CN1630706A - 石料表面的清洁和维护组合物 - Google Patents
石料表面的清洁和维护组合物 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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Abstract
本发明主要涉及石料表面的清洁和维护的合成物,包括在溶液中不分解成离子的表面活性剂、能取得pH值为7的季铵表面活性剂、中和剂和水。可选择的,香味剂和其它表面增强添加剂可被包括在本合成物中。本发明的合成物可被用于高度稀释的浓度以清洁和维护石料表面,同时使不良的、不利的表面影响减到最小。
Description
本发明的背景
本发明主要涉及合成物,用于清洁和维护表面,并特别是石料表面。而且本发明涉及合成物,该合成物被提供在维护高表面光洁度的同时常规的清洁表面。
本发明的现有技术
大理石是一种相对松软的天然石料,因此,在导致划伤和其它表面损伤时需要高水平的维护。此外,大理石和其它石料表面经常与常用的清洁剂和抛光剂中的组分发生反应。因为这些原因,为了维持表面的正常外观必须采用慎重的维护。其它类型的石料地面包括水磨石、菱镁矿石、石灰石、花岗石和石灰华也需要高水平的维护以减少或除去划伤。
有机酸,例如草酸被用于清洁和“再结晶”石料类的表面,尤其是地面。使用这种合成物的一个缺点是较长的操作时间和随后讨厌的清除工作。例如,有机酸和草酸基的产品的典型的应用需要15至30分钟每20到25平方英尺。这种合成物被应用为粉末或膏剂与大量的水进行抛光。合成物不允许干周,重要的是,会造成拖痕。随后的清除涉及将该产品移至下一块地面或清除渣滓。此外,在使用中,合成物必须连续的被清除以确定取得的光泽度的水平。在这一过程中缺少控制与劳动强度大、施用量大和清除工作都是使用这种合成物时面对的重要问题。此外,在预期的光泽度取得后,保持这种高光泽度的日常维护是困难的。通常使用的清洁剂会经常有拖痕和“鱼眼”的问题。而且,随时间,高光泽度的表面变暗是一个问题。
总之,大量的不足存在于石料表面维护的合成物的相关技术和使用方法中。现有技术的清洁合成物可充分清洁表面的同时,通常的表面清洁剂的使用导致变暗的光泽度、拖痕和鱼眼。同时,许多合成物试图侵蚀表面会造成基质的相当的损害。这样,更多的劳动强度和重结晶的时间和/或抛光必须经常的重复以维持预期的外观。
这样,正在寻找能够散布方便,在清洁表面的同时维持要求的高的光泽度而没有拖痕、变暗、鱼眼、浸蚀或其它对石料表面的损害的维护合成物。很明显,需要改进和更新石料表面的维护合成物以提供充分的清洁的同时维护这种表面的高的光泽度。而且,需要改进维护合成物以克服现有技术的缺陷。
本发明的目标
本发明的目标是提供一种表面维护合成物,该合成物可克服现有技术的缺陷。本发明更进一步的目标是提供一种可有效应用于石料表面的维护合成物。本发明的另一个目标是为石料表面提供一种维护合成物,在保持对石料表面的高清洁能力的同时维持高光泽度。本发明的另一个目标是提供用于石料表面的日常的维护清洁剂,减少拖痕和其它不良的外观影响。本发明还有另一个目标是提供用于石料表面的日常的维护合成物,不会对表面造成变暗或拖痕或浸蚀或其它损害。这些以及其它的重要的目标将从以下描述而更为清晰。
本发明的概述
本发明主要涉及清洁合成物,包括在溶液中不分解成离子的表面活性剂、季铵表面活性剂、中和剂和水。此外,中和剂可被包括在本合成物中。香味剂和其它表面增强添加剂可被包括在本合成物中。典型的合成物包括约0.01至0.05重量百分比的在溶液中不分解成离子的表面活性剂,约0.03至约0.5重量百分比的季铵表面活性剂和90至99.7重量百分比的水。中和剂可以0.0001至0.0005重量百分比的数量存在合成物中。而且,本合成物可包括0.0001至0.01重量百分比的芳香剂。
本发明的合成物中的在溶液中不分解成离子的表面活性剂包括链烷醇酰胺、氧化胺、嵌段共聚合物、乙氧基化醇、乙氧烷基酚、乙氧基化脂肪酸、乙氧基化酯和油、山梨聚糖衍生物、蔗糖酯、葡萄糖酯和衍生物。可选择的,这些溶液中不分解成离子的表面活性剂的组合可被使用。优选的是,溶液中不分解成离子的表面活性剂是乙氧基化醇。
本发明的合成物中的季铵表面活性剂优选的是季铵氯化物,例如二(辛基癸基)二甲基铵氯化物。典型的中和剂包括本领域普通技术人员都了解的碱性物、碱和碱金属盐,例如氢氧化钠、碳酸氢钠、碳酸钠、氢氧化钾、碳酸氢钾、碳酸钾、氢氧化镁、碳酸镁、氢氧化钙、碳酸钙和其它中和性原料。一个优选的中和剂是氢氧化钠。
本发明的优选的方案包括大约0.02至0.2重量百分比的溶液中不分解成离子的表面活性剂、大约0.005至0.1重量百分比的季铵表面活性剂和大约95至99.97重量百分比的水。优选的中和剂的量在大约0.0001至大约0.0005或足够取得PH值大约为7。这种合成物在石料表面的维护中,对于保持高光泽度而不对高光泽度或石料表面造成损伤十分有用。本发明的合成物在日常使用中作为石料表面的维护剂和/或清洁剂而不会有对高光泽度的损伤或变形。
本发明的详细描述
本发明涉及对石料表面的处理的合成物的改进——主要是,用于清洁和维护石料表面的合成物和维护石料表面的方法。本发明的清洁合成物包括至少一种溶液中不分解成离子的表面活性剂、至少一种季铵表面活性剂和水,在下面的描述中进一步详述。
溶液中不分解成离子的表面活性剂例如链烷醇酰胺、氧化胺、嵌段共聚合物、乙氧基化醇、乙氧烷基酚、乙氧基化脂肪酸、乙氧基化酯和油、山梨聚糖衍生物、蔗糖酯、葡萄糖酯和衍生物,和其它类型的被发现在本发明中特别有用的溶液中不分解成离子的表面活性剂。尤其是,乙氧基化醇被发现当应用在本发明的合成物中时可产生可接受的结果。本发明的合成物特有的包括大约0.01至0.5重量百分比的至少一种溶液中不分解成离子的表面活性剂。优选的方案包括0.02至0.2重量百分比的溶液中不分解成离子的表面活性剂。非常优选的方案包括0.03至0.12重量百分比的溶液中不分解成离子的表面活性剂。
本发明的季铵表面活性剂和溶液中不分解成离子的表面活性剂共同起效以提供本发明产生的提升的效果。季铵氯化物表面活性剂例如季铵氯化物表面活性剂可被应用在本发明的合成物中。优选的是,一种被证明是有效的此类季铵氯化物表面活性剂是二(辛基癸基)二甲基铵氯化物。优选的是,本发明的合成物包括0.03至0.5重量百分比的季铵表面活性剂。优选的实施方案包括0.005至0.1重量百分比的季铵表面活性剂。非常优选的实施方案包括0.008至0.04重量百分比的季铵表面活性剂。Stepan公司证明有效的季铵表面活性剂包括BTC2125、BTC818、BTC885和BTC1010。此外,McIntyre GroupTM证明有效的另一个季铵表面活性剂是Mackernium621。
本发明的组合物也包括水。组合物优选的包括90至99.97重量百分比的水。这使清洁组合物能够被高度的稀释并使清洁剂的效果最优的同时减少清洁效果,减少同类清洁剂中常发生的不利影响。已经发现,组合物越稀释,清洁效果越好并且导致高度光泽的石料表面。
本发明的组合物也优选的包括中和剂,例如百分之50的氢氧化钠溶液。中和剂是用于中和配方使PH值大约为7,中性。这是显然需要的,由于季铵氯化物表面活性剂的轻微酸性,否则会导致若酸性的配方,造成对石料表面的阴霾和浸蚀的损伤。中和剂在组合物中是0.0001至0.0005的重量百分比。特别是,中和剂应该在足够的数量使PH值呈现大约为7。
如果较理想的,本发明的组合物也可包括其它添加剂,例如香味剂。典型的香味剂在总组合物中呈现大约为0.0001至0.01重量百分比。一种此类香味剂为IFF2832-HF,这是一种苹果香味剂。其它香味剂也适用并被本技术领域普通技术人员所知。
例1呈现了本发明的组成。
例1 | |
成分 | 重量百分比 |
水 | 99.84 |
Tergitol 15-S-7 | 0.12 |
BTC-818 | 0.0352 |
IFF2832HS | 0.0031 |
氢氧化钠,50% | 0 |
例1的组合物是通过如表中顺序加入成分,并搅拌,直至均匀并由氢氧化钠中和。
例2的组合物是通过如表中顺序加入成分,并搅拌,直至均匀并由氢氧化钠中和。
例2 | |
成分 | 重量百分比 |
水 | 99.92 |
Tergitol 15-S-7 | 0.061 |
BTC-818 | 0.0176 |
IFF2832HS | 0.0016 |
氢氧化钠,50% | 0 |
例3的组合物是通过如表中顺序加入成分,并搅拌,直至均匀并由氢氧化钠中和。
例2 | |
成分 | 重量百分比 |
水 | 99.96 |
Tergitol 15-S-7 | 0.030 |
BTC-818 | 0.009 |
IFF2832HS | 0.0008 |
氢氧化钠,50% | 0 |
这些例子描绘了一些可能的本发明的组合物的配方。然而本发明的机理与具体的实施方案相通,应该清楚的理解,这些详述仅通过例子的方式完成并不趋向于限制本发明的范围。
Claims (20)
1.一种用于清洁石料表面的组合物,包括:
(a)约0.01至0.5重量百分比的溶液中不分解成离子的表面活性剂;
(b)约0.003至0.5重量百分比的季铵表面活性剂;
(c)约90至99.97重量百分比的水;以及
(d)中和剂,数量足够使组合物的PH值大约为7;
当其中的组合物被应用时,不会使石料表面变暗、产生条痕、浸蚀、变形或损伤。
2.根据权利要求12的组合物,其中的中和剂呈现为0.0001至0.0005重量百分比的含量。
3.根据权利要求12的组合物,其中的溶液中不分解成离子的表面活性剂是选自下组的,包括链烷醇酰胺、氧化胺、嵌段共聚合物、乙氧基化醇、乙氧烷基酚、乙氧基化脂肪酸、乙氧基化酯和油、山梨聚糖衍生物、蔗糖酯及衍生物、葡萄糖酯及衍生物,及其混合物。
4.根据权利要求12的组合物,其中的中和剂是选自下组的,包括氢氧化钠、碳酸氢钠、碳酸钠、氢氧化钾、碳酸氢钾、碳酸钾、氢氧化镁、碳酸镁、氢氧化钙和碳酸钙。
5.根据权利要求1的组合物,其中石料表面是大理石表面。
6.根据权利要求1的组合物,其中溶液中不分解成离子的表面活性剂是乙氧基化醇。
7.用于清洁石料表面的组合物主要包括:
(a)约0.01至0.5重量百分比的溶液中不分解成离子的表面活性剂;
(b)约0.003至0.5重量百分比的季铵表面活性剂;
(c)约90至99.97重量百分比的水;以及
(d)中和剂,数量足够使组合物的PH值大约为7;
(e)可选择的香味剂;以及
(f)可选择的其它外观提升添加剂;
当其中的组合物被应用时,不会使石料表面变暗、产生条痕、浸蚀、变形或损伤。
8.根据权利要求18的组合物,其中的中和剂呈现为0.0001至0.0005重量百分比的含量。
9.根据权利要求18的组合物,其中的溶液中不分解成离子的表面活性剂是选自下组的,包括链烷醇酰胺、氧化胺、嵌段共聚合物、乙氧基化醇、乙氧烷基酚、乙氧基化脂肪酸、乙氧基化酯和油、山梨聚糖衍生物、蔗糖酯及衍生物、葡萄糖酯及衍生物,及其混合物。
10.根据权利要求18的组合物,其中季铵表面活性剂是季铵氯化物。
11.根据权利要求18的组合物,其中的中和剂是选自下组的,包括氢氧化钠、碳酸氢钠、碳酸钠、氢氧化钾、碳酸氢钾、碳酸钾、氢氧化镁、碳酸镁、氢氧化钙和碳酸钙。
12.根据权利要求18的组合物,其中石料表面是大理石表面。
13.根据权利要求18的组合物,其中的组合物包括含量为0.0001至0.01重量百分比的香味剂。
14.用于清洁石料表面的组合物主要包括:
(a)约0.01至0.5重量百分比的溶液中不分解成离子的表面活性剂;
(b)约0.003至0.5重量百分比的季铵表面活性剂;
(c)约90至99.97重量百分比的水;以及
(d)中和剂,数量足够使组合物的PH值大约为7;
(e)可选择的香味剂;以及
(f)可选择的其它外观提升添加剂;
当其中的组合物被应用时,不会使石料表面变暗、产生条痕、浸蚀、变形或损伤。
15.根据权利要求25的组合物,其中的中和剂呈现为0.0001至0.0005重量百分比的含量。
16.根据权利要求25的组合物,其中的溶液中不分解成离子的表面活性剂是选自下组的,包括链烷醇酰胺、氧化胺、嵌段共聚合物、乙氧基化醇、乙氧烷基酚、乙氧基化脂肪酸、乙氧基化酯和油、山梨聚糖衍生物、蔗糖酯及衍生物、葡萄糖酯及衍生物,及其混合物。
17.根据权利要求25的组合物,其中季铵表面活性剂是季铵氯化物。
18.根据权利要求25的组合物,其中的中和剂是选自下组的,包括氢氧化钠、碳酸氢钠、碳酸钠、氢氧化钾、碳酸氢钾、碳酸钾、氢氧化镁、碳酸镁、氢氧化钙和碳酸钙。
19.根据权利要求25的组合物,其中石料表面是大理石表面。
20.据权利要求25的组合物,其中的组合物包括含量为0.0001至0.01重量百分比的香味剂。
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US10/073,815 | 2002-02-11 | ||
US10/073,815 US6635609B2 (en) | 2002-02-11 | 2002-02-11 | Surface maintenance composition |
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CN100540646C CN100540646C (zh) | 2009-09-16 |
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US (1) | US6635609B2 (zh) |
EP (1) | EP1474502B1 (zh) |
JP (1) | JP2005517766A (zh) |
KR (1) | KR20040081774A (zh) |
CN (1) | CN100540646C (zh) |
AT (1) | ATE341610T1 (zh) |
AU (1) | AU2003210797B2 (zh) |
BR (1) | BR0307272B1 (zh) |
CA (1) | CA2472919C (zh) |
DE (1) | DE60308824T2 (zh) |
ES (1) | ES2268379T3 (zh) |
MX (1) | MXPA04007791A (zh) |
NZ (1) | NZ534057A (zh) |
WO (1) | WO2003068900A1 (zh) |
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DE102004036067A1 (de) * | 2004-07-24 | 2006-02-16 | Goldschmidt Gmbh | Wässrige Reinigungsmittelkonzentrate für raue, insbesondere profilierte Fliesen und Platten |
US7459421B2 (en) * | 2005-06-03 | 2008-12-02 | J&J Marketing, Llc | Cleaning and conditioning composition and method |
US7910532B2 (en) * | 2006-04-06 | 2011-03-22 | Karin M. Johnson | Hard surface cleaner formulation and method of use |
JP5295548B2 (ja) * | 2006-12-01 | 2013-09-18 | 花王株式会社 | 床水拭き用助剤 |
US9615675B2 (en) | 2008-06-10 | 2017-04-11 | Display Technologies, Llc | System for displaying products on a shelf |
GB201211701D0 (en) | 2012-07-02 | 2012-08-15 | Reckitt Benckiser Llc | Aqueous alcoholic microbicidal compositions comprising zinc ions |
GB201211688D0 (en) | 2012-07-02 | 2012-08-15 | Reckitt Benckiser Llc | Aqueous alcoholic microbicidal compositions comprising zinc ions |
GB201211691D0 (en) | 2012-07-05 | 2012-08-15 | Reckitt Benckiser Llc | Sprayable aqueous alcoholic microbicidal compositions comprising zinc ions |
GB201211702D0 (en) | 2012-07-02 | 2012-08-15 | Reckitt Benckiser Llc | Sprayable aqueous alcoholic microbicidal compostions comprising zinc ions |
WO2014083330A1 (en) | 2012-11-30 | 2014-06-05 | Reckitt & Colman (Overseas) Limited | Microbicidal personal care compositions comprising metal ions |
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US4738876A (en) | 1985-06-05 | 1988-04-19 | S. C. Johnson & Son, Inc. | Stone surface treating methods and compositions |
DE3533531A1 (de) | 1985-09-20 | 1987-04-02 | Henkel Kgaa | Reinigungsmittel fuer harte oberflaechen |
US5658557A (en) * | 1989-08-07 | 1997-08-19 | The Procter & Gamble Company | Hair care compositions comprising silicone-containing copolymers |
US5264269A (en) * | 1989-09-21 | 1993-11-23 | Kao Corporation | Water-disintegratable cleaning article in laminated sheet form |
DE4310136A1 (de) * | 1993-03-29 | 1994-10-06 | Henkel Kgaa | Verfahren zur Reinigung von Steinoberflächen |
US5554320A (en) | 1993-11-22 | 1996-09-10 | Yianakopoulos; Georges | Liquid cleaning compositions |
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US5490883A (en) | 1994-06-16 | 1996-02-13 | The Servicemaster Company, L.P. | Solution and method for cleaning marble surfaces |
DE69524212T2 (de) * | 1995-06-12 | 2002-07-25 | THE PROCTER & GAMBLE COMPANY, CINCINNATI | Reinigungszusammensetzung und Verfahren zum Reinigen von empfindlichen Oberflächen |
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GB2336371B (en) * | 1998-04-14 | 2002-05-08 | Reckitt & Colman Inc | Aqueous disinfecting and cleaning compositions |
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US20030153478A1 (en) | 2003-08-14 |
US6635609B2 (en) | 2003-10-21 |
DE60308824D1 (de) | 2006-11-16 |
JP2005517766A (ja) | 2005-06-16 |
NZ534057A (en) | 2007-02-23 |
AU2003210797A1 (en) | 2003-09-04 |
WO2003068900A1 (en) | 2003-08-21 |
EP1474502B1 (en) | 2006-10-04 |
ES2268379T3 (es) | 2007-03-16 |
MXPA04007791A (es) | 2004-10-15 |
DE60308824T2 (de) | 2007-01-18 |
BR0307272A (pt) | 2004-12-14 |
AU2003210797B2 (en) | 2007-09-20 |
CA2472919A1 (en) | 2003-08-21 |
CN100540646C (zh) | 2009-09-16 |
KR20040081774A (ko) | 2004-09-22 |
BR0307272B1 (pt) | 2013-03-19 |
ATE341610T1 (de) | 2006-10-15 |
CA2472919C (en) | 2008-04-29 |
EP1474502A1 (en) | 2004-11-10 |
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