
EP1499670A2 (en) | 2005-01-26 |
MXPA04010676A (es) | 2004-12-13 |
US20030204025A1 (en) | 2003-10-30 |
WO2004041920A3 (en) | 2004-10-21 |
JP2005532469A (ja) | 2005-10-27 |
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